Citation: HE Qiaosang, LU Yan, LIAO Shangfu, LI Xiudi. Determination of four polycyclic aromatic hydrocarbons in anthracene oil for toys by high performance liquid chromatography with diode array detection and fluorescence detection[J]. Chinese Journal of Chromatography, ;2013, 31(5): 435-440. doi: 10.3724/SP.J.1123.2012.12047 shu

Determination of four polycyclic aromatic hydrocarbons in anthracene oil for toys by high performance liquid chromatography with diode array detection and fluorescence detection

HE Qiaosang ¹ ,
LU Yan ¹ ,
LIAO Shangfu ¹ ,
LI Xiudi ^2,,

1.
1. Zhejiang Institute of Quality Inspection Science, Hangzhou 310013, China;

Corresponding author: LI Xiudi,
Received Date: 28 December 2012
Available Online: 1 March 2013
Fund Project: 浙江省质量技术监督系统科研计划项目(20100402). (20100402)

A method using high performance liquid chromatography with diode array detection coupled with fluorescence detection was applied to determine four polycyclic aromatic hydrocarbons in anthracene oil for toys. This method showed good abilities of the baseline separation and high sensitivity under the optimized analytical conditions. The limits of the fluorescence detection were 0.5-1000 μg/L, while the limits of the diode array detection were 0.5-1000 mg/L. The precisions of the method were 0.7%-8.8%. The recoveries of the standard samples were 70.0%-120%. The limits of detection (LOD) of anthracene, pyrene, phenanthrene and fluoranthene were 0.1, 0.1, 0.2 and 0.3 μg/L, and the limits of quantitation (LOQ) of the four substances were 0.4, 0.2, 0.5 and 0.8 μg/L, respectively. In comparison with other methods, the method has higher detection speed and lower detection limits, which is useful to analyze rapidly those four polycyclic aromatic hydrocarbons in anthracene oil for toys.
- high performance liquid chromatography (HPLC),
- diode array detection,
- fluorescence detection,
- polycyclic aromatic hydrocarbons,
- anthracene oil,
- toys
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