Citation: ZHAI Rui, JIAO Fenglong, LIN Hongjun, HAO Feiran, LI Jiabin, YAN Hui, LI Nannan, WANG Huanhuan, JIN Zuyao, ZHANG Yangjun, QIAN Xiaohong. Progress in metal-organic frameworks[J]. Chinese Journal of Chromatography, ;2014, 32(2): 107-116. doi: 10.3724/SP.J.1123.2013.10002 shu

Progress in metal-organic frameworks

  • Corresponding author: ZHANG Yangjun,  QIAN Xiaohong, 
  • Received Date: 8 October 2013
    Available Online: 22 November 2013

    Fund Project: 国家重大科学计划项目(2012CB910603,2010CB912704) (2012CB910603,2010CB912704)国家重大科学仪器设备开发专项项目(2011YQ030139,2011YQ06008408,2011YQ09000504,2012YQ12004407) (2011YQ030139,2011YQ06008408,2011YQ09000504,2012YQ12004407)国家高技术研究发展计划项目(2012AA020202) (2012AA020202)国家自然科学基金重点项目(20735005,21275159,31100591). (20735005,21275159,31100591)

  • Metal-organic frameworks (MOFs) are a class of crystalline materials built from organic binding ligands and metal ions through self-assembly. Currently, MOFs have drawn a growing interest among the scientific teams of various fields. Compared with conventional inorganic porous materials, MOFs possess larger specific surface areas, higher porosity and diversity of structures and functions, thus many potential applications have been proposed in the domains of gas adsorption and separation, sensors, drug delivery, catalysis or others. The combinations of MOFs and other materials such as graphene oxide, magnetic nanoparticles have obvious advantages in adsorption and separation. The appearance of novel materials greatly promotes interdisciplinary developments such as organic chemistry, inorganic chemistry, coordination chemistry, materials chemistry, life science and computer science. This article reviews the progress of MOFs in recent years, including the characteristics of MOFs, advances at home and abroad, applications, central issues of compound MOFs and the prospects in the future.
  • 加载中
    1. [1]

      [1] Li H, Eddaoudi M, O'Keeffe M, et al. Nature, 1999, 402(6759): 276  

    2. [2]

      [2] Chae H K, Siberio-Perez D Y, Kim J, et al. Nature, 2004, 427(6974): 523  

    3. [3]

      [3] Furukawa H, Ko N, Go Y B, et al. Science, 2010, 329(5990): 424  

    4. [4]

      [4] Eddaoudi M, Kim J, Rosi N, et al. Science, 2002, 295(5554): 469  

    5. [5]

      [5] Deng H X, Doonan C J, Furukawa H, et al. Science, 2010, 327(5967): 846  

    6. [6]

      [6] Yaghi O M, Li G M, Li H L. Nature, 1995, 378(6558): 703  

    7. [7]

      [7] Eddaoudi M, Li H L, Yaghi O M. J Am Chem Soc, 2000, 122(7): 1391  

    8. [8]

      [8] Rowsell J L C, Spencer E C, Eckert J, et al. Science, 2005, 309(5739): 1350  

    9. [9]

      [9] Chen B, Eddaoudi M, Hyde S T, et al. Science, 2001, 291(5506): 1021  

    10. [10]

      [10] Rosi N L, Eckert J, Eddaoudi M, et al. Science, 2003, 300(5622): 1127  

    11. [11]

      [11] Eddaoudi M, Kim J, O'Keeffe M, et al. J Am Chem Soc, 2002, 124(3): 376  

    12. [12]

      [12] Millward A R, Yaghi O M. J Am Chem Soc, 2005, 127(51): 17998  

    13. [13]

      [13] Li Q W, Zhang W Y, Miljanic O S, et al. Science, 2009, 325(5942): 855  

    14. [14]

      [14] Park K S, Ni Z, Cote A P, et al. Proc Natl Acad Sci, 2006, 103(27): 10186  

    15. [15]

      [15] Banerjee R, Phan A, Wang B, et al. Science, 2008, 319(5865): 939  

    16. [16]

      [16] Morris W, Doonan C J, Furukawa H, et al. J Am Chem Soc, 2008, 130(38): 12626  

    17. [17]

      [17] Houndonougbo Y, Signer C, He N, et al. J Phys Chem C, 2013, 117(20): 10326  

    18. [18]

      [18] Serre C, Millange F, Thouvenot C, et al. J Am Chem Soc, 2002, 124(45): 13519  

