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Citation: ZHAO Qinqin, SHI Hongxin, WU Hongke, CHEN Lijun, XIANG Juping. Synthesis and Performance of Polyethylene Glycol p-Perfluorous Nonenyloxyphenyl Sulflonate Surfactant[J]. Chinese Journal of Applied Chemistry, ;2012, 29(8): 906-909. doi: 10.3724/SP.J.1095.2012.00379 shu

Synthesis and Performance of Polyethylene Glycol p-Perfluorous Nonenyloxyphenyl Sulflonate Surfactant

1.
Laboratory of Green Chemistry Synthesis-technology, College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032, China

Corresponding author: SHI Hongxin,
Received Date: 29 August 2011
Available Online: 21 November 2011
Fund Project: 浙江省科技厅创新团队资助项目(2011R09002-10) (2011R09002-10)

Polyethylene glycol p-perfluorous nonenyloxyphenyl sulflonates(PFNPS-PEG-n) were synthesized from p-perfluorous nonenyloxyphenylsulfonyl chloride(PFNPSC) and polyethylene glycol(PEG-n),and were characterized by IR and ¹⁹F NMR,respectively.The effects of average relative molecular mass of PEG-n and reaction time on alcoholysis were investigated.The performances of these surfactants such as surface tensions,foaming characterisitics and emulsifiabilities were studied.The surface activity of PFNPS-PEG-n synthesized from PEG-600 is the best,and the optimal reaction conditions are n(PFNPSC): n((PEG-600)=1: 1,reacts at 40℃ for 6~8 h in CCl₄ in the present of NEt₃.The critical micelle concentration(CMC) of PFNPS-PEG-600 is 0.56 g/L,and its γ_CMC is 19.1 mN/m;20 mL 1 g/L PFNPS-PEG-600 will produce 95 mL foam,and its half-life time is 75 s.Emulsifiability of PFNPS-PEG-1000 is the best among PFNPS-PEG-n.
- fluorocarbon surfactant,
- surface tensions,
- foaming characterisitics,
- emulsifiability
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