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Citation: FENG Cuilan, XU Haiyun, LIU Lantao, WANG Jing, LIU Ying. Catalytic Synthesis of Diaryl Ethers with Magnetically Recoverable Fe₃O₄ Nanoparticles Under Solvent-free and Ligand-free Conditions[J]. Chinese Journal of Applied Chemistry, ;2014, 31(5): 536-540. doi: 10.3724/SP.J.1095.2014.30340 shu

Catalytic Synthesis of Diaryl Ethers with Magnetically Recoverable Fe₃O₄ Nanoparticles Under Solvent-free and Ligand-free Conditions

1.
College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu 476000, China

Corresponding author: FENG Cuilan,
Received Date: 8 July 2013
Available Online: 22 September 2013
Fund Project: 国家自然科学基金(201102087) (201102087)河南省科技厅科技攻关项目(112102210477) (112102210477)河南省青年骨干教师(2011GGJS-157)资助 (2011GGJS-157)

Magnetite nanoparticles as efficient catalyst for C——O cross-coupling reaction of aryl bromide with phenol under solvent-free and ligand-free conditions were described.Under the optimized conditions:130℃,48 h and 7% molar fraction of Fe₃O₄,the yield of diaryl ether reaches up to 94.7%.The separated magnetite nanoparticles catalyst can be recycled for 4 runs in the C——O cross-coupling reaction without significantly loss of catalytic activity.
- cross-coupling,
- magnetic Fe₃O₄ nanoparticles,
- diaryl ether,
- arylation,
- recyclability
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Catalytic Synthesis of Diaryl Ethers with Magnetically Recoverable Fe3O4 Nanoparticles Under Solvent-free and Ligand-free Conditions

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Catalytic Synthesis of Diaryl Ethers with Magnetically Recoverable Fe₃O₄ Nanoparticles Under Solvent-free and Ligand-free Conditions