    19. [19]

      [19] Boutin A, Coudert F X, Springuel-Huet M A, et al. J Phys Chem C, 2010, 114(50): 22237  

    20. [20]

      [20] Horcajada P, Serre C, Maurin G, et al. J Am Chem Soc, 2008, 130(21): 6774  

    21. [21]

      [21] Ferey G, Serre C, Draznieks C M, et al. Angew Chem, 2004, 116(46): 6456  

    22. [22]

      [22] Ferey G, Draznieks C M, Serre C, et al. Science, 2005, 309(5743): 20402

    23. [23]

      [23] Latroche M, Surble S, Serre C, et al. Angew Chem Int Ed, 2006, 45(48): 8227  

    24. [24]

      [24] Llewellyn P L, Bourrelly S, Serre C, et al. Langmuir, 2008, 24(14): 7245  

    25. [25]

      [25] Agostoni V, Chalati T, Horcajada P, et al. Adv Healthcare Mater, 2013, 2(12):1630  

    26. [26]

      [26] Henschel A, Gedrich K, Kraehnert R, et al. Chem Commun, 2008, 40(4): 4192

    27. [27]

      [27] Chen J X, Ohba M, Zhao D Y, et al. Cryst Growth Des, 2006, 6(3): 664  

    28. [28]

      [28] Ikezoe Y, Washino G, Uemura T, et al. Nat Mater, 2012, 11(12): 1081

    29. [29]

      [29] Ohmori O, Kawano M, Fujita M. Angew Chem Int Ed, 2005, 44(13): 1962  

    30. [30]

      [30] Kawano M, Kawamichi T, Haneda T, et al. J Am Chem Soc, 2007, 129(50): 15418  

    31. [31]

      [31] Inokuma Y, Kojima N, Arai T, et al. J Am Chem Soc, 2011, 133(49): 19691  

    32. [32]

      [32] Tian Y Q, Chen Z X, Weng L H, et al. Inorg Chem, 2004, 43(15): 4631  

    33. [33]

      [33] Xu G C, Ma X M, Zhang L, et al. J Am Chem Soc, 2010, 132(28): 9588  

    34. [34]

      [34] Xu G C, Zhang W, Ma X M, et al. J Am Chem Soc, 2011, 133(38): 14948  

    35. [35]

      [35] Gassensmith J J, Furukawa H, Smaldone R A, et al. J Am Chem Soc, 2011, 133(39): 15312  

    36. [36]

      [36] Wu D, Gassensmith J J, Gouvea D, et al. J Am Chem Soc, 2013, 135(18): 6790  

    37. [37]

      [37] Kaye S S, Dailly A, Yaghi O M, et al. J Am Chem Soc, 2007, 129(46): 14176  

    38. [38]

      [38] Rowsell J L C, Yaghi O M. J Am Chem Soc, 2006, 128(4): 1304  

    39. [39]

      [39] Furukawa H, Miller M A, Yaghi O M. J Mater Chem, 2007, 17(30): 3197  

    40. [40]

      [40] Farha O K, Yazaydin A O, Eryazici I, et al. Nat Chem, 2010, 2(11): 944  

    41. [41]

      [41] Gu X J, Lu Z H, Xu Q. Chem Commun, 2010, 46(39): 7400  

    42. [42]

      [42] Dybtsev D N, Chun H, Yoon S H, et al. J Am Chem Soc, 2004, 126(1): 32  

    43. [43]

      [43] Demessence A, D'Alessandro D M, Foo M L, et al. J Am Chem Soc, 2009, 131(25): 8784  

    44. [44]

      [44] Bloch E D, Britt D, Lee C, et al. J Am Chem Soc, 2010, 132(41): 14382  

    45. [45]

      [45] Britt D, Tranchemontagne D, Yaghi O M. Proc Natl Acad Sci, 2008, 105(33): 11623  

    46. [46]

      [46] Rieter W J, Taylor K M L, An H, et al. J Am Chem Soc, 2006, 128(28): 9024  

    47. [47]

      [47] Taylor-Pashow K M L, Rocca J D, Xie Z G, et al. J Am Chem Soc, 2009, 131(40): 14261  

    48. [48]

      [48] Sadakiyo M, Yamada T, Kitagawa H. J Am Chem Soc, 2009, 131(29): 9906  

    49. [49]

      [49] Okawa H, Sadakiyo M, Yamada T, et al. J Am Chem Soc, 2013, 135(6): 2256  

    50. [50]

