Citation: LIANG Xixi, CHEN Chuang, WANG Weiguo, LI Haiyang. Detection of 1,4-dioxane in water by membrane extraction-gas chromatography/differential mobility spectrometry[J]. Chinese Journal of Chromatography, ;2014, 32(8): 837-842. doi: 10.3724/SP.J.1123.2014.04035 shu

Detection of 1,4-dioxane in water by membrane extraction-gas chromatography/differential mobility spectrometry

LIANG Xixi ^1,2 ,
CHEN Chuang ¹ ,
WANG Weiguo ¹ ,
LI Haiyang ^1,,

1.
1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;

Corresponding author: LI Haiyang,
Received Date: 23 April 2014
Available Online: 9 June 2014
Fund Project: 国家重大科学仪器设备开发专项(2013YQ09070302) (2013YQ09070302)国家自然科学基金项目(21177124,21077101) (21177124,21077101)国民核生化灾害防护国家重点实验室课题(SKLNBC2012-08K). (SKLNBC2012-08K)

The method of detecting trace 1,4-dioxane in water using membrane extraction coupled with gas chromatography/differential mobility spectrometry (GC/DMS) was developed. The parameters including radio frequency voltage, sampling flow rate, permeation time and trapping time were optimized to 1000 V, 50 mL/min, 30 min and 150 s, respectively. The linear range for dioxane was obtained from 2.0 μg/L to 20.0 μg/L. The LOD was found to be 0.67 μg/L. The specificity towards 1,4-dioxane in the presence of five chlorinated hydrocarbons was improved by using two-dimensional GC separation with optimized DMS compensation voltage. This method paves a way for developing field-deployable sensors for real-time monitoring contaminants in groundwater.
- membrane extraction device,
- gas chromatography/differential mobility spectrometry (GC/DMS),
- 1,4-dioxane,
- chlorinated hydrocarbons,
- water
1. [1]
  [1] NIST Standard Reference Database Number 69.[2014-04-23]. http://webbook.nist.gov/chemistry/
2. [2]
  [2] Wells G, Schroth W, Brauch H, et al. Clin Nephrol, 2009, 71(6): 708
3. [3]
  [3] Grimmett P E, Munch J W. J Chromatogr Sci, 2009, 47(1): 31
4. [4]
  [4] Draper W M, Dhoot J S, Remoy J W, et al. Analyst, 2000, 125(8): 1403
5. [5]
  [5] Isaacson C, Mohr T K G, Field J A. Environ Sci Technol, 2006, 40(23): 7305
6. [6]
  [6] Epstein P S, Mauer T, Wagner M, et al. Anal Chem, 1987, 59(15): 1987
7. [7]
  [7] Kawata K, Ibaraki T, Tanabe A, et al. J Chromatogr A, 2001, 911(1): 75
8. [8]
  [8] Shirey R E, Linton C M. J Chromatogr Sci, 2006, 44(7): 444
9. [9]
  [9] Shin H-S, Lim H-H. Chromatographia, 2011, 73(11/12): 1233
10. [10]
  [10] Jochmann M A, Kmiecik M P, Schmidt T C. J Chromatogr A, 2006, 1115(1): 208
11. [11]
  [11] Du Y, Zhang W, Whitten W, et al. Anal Chem, 2010, 82(10): 4089
12. [12]
  [12] Shvartsburg A A. Differential Ion Mobility Spectrometry: Nonlinear Ion Transport and Fundamentals of FAIMS. Boca Raton, FL: CRC Press, 2009
13. [13]
  [13] Zhang J, Li L F, Guo D P, et al. Chinese Journal of Analytical Chemistry (张洁, 李灵锋, 郭大鹏, 等. 分析化学), 2013, 41(7): 986
14. [14]
  [14] Wang J C, Xiong L, Zhang H J, et al. Chinese Journal of Chromatography (王金成, 熊力, 张海军, 等. 色谱), 2013, 31(2): 139
15. [15]
  [15] Telgheder U, Malinowski M, Jochmann M A. Int J Ion Mobil Spec, 2009, 12(4): 123
16. [16]
  [16] Li M, Conlon P, Fiorenza S, et al. Ground Water Monit Remediat, 2011, 31: 70
17. [17]
  [17] Nakamura S, Daishima S. Anal Chim Acta, 2005, 548: 79
18. [18]
  [18] Kennedy R A, Mayhew C A, Thomas R, et al. Int J Mass Spectrom, 2003, 223/224: 627
19. [19]
  [19] Nicoletti A, Paradisi C, Scorrano G. Rapid Commun Mass Spectrom, 2001, 15(20): 1904
20. [20]
  [20] Mayhew C A, Thomas R, Watts P. Int J Mass Spectrom, 2003, 223/224: 91
21. [21]
  [21] Dotremont C, Goethaert S, Vandecasteele C. Desalination, 1993, 91(2): 177
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