Citation: YAN Xiao-Ju, HE Huan, PENG Ying, WANG Xiao-Meng, GAO Zhan-Qi, YANG Shao-Gui, CHEN Hong-Zhe, SUN Cheng. Determination of Organophosphorus Flame Retardants in Surface Water by Solid Phase Extraction Coupled with Gas Chromatography-Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, ;2012, 40(11): 1693-1697. doi: 10.3724/SP.J.1096.2012.20298 shu

Determination of Organophosphorus Flame Retardants in Surface Water by Solid Phase Extraction Coupled with Gas Chromatography-Mass Spectrometry

1.
School of the Environment, Nanjing University, State Key Laboratory of Pollution Control and Resources Reuse, Nanjing 210046, China

Corresponding author: CHEN Hong-Zhe, SUN Cheng,
Received Date: 23 March 2012
Available Online: 20 July 2012
Fund Project: 本文系国家自然科学基金(No.2127061) (No.2127061) 江苏省环境监测科研基金项目(No.1115) (No.1115)江苏省研究生创新计划(No.CXZZ11-0050)资助 (No.CXZZ11-0050)

Organophosphorus flame retardants (OPFRs), as their increasing production and consumption, are almost ubiquitous in environmental compartments. In this study, a solid phase extraction (SPE) coupled with gas chromatography-mass spectrometric (SPE-GC-MS) method was developed for the determination of 8 typical OPFRs. The targets in water samples were concentrated by Poly-Sery PSD SPE cartridge, and then eluted by 4 mL ethyl acetate. The OPFRs were qualified and quantified by GC-MS in selective ion scan monitoring method (SIM). Good linearity was observed in the range of 2 to 200 ng/L OPFRs with correlation coefficients varing between 0.9937 and 0.9995. The limits of detection and limits of quantification ranged from 0.006 to 0.850 ng/L and 0.015 to 2.000 ng/L, respectively. Spiked recoveries of pure water and river water samples ranged from 70.3% to 114.3%, with the relative standard deviations less than 15%, except for tri(2-ethylhexyl)phosphate(TEHP). The satisfied recovery of TEHP was achieved when the spiked concentration was less than 50 ng/L. The results showed that the SPE-GC-MS analytical method established was sensitive and accurate for the determination of OPFRs in surface water samples. Then the method was applied to analyze OPFRs in the water collected in Meiliang Bay of Taihu Lake, and it was found that the total concentration of OPFRs was ranging from 1000 to 2700 ng/L.
- Organophosphorus flame retardants,
- Solid phase extraction,
- Gas chromatography-mass spectrometry,
- Surface water
1. [1]
  1 Reemtsma T, Quintana J B, Rodil R, Garcia-Lopez M, Rodriguez I. Trac-Trend Anal. Chem., 2008, 27(9): 727-737
2. [2]
  2 Weil E D, Levchik S V. J. Fire Sci., 2008, 26(3): 243-281
3. [3]
  3 Marklund A, Andersson B; Haglund P. Chemosphere, 2003, 53(9): 1137-1146
4. [4]
  4 Andresen J A, Grundmann A, Bester K. Sci. Total Environ., 2004, 332(1-3): 155-166
5. [5]
  5 Marklund A, Andersson B; Haglund P. Environ. Sci. Technol., 2005, 39(10): 3555-3562
6. [6]
  6 Kim S D, Cho J,Kim I S,Vanderford B J; Snyder S A. Water Res., 2007, 41(5): 1013-1021
7. [7]
  7 Bacaloni A, Cucci F,Guarino C, Nazzari M, Samperi R, Lagana A. Environ. Sci. Technol., 2008, 42(6): 1898-1903
8. [8]
  8 Stapleton H M, Klosterhaus S, Eagle S, Fuh J, Meeker J D, Blum A, Webster T F. Environ. Sci. Technol., 2009, 43(19): 7490-7495
9. [9]
  9 Fries E, Mihajlovic I. J. Environ. Monitor., 2011, 13(10): 2692-2694
10. [10]
  10 Kim J W, Isobe T, Chang K H, Amano A, Maneja R H, Zamora P B, Siringan F P, Tanabe S. Environ. Pollut., 2011, 159(12): 3653-3659
11. [11]
  11 Wang X W, J-f L, Yin Y G. J. Chromatogr. A, 2011, 1218(38): 6705-6711
12. [12]
  12 Ingerowski G, Friedle A, Thumulla J. Indoor Air., 2001, 11(3): 145-149
