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Citation: HUANG Yisui, YANG Fafu, GUO Hongyu. Synthesis and Properties of Cellulose Resin Crosslinked with Perylene Tetracarboxylic Diimides[J]. Chinese Journal of Applied Chemistry, ;2014, 31(8): 892-900. doi: 10.3724/SP.J.1095.2014.30665 shu

Synthesis and Properties of Cellulose Resin Crosslinked with Perylene Tetracarboxylic Diimides

HUANG Yisui ^a ,
YANG Fafu ^b,c,, ,
GUO Hongyu ^b

1.
a College of Environmental Science and Engineering, Fujian Normal University, Fuzhou, 350007, China;
2.
b College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou, 350007, China;
3.
c Fujian Key Laboratory of Polymer Materials, Fujian Normal University, Fuzhou, 350007, China

Corresponding author: YANG Fafu,
Received Date: 30 December 2013
Available Online: 20 March 2014
Fund Project: 国家自然科学基金(20402002) (20402002)福建省自然科学基金(2011J01031)资助项目 (2011J01031)

The novel cellulose resin crosslinked with perylene tetracarboxylic diimides 3 was synthesized and its structure was characterized by elemental analysis,Fourier transform infrared spectroscopy(FT-IR) and scanning electron microscopy(SEM). Dye adsorption experiments of polymer 3 suggested that it exhibited excellent adsorption capacities for four tested dyes[orange G sodium salt(OG),brilliant ponceau 5R(BP),methylene blue(MB) and crystal violet(CV)]. The adsorption capacities for OG,BP,MB,CV were as high as 1.04,1.21,1.14 and 0.96 mmol/g,respectively. The adsorption processes obeyed a pseudo second-order model,followed the Langmuir isotherm equation,and were exothermic and spontaneous. The pH values between 2~12 had slight influences on adsorption capacities. The adsorption results indicated that the electrostatic action,hydrogen bond and π-π stacking action played important roles in adsorption processes.
- cellulose,
- perylene,
- adsorption,
- dye
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