      [50] Zhan W W, Kuang Q, Zhou J Z, et al. J Am Chem Soc, 2013, 135(5): 1926  

    51. [51]

      [51] Navarro J A R, Barea E, Rodriguez-Dieguez A, et al. J Am Chem Soc, 2008, 130(12): 3978  

    52. [52]

      [52] Okawa H, Shigematsu A, Sadakiyo M, et al. J Am Chem Soc, 2009, 131(17): 13516

    53. [53]

      [53] Song F, Wang C, Falkowski J M, et al. J Am Chem Soc, 2010, 132(43): 15390  

    54. [54]

      [54] Gascon J, Aktay U, Hernandez-Alonso M D, et al. J Catal, 2009, 261(1): 75  

    55. [55]

      [55] Jiang H L, Akita T, Ishida T, et al. J Am Chem Soc, 2011, 133(5): 1304  

    56. [56]

      [56] Aijaz A, Karkamkar A, Choi Y J, et al. J Am Chem Soc, 2012, 134(34): 13926  

    57. [57]

      [57] Horcajada P, Serre C, Vallet-Regi M, et al. Angew Chem, 2006, 118(36): 6120  

    58. [58]

      [58] Rieter W J, Pott K M, Taylor K M L, et al. J Am Chem Soc, 2008, 130(35): 11584  

    59. [59]

      [59] Imaz I, Rubio-Martinez M, Garcia-Fernandez L, et al. Chem Commun, 2010, 46(26): 4737  

    60. [60]

      [60] Ke F, Qiu L G, Yuan Y P, et al. J Mater Chem, 2012, 22(19): 9497  

    61. [61]

      [61] Huo S H, Yan X P. Analyst, 2012, 137(15): 3445  

    62. [62]

      [62] Banerjee A, Gokhale R, Bhatnagar S, et al. J Mater Chem, 2012, 22(37): 19694  

    63. [63]

      [63] Ke F, Yuan Y P, Qiu L G, et al. J Mater Chem, 2011, 21(11): 3843  

    64. [64]

      [64] Wang Y, Xie J, Wu Y C, et al. J Mater Chem A, 2013, 1(31): 8782  

    65. [65]

      [65] Petit C, Bandosz T J. J Mater Chem, 2009, 19(36): 6521  

    66. [66]

      [66] Petit C, Bandosz T J. Adv Mater, 2009, 21(46): 4753

    67. [67]

      [67] Petit C, Mendoza B, Bandosz T J. Langmuir, 2010, 26(19): 15302  

    68. [68]

      [68] Levasseur B, Petit C, Bandosz T J. Appl Mater Interfaces, 2010, 2(12): 3606  

    69. [69]

      [69] Petit C, Burress J, Bandosz T J. Carbon, 2011, 49(2): 563  

    70. [70]

      [70] Petit C, Huang L L, Jagiello J, et al. Langmuir, 2011, 27(21): 13043  

    71. [71]

      [71] Petit C, Mendoza B, O'Donnell D, et al. Langmuir, 2011, 27(16): 10234  

    72. [72]

      [72] Petit C, Bandosz T J. Adv Funct Mater, 2011, 21(11): 2108  

    73. [73]

      [73] Petit C, Bandosz T J. Dalton Trans, 2012, 41(14): 4027  

    74. [74]

      [74] Huang Z H, Liu G Q, Kang F Y. Appl Mater Interfaces, 2012, 4(9): 4942  

    75. [75]

      [75] Lin W, Wang J L, Ying W T, et al. Chinese Journal of Chromatography (林威, 王京兰, 应万涛, 等. 色谱), 2012, 30(8): 763

    76. [76]

      [76] Zhou W, Liu X H, Zhou X W, et al. Chinese Journal of Chromatography (周玮, 刘晓慧, 周新文, 等. 色谱), 2007, 25(5): 623

    77. [77]

      [77] Gu Z Y, Chen Y J, Jiang J Q, et al. Chem Commun, 2011, 47(16): 4787  

  • 加载中
    1. [1]

      Wenjuan SHIYuke LUXiuyuan LILei HOUYaoyu WANG . Mg(Ⅱ) metal-organic frameworks based on biphenyltetracarboxylic acid: Synthesis and CO2 adsorption and catalytic conversion performance. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2455-2463. doi: 10.11862/CJIC.20250220

    2. [2]