13. [13]
  13 Follmann W, Wober J. Toxicol. Lett., 2006, 161(2): 124-134
14. [14]
  14 Lin K. Environ. Chem. Lett., 2009, 7 (4): 309-312
15. [15]
  15 Makinen M S E, Makinen M R A, Koistinen J T B, Pasanen A L, Pasanen P O, Kalliokoski P I, Korpi A M.Environ. Sci. Technol., 2009, 43(3): 941-947
16. [16]
  16 Andresen J, Bester K. Water Res., 2006, 40(3): 621-629
17. [17]
  17 Mihajlovic I, Miloradov M V, Fries E. Environ. Sci. Technol., 2011, 45(6): 2264-2269
18. [18]
  18 Martinez-Carballo E, Gonzalez-Barreiro C, Sitka A, Scharf S, Gans O. Environ. Sci. Technol., 2007, 388(1-3): 290-299
1. [1]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
2. [2]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
3. [3]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
4. [4]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
5. [5]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036
6. [6]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
7. [7]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
8. [8]
  Gaoyan Chen , Chaoyue Wang , Juanjuan Gao , Junke Wang , Yingxiao Zong , Kin Shing Chan . Heart to Heart: Exploring Cardiac CT. University Chemistry, 2024, 39(9): 146-150. doi: 10.12461/PKU.DXHX202402011
9. [9]
  Qianlang Wang , Jijun Sun , Qian Chen , Quanqin Zhao , Baojuan Xi . The Appeal of Organophosphorus Compounds: Clearing Their Name. University Chemistry, 2025, 40(4): 299-306. doi: 10.12461/PKU.DXHX202405205
10. [10]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
11. [11]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
12. [12]
  Haiyang Zhang , Yanzhao Dong , Haojie Li , Ruili Guo , Zhicheng Zhang , Jiangjiexing Wu . Exploring the Integration of Chemical Engineering Principle Experiment with Cutting-Edge Research Achievements. University Chemistry, 2024, 39(10): 308-313. doi: 10.12461/PKU.DXHX202405035
13. [13]
  Fan Wu , Wenchang Tian , Jin Liu , Qiuting Zhang , YanHui Zhong , Zian Lin . Core-Shell Structured Covalent Organic Framework-Coated Silica Microspheres as Mixed-Mode Stationary Phase for High Performance Liquid Chromatography. University Chemistry, 2024, 39(11): 319-326. doi: 10.12461/PKU.DXHX202403031
14. [14]
  Mengzhen JIANG , Qian WANG , Junfeng BAI . Research progress on low-cost ligand-based metal-organic frameworks for carbon dioxide capture from industrial flue gas. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 1-13. doi: 10.11862/CJIC.20240355
15. [15]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
16. [16]
  Qilong Fang , Yiqi Li , Jiangyihui Sheng , Quan Yuan , Jie Tan . Magical Pesticide Residue Detection Test Strips: Aptamer-based Lateral Flow Test Strips for Organophosphorus Pesticide Detection. University Chemistry, 2024, 39(5): 80-89. doi: 10.3866/PKU.DXHX202310004
17. [17]
  Jiaojiao Yu , Bo Sun , Na Li , Cong Wen , Wei Li . Improvement of Classical Organic Experiment Based on the “Reverse-Step Optimization Method”: Taking Synthesis of Ethyl Acetate as an Example. University Chemistry, 2025, 40(3): 333-341. doi: 10.12461/PKU.DXHX202405177
18. [18]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044
19. [19]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
20. [20]
  Zian Lin , Yingxue Jin . Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS) for Disease Marker Screening and Identification: A Comprehensive Experiment Teaching Reform in Instrumental Analysis. University Chemistry, 2024, 39(11): 327-334. doi: 10.12461/PKU.DXHX202403066

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(503)
HTML views(63)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142