引用本文:
杨建东, 王都留, 卢小泉. 不同类型卟啉自组装膜的制备及表征[J]. 应用化学,
2013, 30(3): 343-348.
doi:
10.3724/SP.J.1095.2013.20109
Citation: YANG Jiandong, WANG Duliu, LU Xiaoquan. Preparation and Characterization of Different Self-Assembled Porphyrin Monolayers[J]. Chinese Journal of Applied Chemistry, 2013, 30(3): 343-348. doi: 10.3724/SP.J.1095.2013.20109
Citation: YANG Jiandong, WANG Duliu, LU Xiaoquan. Preparation and Characterization of Different Self-Assembled Porphyrin Monolayers[J]. Chinese Journal of Applied Chemistry, 2013, 30(3): 343-348. doi: 10.3724/SP.J.1095.2013.20109
不同类型卟啉自组装膜的制备及表征
English
Preparation and Characterization of Different Self-Assembled Porphyrin Monolayers
Abstract:
Different self-assembled thiol-substituted porphyrin monolayers (TPPS1 and TPPS4) were prepared and characterized by means of UV-Vis,CV,EIS and XPS.The results showed that the self-assembled porphyrin monolayers have different configurations due to the different numbers of the thiol-substitute in porphyrin molecules.Therefore,these porphyrin monolayers showed different performance in catalysis.On the basis of those observations,we proposed a model for the assembling of multi-thiol substituted porphyrin into monolayer.The established method shows potential for building and developing functional self-assembled porphyrin monolayers in the application of bio-catalysis and optoelectronic devices.
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