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Citation: QIANG Xinxin, ZHAO Zhichao, SONG Fengling, PENG Xiaojun, FAN Jiangli. Preparation of Fluorescent Ultrafine Polymer Nanoparticles[J]. Chinese Journal of Applied Chemistry, ;2012, 29(6): 633-638. doi: 10.3724/SP.J.1095.2012.00383 shu

Preparation of Fluorescent Ultrafine Polymer Nanoparticles

1.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, China

Corresponding author: FAN Jiangli,
Received Date: 31 August 2011
Available Online: 28 October 2011
Fund Project: 国家自然科学基金(21136002,20725621,21076032,20923006) (21136002,20725621,21076032,20923006)国家重点基础研究发展计划(2009CB724706) (2009CB724706)中央高校基本科研业务费专项资金(DUT10LK05) (DUT10LK05)辽宁省教育厅科学研究基金(LS2010040)资助项目 (LS2010040)

A new polymerizable fluorescent dye with high fluorescence quantum yield(0.69) was synthesized.The dye possesses even better photo stability than commercial dye Rhodamine B.The fluorescent ultrafine polymer nanoparticles were obtained by emulsion polymerization initialized by redox initiator.The average diameter of the nanoparticles prepared by Triton X-100 as emulsifier and methyl methacrylate(MMA) as assistant emulsifier and monomer is 22 nm,while the diameter is about 150 nm without MMA.The benzyl chloride groups provide an easy way to further function.
- polymerizable dye,
- ultrafine polymer nanoparticles,
- photostability,
- dye leakage,
- anthrapyridone,
- emulsion polymerization
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