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Citation: ZHOU Hongbin, XIONG Zhiyu, LI Ping, LI Jing, SUN Li, ZHAO Yunxia. Determination of alditols in foods by ion chromatography-mass spectrometry[J]. Chinese Journal of Chromatography, ;2013, 31(11): 1093-1101. doi: 10.3724/SP.J.1123.2013.05008 shu

Determination of alditols in foods by ion chromatography-mass spectrometry

ZHOU Hongbin ^1,, ,
XIONG Zhiyu ^1,2 ,
LI Ping ¹ ,
LI Jing ¹ ,
SUN Li ¹ ,
ZHAO Yunxia ¹

1.
1. State Key Laboratory of Food Additive and Condiment Testing, Zhenjiang 212008, China;

Corresponding author: ZHOU Hongbin,
Received Date: 3 May 2013
Available Online: 4 July 2013
Fund Project: 国家质量监督检验检疫总局公益性科研项目(2012424012-3). (2012424012-3)

A method for the determination of alditols in foods by ion chromatography-mass spectrometry (IC-MS) has been developed. The samples were extracted and cleaned up with the solid phase extraction (SPE). Then, the ion chromatographic separation was performed on a CarboPar MA1 column. The alditols were determined by MS with the selected ion monitoring (SIM) mode and quantified by the external standard method. The calibration curves showed good linearity in the certain ranges with the correlation coefficients (R²) greater than 0.99. The limits of quantification (S/N=10) of erythritol, xylitol, D-sorbitol, D-mannitol, lactitol, maltitol were 0.98, 1.99, 2.24, 5.92, 13.56, 13.21 mg/kg and the limits of detection (S/N=3) were 0.28, 0.59, 0.71, 1.74, 4.14, 4.03 mg/kg, respectively. The spiked recoveries of the alditols in the foods at different levels were in the range of 82.5%-108.0% with the relative standard deviations (RSDs) of 1.5%-7.6%. The sensitivity, accuracy and precision of the method meet the technical standards of the determination. The method can be applied to the determination of alditols in foods.
- ion chromatography-mass spectrometry (IC-MS),
- alditol,
- food
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