Citation: HE Shiwei, HUANG Zhongping, ZHU Yan. Recent advances in preparation of novel chromatographic stationary phases with carbon nanotubes[J]. Chinese Journal of Chromatography, ;2013, 31(12): 1146-1153. doi: 10.3724/SP.J.1123.2013.08043 shu

Recent advances in preparation of novel chromatographic stationary phases with carbon nanotubes

1.
1. Institute of Scientific and Technical Information of Zhejiang Province, Hangzhou 310006, China;

Corresponding author: HUANG Zhongping,
Received Date: 26 August 2013
Available Online: 1 November 2013
Fund Project:

Carbon nanotubes (CNTs) as a new functional material have attracted the interest of scientists and engineers in analytical chemistry, due to their excellent physical, chemical and mechanical properties. The preparation of gas chromatographic stationary phases with CNTs has been performed by packing method or in situ catalytic chemical vapor deposition. The deposition of CNTs on a chromatographic solid matrix (e. g. silica micro-particles or organic polymer microspheres) was carried out to generate a packing material for high performance liquid chromatography. Capillary monolithic columns for liquid chromatography were also prepared by embedding CNTs in polymer monolithic columns. Columns with CNTs have the unique advantages in the separation of aromatic compounds for the π electron system of CNTs. Herein, the recent applications of CNTs in the preparation of chromatographic stationary phases are reviewed, including gas chromatography and liquid chromatography. The future developments in this field are also prospected.
- carbon nanotubes,
- chromatographic stationary phases,
- gas chromatography (GC),
- liquid chromatography (LC),
- review
1. [1]
  [1] Iijima S. Nature, 1991, 354(7): 56
2. [2]
  [2] Poole C P, Owens F J. Introduction to Nanotechnology. Hoboken, NJ, USA: John Wiley and Sons Inc, 2003
3. [3]
  [3] Connell M O. Carbon Nanotubes: Properties and Applications. Boca Raton, FL, USA: CRC, 2006
4. [4]
  [4] Gogotsi Y. Carbon Nanomaterials. Boca Raton, FL, USA: CRC, 2006
5. [5]
  [5] Yang B X, Pramoda K P, Xu G Q, et al. Adv Funct Mater, 2007, 17(13): 2062
6. [6]
  [6] Piran M, Kotlyar V, Medina D D, et al. J Mater Chem, 2009, 19(5): 631
7. [7]
  [7] Gopalan A I, Lee K P, Ragupathy D. Biosens Bioelectron, 2009, 24(7): 2211
8. [8]
  [8] Zhu X Y, Lee S M, Lee Y H, et al. Phys Rev Lett, 2000, 85(13): 2757
9. [9]
  [9] Fu S L, Ding L, Zhu S H, et al. Chinese Journal of Chromatography (付善良, 丁利, 朱绍华, 等. 色谱), 2011, 29(8): 737
10. [10]
  [10] Wu X H, Ding L, Li Z H, et al. Chinese Journal of Chromatography (吴新华, 丁利, 李忠海, 等. 色谱), 2010, 28(11): 1094
11. [11]
  [11] Zhao H X, Jia Y X, Ding M Y, et al. Chinese Journal of Chromatography (赵海香, 贾艳霞, 丁明玉, 等. 色谱), 2011, 29(5): 443
12. [12]
  [12] Peng X J, Pang J S, Deng A H, et al. Chinese Journal of Chromatography (彭晓俊, 庞晋山, 邓爱华, 等. 色谱), 2012, 30(9): 966
13. [13]
  [13] Wu C X, Wang C, Wang Z. Chinese Journal of Chromatography (武春霞, 王春, 王志. 色谱), 2011, 29(1): 6
14. [14]
  [14] Mittermuller M, Volmer D A. Analyst, 2012, 137(14): 3195
15. [15]
  [15] Zhang Z X, Wang Z Y, Liao Y P, et al. J Sep Sci, 2006, 29(12): 1872
16. [16]
  [16] Chen A, Holt-Hindle P. Chem Rev, 2010, 110(6): 3767
17. [17]
  [17] Tasis D, Tagmatarchis N, Bianco A, et al. Chem Rev, 2006, 106(3): 1105
18. [18]
  [18] Li Q L, Yuan D X. J Chromatogr A, 2003, 1003(1/2): 203
19. [19]
  [19] Li Q L, Yuan D X. Acta Chimica Sinica (李权龙, 袁东星. 化学学报), 2002, 60(10): 1876
20. [20]
  [20] Speltini A, Merli D, Quartarone E, et al. J Chromatogr A, 2010, 1217(17): 2918