      Ben Yang Shukun Shen Pujun Jin Yujia Luo Jianyong Hu . Covalent organic frameworks: emerging organic porous materials. University Chemistry, 2026, 41(4): 264-274. doi: 10.12461/PKU.DXHX202502128

    3. [3]

      Yi DINGPeiyu LIAOJianhua JIAMingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393

    4. [4]

      Hui-Ying ChenHao-Lin ZhuPei-Qin LiaoXiao-Ming Chen . Integration of Ru(Ⅱ)-Bipyridyl and Zinc(Ⅱ)-Porphyrin Moieties in a Metal-Organic Framework for Efficient Overall CO2 Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306046-0. doi: 10.3866/PKU.WHXB202306046

    5. [5]

      Zhongxin YUWei SONGYang LIUYuxue DINGFanhao MENGShuju WANGLixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304

    6. [6]

      Kaimin WANGNa HEShiyi LIXuling BAIWeiqing SUNYanqing YEYulu MA . Synthesis, Hirshfeld surface analysis and properties of two Zn(Ⅱ)/Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 55-64. doi: 10.11862/CJIC.20250178

    7. [7]

      Xiao SANGQi LIUJianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158

    8. [8]

      Botao QUQian WANGQian WANGRuiping ZHANG . Synthesis, crystal structures, and luminescence properties of zinc coordination polymers based on 2,5-dibromoterephthalate. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 917-924. doi: 10.11862/CJIC.20260357

    9. [9]

      Ping LIGeng TANXin HUANGFuxing SUNJiangtao JIAGuangshan ZHUJia LIUJiyang LI . Green synthesis of metal-organic frameworks with open metal sites for efficient ammonia capture. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2063-2068. doi: 10.11862/CJIC.20250020

    10. [10]

      Zhe Ji Guangxu Lan Jiangnan Li Sihai Yang . A New Protocol to Construct Molecular Materials: A Brief Introduction on the 2025 Nobel Prize in Chemistry. University Chemistry, 2025, 40(12): 70-77. doi: 10.12461/PKU.DXHX202511097

    11. [11]

      Ruige ZHANGZhe ZHANGHe ZHENGZhan SHI . Recent advances of metal-organic frameworks for alkaline electrocatalytic oxygen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2011-2028. doi: 10.11862/CJIC.20250185

    12. [12]

      Xiaogang YANGXinya ZHANGJing LIHuilin WANGMin LIXiaotian WEIXinci WULufang MA . Synthesis, structure, and photoelectric properties of Zinc(Ⅱ)-triphenylamine based metal-organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2078-2086. doi: 10.11862/CJIC.20250167

    13. [13]

      Xiaowei TANGShiquan XIAOJingwen SUNYu ZHUXiaoting CHENHaiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173

    14. [14]

      Hong CAIJiewen WUJingyun LILixian CHENSiqi XIAODan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382

    15. [15]

      Jianding LIJunyang FENGHuimin RENGang LI . Proton conductive properties of a Hf(Ⅳ)-based metal-organic framework built by 2,5-dibromophenyl-4,6-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1094-1100. doi: 10.11862/CJIC.20240464

    16. [16]

      Bizhu ShaoHuijun DongYunnan GongJianhua MeiFengshi CaiJinbiao LiuDichang ZhongTongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO2 Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026

    17. [17]

      Qiang MAYiming ZHUMeiqi HUAGuangyu LUXingdong WANGHailong YUHuan PANGYuping LI . Research progress on metal-organic frameworks as comprehensive carrier platforms for delivering anti-glioma drugs. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 657-667. doi: 10.11862/CJIC.20250250

    18. [18]

      Zelong LIANGShijia QINPengfei GUOHang XUBin ZHAO . Synthesis and electrocatalytic CO2 reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409

    19. [19]

      Zhuo WangXue BaiKexin ZhangHongzhi WangJiabao DongYuan GaoBin Zhao . MOF-Templated Synthesis of Nitrogen-Doped Carbon for Enhanced Electrochemical Sodium Ion Storage and Removal. Acta Physico-Chimica Sinica, 2025, 41(3): 100026-0. doi: 10.3866/PKU.WHXB202405002

    20. [20]

      Mengmeng SUNRui JIANGTianyi ZHAOJimin YANG . Fabrication of carboxyl-modified UiO-67 nanomaterials and their highly efficient removal mechanism of anionic dye. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 499-506. doi: 10.11862/CJIC.20250281

Metrics
  • PDF Downloads(0)
  • Abstract views(1631)
  • HTML views(237)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return