Citation: MENG Jie, SUN Yuxiu, LI Yan. Synthesis of two metal-organic complexes and characterization of their adsorption behaviour of ten polycyclic aromatic hydrocarbons[J]. Chinese Journal of Chromatography, ;2014, 32(7): 753-761. doi: 10.3724/SP.J.1123.2014.03014 shu

Synthesis of two metal-organic complexes and characterization of their adsorption behaviour of ten polycyclic aromatic hydrocarbons

1.
Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 300387, China

Corresponding author: LI Yan,
Received Date: 11 March 2014
Available Online: 13 April 2014
Fund Project: 国家自然科学基金重点项目(21375095) (21375095)全国优秀博士学位论文作者专项资助资金(FANEDD-201023) (FANEDD-201023)天津市应用基础研究计划重点项目(12JCZDJC21700) (12JCZDJC21700)天津市高校“中青年骨干创新人才培养计划”项目(ZX110GG015) (ZX110GG015)天津市高等学校创新团队培养计划项目(TD12-5038). (TD12-5038)

Metal-organic frameworks (MOFs) are concerned mainly due to the unusual properties for diverse analytical applications, such as high surface area, good thermal stability, in-pore functionality and outer-surface modification. Two metal-organic complexes were prepared by two methods of hydrothermal synthesis and room temperature synthesis, separately. The compositions, structures, thermal stability and adsorption properties of the two complexes were characterized by X-ray powder diffraction (XRD), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and Brunauer-Emmett-Teller (BET) method, which indicated that the two complexes have not only good thermal stability but also good adsorption for polycyclic aromatic hydrocarbons (PAHs). PAHs enter into environment leading to pollution by industrial and agricultural production and life, rooting in the incomplete combustion or pyrolysis of organism. PAHs are strongly carcinogenic and mutagenic. Some PAHs are considered as endocrine disruptors, and maybe have biological effects on human health. Regulations have thus been formulated for monitoring and controlling PAHs by the United States Environmental Protection Agency (U. S. EPA) and other government agencies. Adsorption kinetic of PAHs on the two complexes could be well described by the pseudo-second order kinetic model, and the adsorption behaviors of the two complexes on PAHs are in accord with Langmuir model. In addition, the adsorption capacities increase with the increasing adsorbent dosage. It is proved by the FT-IR data that π-π interactions between the PAHs and the framework terephthalic acid molecules. Ten PAHs were adsorbed well on the two complexes which have good adsorptive selectivity. By further optimizing of the two complex materials, it is promising to use them as chromatographic stationary phases.
- metal-organic complexe,
- synthesis,
- polycyclic aromatic hydrocarbons (PAHs),
- adsorption kinetic,
- adsorption isotherm,
- gas chromatography (GC)
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沈阳化工大学材料科学与工程学院沈阳 110142