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Citation: LUO Dong, GAO Meixiang, MAO Liqiu, YIN Dulin. Oxidation of Cyclohexylamine to Cyclohexanone Oxime Catalyzed by NaY Zeolite Moledular Sieves[J]. Chinese Journal of Applied Chemistry, ;2013, 30(12): 1443-1448. doi: 10.3724/SP.J.1095.2013.30073 shu

Oxidation of Cyclohexylamine to Cyclohexanone Oxime Catalyzed by NaY Zeolite Moledular Sieves

National & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China

Received Date: 29 January 2013
Revised Date: 27 March 2013

The liquid phase cyclohexyamine oxidation reaction to prepare cyclohexanone oxime on NaY zeolite catalyst was studied. The effects of oxidant and solvent on the reaction were investigated. The results show that NaY zeolite has the best catalytic performance when acetonitrile and hydrogen peroxide were used as solvent and oxidant respectively. An orthogonal experimental method to study the response of the optimum conditions was carried out. The results show that the effects of the amount of catalyst,the amount of solvent,reaction time,reaction temperature and amount of oxidant on the yield of cyclohexanone oxime decrease in turn. The optimal reaction conditions are as follows:0.3 g catalyst,V (cyclohexylamine):V (solvents):V (oxidants)=1:3:3,65℃ and 2 h.
- cyclohexylamine,
- oxidation,
- cyclohexanone oxime,
- hydrogen peroxide,
- NaY catalyst
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