Citation: HAN Fang, HU Yan-Yun, ZHANG Lei, SHENG Xuan, SUN Hao, SONG Wei, LV Ya-Ning, ZHENG Ping. Determination of Triazines Residues in Food Samples Using Dummy Molecularly Imprinted Solid Phase Extraction Based on Molecular Simulation[J]. Chinese Journal of Analytical Chemistry, ;2012, 40(11): 1648-1653. doi: 10.3724/SP.J.1096.2012.20196 shu

Determination of Triazines Residues in Food Samples Using Dummy Molecularly Imprinted Solid Phase Extraction Based on Molecular Simulation

HAN Fang ^1,2 ,
HU Yan-Yun ^1,2 ,
ZHANG Lei ^1,2 ,
SHENG Xuan ¹ ,
SUN Hao ¹ ,
SONG Wei ² ,
LV Ya-Ning ² ,
ZHENG Ping ^1,2,,

1.
¹ Anhui Entry-Exit Inspection and Quarantine Bureau, Hefei 230029, China;

Corresponding author: ZHENG Ping,
Received Date: 28 February 2012
Available Online: 24 May 2012

The molecularly imprinted polymers (MIPs) capable of extracting triazines from food samples were prepared by suspension polymerization using butylmelamine (BME) as template, methacrylic acid (MAA) as monomer and ethylene glycol dimethacrylate (EDMA) as cross-linker, respectively. Molecular modeling approach was used to screen the most suitable dummy template. The selective adsorption of MIPs was evaluated by high performance liquid chromatography. The synthesized MIPs were used as the solid phase extraction (SPE) materials. The optimum loading, washing and eluting conditions for molecularly imprinted solid phase extraction (MISPE) were established to obtain high selectivity and sensitivity. Compared with commercial SPE columns, MISPE exhibited selective binding properties for triazines, and the matrix effect was significantly decreased. The recoveries of all 10 triazines in matrix spiked samples were ranged from 87.8% to 105.2%, with the relative standard deviations (RSD) below 13% (n=6).
- Molecularly imprinted solid phase extraction,
- Dummy template,
- Molecular simulation,
- Triazines
1. [1]
  1 Barcelo D. J. Chromatogr. A, 1993, 643(1-2): 117-143
2. [2]
  2 QI Yan, ZHAN Chun-Rui, ZHANG Xin-Zhong, YANG Qiang. Chinese J. Anal. Chem., 2006, 34(6): 787-790
3. [3]
  祁彦, 占春瑞, 张新忠, 杨强. 分析化学, 2006, 34(6): 787-790
4. [4]
  3 WANG Ying, WANG Zi-Ming, REN Rui-Bing, XIAO Yao. Chinese J. Anal. Chem., 2010, 38(7): 979-983
5. [5]
  王影, 汪子明, 任瑞冰, 肖瑶. 分析化学, 2010, 38(7): 979-983
6. [6]
  4 LI Wei-Jian, NIE Zhi-Qiang, CAI Yan-Ming, LIU Xiao-Wei. J. Agro-Environment Science., 2009, 28(1): 211-215
7. [7]
  李卫建, 聂志强, 蔡彦明, 刘潇威. 农业环境科学学报, 2009, 28(1): 211-215
8. [8]
  5 HU Yu-Ling, ZHU Fei, LI Jia-Wei, LI Gong-Ke. Chinese J. Anal. Chem., 2009, 37(3): 466-470
9. [9]
  胡玉玲, 朱飞, 李家威, 李攻科. 分析化学, 2009, 37(3): 466-470
10. [10]
  6 Hu X G, Hu Y L, Li G K. J. Chromatogr. A, 2007, 1147(1): 1-9
11. [11]
  7 Koeber R, Fleischer C, Lanza F, Boos K S, Sellergren B,Barcelo D. Anal. Chem., 2001, 73(11): 2437-2444
12. [12]
  8 Yin J F, Meng Z H, Zhu Y S, Song M Y, Wang H L. Anal. Methods, 2011, 3: 173-180
13. [13]
  9 Yin J F, Meng Z H, Du M J, Liu C, Song M Y, Wang H L. J. Chromatogr. A, 2010, 1217(33): 5420-5426
14. [14]
  10 Zhang L, Han F, Hu Y Y, Zheng P, Sheng X, Sun H, Song W, Lv Y N. Anal. Chim. Acta, 2012, 10.1016/j. aca. 2012. 04. 008
15. [15]
  11 Determination of 450 Pesticides and Related Chemical Residues in Fruits and Vegetables-LC-MS-MS Method.National Standards of the People's Republic of China
16. [16]
  水果和蔬菜中405种农药及相关化学品残留量的测定. 中华人民共和国国家标准. GB/T 20769-2008
17. [17]
  12 Piletsky S A, Karim K, Piletska E V, Day C J, Freebairn K W, Legge C H, Turner A P F. Analyst, 2001, 126(10): 1826-1830
18. [18]
  13 Matsui J, Fujiwara K, Ugata S, Takeuchi T. J. Chromatogr. A, 2000, 889(1-2): 25-31
19. [19]
  14 Chapuis F, Pichon V, Lanza F, Sellergren B, Hennion M C. J. Chromatogr. B, 2004, 804(1): 93-101
20. [20]
  15 Orr A A. J. Paint Technol, 1975, 47(607): 45
21. [21]
  16 Matuszewski B K, Constanzer M L, Chavez-Eng C M. Anal. Chem., 2003, 75(13): 3019-3030
1. [1]
  Feng Zheng , Ruxun Yuan , Xiaogang Wang . “Research-Oriented” Comprehensive Experimental Design in Polymer Chemistry: the Case of Polyimide Aerogels. University Chemistry, 2024, 39(10): 210-218. doi: 10.12461/PKU.DXHX202404027
2. [2]
  Yaping Li , Sai An , Aiqing Cao , Shilong Li , Ming Lei . The Application of Molecular Simulation Software in Structural Chemistry Education: First-Principles Calculation of NiFe Layered Double Hydroxide. University Chemistry, 2025, 40(3): 160-170. doi: 10.12461/PKU.DXHX202405185