21. [21]
  [21] Merli D, Speltini A, Ravelli D, et al. J Chromatogr A, 2010, 1217(46): 7275
22. [22]
  [22] Speltini A, Merli D, Dondi D, et al. Anal Bioanal Chem, 2012, 403(4): 1157
23. [23]
  [23] Lin Y, Taylor S, Li H, et al. J Mater Chem, 2004, 14(4): 527
24. [24]
  [24] Menna E, Negra F D, Prato M, et al. Carbon, 2006, 44(8): 1581
25. [25]
  [25] Chang Y X, Zhou L L, Li G X, et al. J Liq Chromatogr R T, 2007, 30(19): 2953
26. [26]
  [26] Kwon S H, Park J H. J Sep Sci, 2006, 29(7): 945
27. [27]
  [27] Andre C, Gharbi T, Guillaume Y C. J Sep Sci, 2009, 32(10): 1757
28. [28]
  [28] Andre C, Aljhani R, Gharbi T, et al. J Sep Sci, 2011, 34(11): 1221
29. [29]
  [29] Liang X J, Liu S J, Liu H M, et al. J Sep Sci, 2010, 33(21): 3304
30. [30]
  [30] Zhong Y Y, Zhou W F, Zhang P M, et al. Talanta, 2010, 82(4): 1439
31. [31]
  [31] Zakaria P, Hutchinson J P, Avdalovic N, et al. Anal Chem, 2005, 77(2): 417
32. [32]
  [32] Hilder E F, Svec F, Frechet J M J. J Chromatogr A, 2004, 1053(1/2): 101
33. [33]
  [33] Slingsby R W, Pohl C A. J Chromatogr, 1988, 458(1): 241
34. [34]
  [34] Huang Z P, Wu H W, Wang F L, et al. J Chromatogr A, 2013, 1294(1): 152
35. [35]
  [35] Huang Z P, Xi L L, Subhani Q, et al. Carbon, 2013, 62(1): 127
36. [36]
  [36] Saridara C, Mitra S. Anal Chem, 2005, 77(21): 7094
37. [37]
  [37] Karwa M, Mitra S. Anal Chem, 2006, 78(6): 2064
38. [38]
  [38] Hussain C M, Saridara C, Mitra S. Anal Chem, 2010, 82(12): 5184
39. [39]
  [39] Hussain C M, Saridara C, Mitra S. RSC Adv, 2011, 1(4): 685
40. [40]
  [40] Yuan L M, Ren C X, Li L, et al. Anal Chem, 2006, 78(18): 6384
41. [41]
  [41] Ren C X, Ai P, Yuan L M. Chinese Journal of Analysis Laboratory (任朝兴, 艾萍, 袁黎明. 分析试验室), 2008, 27(7): 23
42. [42]
  [42] Zhao L, Ai P, Xiong W W, et al. Chinese Journal of Analysis Laboratory (赵丽, 艾萍, 熊维伟, 等. 分析试验室), 2009, 28(9): 85
43. [43]
  [43] Zhao L, Ai P, Duan A H, et al. Anal Bioanal Chem, 2011, 399(1): 143
44. [44]
  [44] Sun C, Zheng Y J, Tian J Z. Journal of Science of Teachers' College and University (孙澈, 郑永杰, 田景芝. 高师理科学刊), 2013, 33(2): 57
45. [45]
  [45] Wang Q, Svec F, Frechet J M J. Anal Chem, 1993, 65(17): 2243
46. [46]
  [46] Wang Q, Svec F, Frechet J M J. J Chromatogr A, 1994, 669(1/2): 230
47. [47]
  [47] Li Y, Chen Y, Xiang R, et al. Anal Chem, 2005, 77(5): 1398
48. [48]
  [48] Chambers S D, Svec F, Frechet J M J. J Chromatogr A, 2011, 1218(18): 2546
49. [49]
  [49] Ren H B, Liu R M. Chinese Journal of Analysis Laboratory (任呼博, 柳仁民. 分析试验室), 2009, 28(12): 1
50. [50]
  [50] Andre C, Lenancker G, Guillaume Y C. Talanta, 2012, 99(1): 580
51. [51]
  [51] Aqel A, Yusuf K, Al-Othman Z A, et al. Analyst, 2012, 137(18): 4309
52. [52]
  [52] Wang N N, He S W, Yan W W, et al. J Appl Polym Sci, 2013, 128(1): 741
53. [53]
  [53] Safavi A, Maleki N, Doroodmand M M. Anal Chim Acta, 2010, 675(2): 207
54. [54]
  [54] Katz E, Willner I. Chem Phys Chem, 2004, 5(8): 1084
55. [55]
  [55] Zhong Y Y, Zhou W F, Zhu H B, et al. Anal Chim Acta, 2011, 686(1/2): 1
56. [56]
  [56] Zhong Y Y, Zhou W F, Zeng X L, et al. Chin Chem Lett, 2011, 22(4): 461
57. [57]
  [57] Stadermann M, McBrady A D, Dick B, et al. Anal Chem, 2006, 78(16): 5639
58. [58]
  [58] Reid V R, Stadermann M, Bakajin O, et al. Talanta, 2009, 77(4): 1420
59. [59]
  [59] Fonverne A, Ricoul F, Demesmay C, et al. Sensor Actuat B: Chem, 2008, 129(2): 510
60. [60]
  [60] Fonverne A, Demesmay C, Ricoul F, et al. Sensor Actuat A: Phys, 2011, 167(2): 517
61. [61]
  [61] Yu J G, Huang D S, Huang K L, et al. Chin J Chem, 2011, 29(5): 893
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