3. [3]
  Pingping Zhu , Yongjun Xie , Yuanping Yi , Yu Huang , Qiang Zhou , Shiyan Xiao , Haiyang Yang , Pingsheng He . Excavation and Extraction of Ideological and Political Elements for the Virtual Simulation Experiments at Molecular Level: Taking the Project “the Simulation and Computation of Conformation, Morphology and Dimensions of Polymer Chains” as an Example. University Chemistry, 2024, 39(2): 83-88. doi: 10.3866/PKU.DXHX202309063
4. [4]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
5. [5]
  Hujun Qian , Rui Shi , Guanglu Wu , Xuanbo Zhu . A Preliminary Study on the Development of a Virtual Simulation Platform for Polymer Physics Teaching and Its Teaching Practice. University Chemistry, 2025, 40(4): 147-153. doi: 10.12461/PKU.DXHX202409009
6. [6]
  Yuxia Luo , Xiaoyu Xie , Fangfang Chen . 药物递送魔法师——分子印迹聚合物. University Chemistry, 2025, 40(8): 202-210. doi: 10.12461/PKU.DXHX202409129
7. [7]
  Chengxiao Zhao , Zhaolin Li , Dongfang Wu , Xiaofei Yang . SBA-15 templated covalent triazine frameworks for boosted photocatalytic hydrogen production. Acta Physico-Chimica Sinica, 2026, 42(1): 100149-0. doi: 10.1016/j.actphy.2025.100149
8. [8]
  Xiaodong Chen , Yumin Zhang . An Improved Simulated Annealing Algorithm for Predicting the Molecular Formulas of Organic Compounds. University Chemistry, 2025, 40(9): 19-24. doi: 10.12461/PKU.DXHX202408095
9. [9]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
10. [10]
  Jiarong Feng , Yejie Duan , Chu Chu , Dezhen Xie , Qiu'e Cao , Peng Liu . Preparation and Application of a Streptomycin Molecularly Imprinted Electrochemical Sensor: A Suggested Comprehensive Analytical Chemical Experiment. University Chemistry, 2024, 39(8): 295-305. doi: 10.3866/PKU.DXHX202401016
11. [11]
  Laiying Zhang , Yinghuan Wu , Yazi Yu , Yecheng Xu , Haojie Zhang , Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, 2024, 39(4): 213-220. doi: 10.3866/PKU.DXHX202310126
12. [12]
  Yulian Hu , Xin Zhou , Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO₂ Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088
13. [13]
  Binbin Liu , Yang Chen , Tianci Jia , Chen Chen , Zhanghao Wu , Yuhui Liu , Yuhang Zhai , Tianshu Ma , Changlei Wang . Hydroxyl-functionalized molecular engineering mitigates 2D phase barriers for efficient wide-bandgap and all-perovskite tandem solar cells. Acta Physico-Chimica Sinica, 2026, 42(1): 100128-0. doi: 10.1016/j.actphy.2025.100128
14. [14]
  Jiayao Wang , Guixu Pan , Ning Wang , Shihan Wang , Yaolin Zhu , Yunfeng Li . Preparation of donor-π-acceptor type graphitic carbon nitride photocatalytic systems via molecular level regulation for high-efficient H₂O₂ production. Acta Physico-Chimica Sinica, 2025, 41(12): 100168-0. doi: 10.1016/j.actphy.2025.100168
15. [15]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
16. [16]
  Zhenhua Wang , Haoyang Feng , Xiaoyang Shao , Wenru Fan . Vitamins in Solid Propellants: Controlled Synthesis of Neutral Macromolecular Bonding Agents. University Chemistry, 2025, 40(4): 1-9. doi: 10.3866/PKU.DXHX202401007
17. [17]
  Qinhui Guan , Yuhao Guo , Na Li , Jing Li , Tingjiang Yan . Molecular sieve-mediated indium oxide catalysts for enhancing photocatalytic CO₂ hydrogenation. Acta Physico-Chimica Sinica, 2025, 41(11): 100133-0. doi: 10.1016/j.actphy.2025.100133
18. [18]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
19. [19]
  Yujie WANG , Laobang WANG , Zheng ZHANG , Qi LIU , Jianping LANG . Construction of W/Cu/S cluster-based supramolecular compounds via alkynyl/sulfur cycloaddition and their third-order nonlinear optical properties. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2069-2077. doi: 10.11862/CJIC.20250129
20. [20]
  Yajie Li , Bin Chen , Yiping Wang , Hui Xing , Wei Zhao , Geng Zhang , Siqi Shi . Inhibiting Dendrite Growth by Customizing Electrolyte or Separator to Achieve Anisotropic Lithium-Ion Transport: A Phase-Field Study. Acta Physico-Chimica Sinica, 2024, 40(3): 2305053-0. doi: 10.3866/PKU.WHXB202305053

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(678)
HTML views(35)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142