Home

Citation: ZENG Zhi, XIE Runqian, TAN Lixian, ZHANG Tao. GC-MS Analysis and Determination of Chemical Components of the Extracts from Ligusticum Chuanxiong Hort.by Steam Distillation and Supercritical CO₂ Extraction[J]. Chinese Journal of Applied Chemistry, ;2011, 28(8): 956-962. doi: 10.3724/SP.J.1095.2011.00598 shu

GC-MS Analysis and Determination of Chemical Components of the Extracts from Ligusticum Chuanxiong Hort.by Steam Distillation and Supercritical CO₂ Extraction

ZENG Zhi ^a,b,, ,
XIE Runqian ^a ,
TAN Lixian ^a ,
ZHANG Tao ^c

1.
a School of Chemistry and Environment, South China Normal University, Guangzhou 510631;
2.
b Faculty of Bioresource Sciences, Akita Prefectural University, Akita 010-0195, Japan;
3.
c Institute of Opto-electronic Materials and Technology, South China Normal University, Guangzhou 510631

Corresponding author: ZENG Zhi,
Received Date: 11 October 2010
Available Online: 28 December 2010
Fund Project: 广东省科技计划重大专项(A301020101) (A301020101)广东省自然科学基金(01142)资助项目 (01142)

The chemical components of Ligusticum chuanxiong Hort.were extracted by steam distillation and supercritical CO₂ extraction,and analyzed by combined capillary gas chromatography-mass spectrometry(GCMS).Thirty and thirty four compounds were identified,respectively,and their relative contents were determined.This study revealed that the major components of L.chuanxiong Hort.by steam distillation and supercritical CO₂ extraction were(Z)-ligustilide.The chemical components from L.chuanxiong Hort.extracted by supercritical CO₂ extraction possessed more bioactive substances such as butylphthalide,butylidene phthalide,senkyunolide A,(Z)-ligustilide,(E)-ligustilide and senkyunolide I.However,the components from L.chuanxiong Hort.extracted by steam distillation contained more terpenes except for the bioactive substances.Therefore,supercritical CO₂ extraction has more productivity than steam distillation for the extraction of the bioactive substances from L.chuanxiong Hort.Through the interpretation and summarization of the regular patterns of the lactones with unsaturated and saturated side chains from L.chuanxiong Hort.,the structures of the lactones with unsaturated side chain such as(Z)-ligustilide,(E)-ligustilide,butylidene phthalide and senkyunolide I as well as the lactones with saturated side chain such as butylphthalide and senkyunolide A have been determined.
- Ligusticum chuanxiong Hort.,
- steam distillation,
- supercritical CO₂ extraction,
- mass spectrometry,
- chemical component,
- structure determination
1. [1]
  Wei Shao , Wanqun Zhang , Pingping Zhu , Wanqun Hu , Qiang Zhou , Weiwei Li , Kaiping Yang , Xisheng Wang . Design and Practice of Ideological and Political Cases in the Course of Instrument Analysis Experiment: Taking the GC-MS Experiment as an Example. University Chemistry, 2024, 39(2): 147-154. doi: 10.3866/PKU.DXHX202309048
2. [2]
  Weiliang Wang , Zijing Yu , Jingyuan Li , Hong Shang . The Debate between Traditional Chinese Medicine and Western Medicine. University Chemistry, 2024, 39(9): 109-114. doi: 10.12461/PKU.DXHX202402001
3. [3]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
4. [4]
  Yuan Zhuang , Wenhui Li , Jie Li . Curriculum Reform of “Chemical Composition Analysis of Materials” under Background of First-Class Discipline Construction. University Chemistry, 2025, 40(5): 283-290. doi: 10.12461/PKU.DXHX202407070
5. [5]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Research on Cu-Based and Pt-Based Catalysts for Hydrogen Production through Methanol Steam Reforming. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-0. doi: 10.1016/j.actphy.2025.100049
6. [6]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
7. [7]
  Yao Chen , Bing Peng , Yuchi Zhao , Xiang Xiao , Tong Wang . Professional Synthesis and Innovation Experiment: Rapid Identification Experiment of Tea Grades Based on Colorimetric Sensor Array and Chemometrics. University Chemistry, 2026, 41(2): 366-374. doi: 10.12461/PKU.DXHX202503043
8. [8]
  Zian Lin , Yingxue Jin . Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS) for Disease Marker Screening and Identification: A Comprehensive Experiment Teaching Reform in Instrumental Analysis. University Chemistry, 2024, 39(11): 327-334. doi: 10.12461/PKU.DXHX202403066
9. [9]
  Xiaoqi LAN , Wei LI , Long JING , Mengyu SU , Xiaoling LUO , Zheng LIU , Qun TANG . Synthesis, crystal structure, and spectral properties of transition-metal-organic frameworks based on thiophene carboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 309-316. doi: 10.11862/CJIC.20250212
10. [10]
  Yue-Zhou Zhu , Kun Wang , Shi-Sheng Zheng , Hong-Jia Wang , Jin-Chao Dong , Jian-Feng Li . Application and Development of Electrochemical Spectroscopy Methods. Acta Physico-Chimica Sinica, 2024, 40(3): 2304040-0. doi: 10.3866/PKU.WHXB202304040
11. [11]
  Yunying Wu , Zhilan Mo , Xue Zhou , Yu Yuan , Yunfei Ma , Jing Chen , Gang Tang . Empowering the Digital Transformation of Organic Chemistry Experiments with Sensing Technology: A Case of Atmospheric Distillation, Vacuum Distillation and Fractionation. University Chemistry, 2025, 40(11): 310-317. doi: 10.12461/PKU.DXHX202503078
12. [12]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-0. doi: 10.1016/j.actphy.2025.100054
13. [13]
  Houjin Li , Shuanglian Cai , Yuan Zheng , Zhanxiang Liu , Chengshan Yuan , Lin Wu , Guangao Yu , Jie Han , Qingwen Liu , Xin Du , Ying Xiong , Qihan Zhang , Xingwen Sun , Jianrong Zhang , Shuyong Zhang . Basic Operations and Standardization Suggestions for Organic Chemistry Distillation Experiments. University Chemistry, 2025, 40(5): 40-54. doi: 10.12461/PKU.DXHX202411053
14. [14]
  Yajun Jian , Quan Gu , Quanguo Zhai . Chemistry Frontiers-Intelligent Educational Technologies Collaborate to Construct CO₂ Teaching Units. University Chemistry, 2026, 41(2): 82-94. doi: 10.12461/PKU.DXHX202503014
15. [15]
  Xianyong Lu , Tao Hu . Developing an Innovative Inorganic Chemistry Teaching Model Based on Aerospace Specialty Characteristics. University Chemistry, 2025, 40(7): 127-131. doi: 10.12461/PKU.DXHX202409037
16. [16]
  Yan Zhang , Xiaoyan Cao , Yiming Li , Shuwei Xia , Mutai Bao . Comparison of Electrolyte Solutions Section in Physical Chemistry Textbooks at Home and Abroad. University Chemistry, 2025, 40(9): 303-309. doi: 10.12461/PKU.DXHX202502027
17. [17]
  Feifan Zhao , Feiyan Xu , Jiaguo Yu . Interfacial stabilization of alkali metal oxides on carbon spheres for high-performance CO₂ chemisorption. Acta Physico-Chimica Sinica, 2026, 42(5): 100234-0. doi: 10.1016/j.actphy.2025.100234
18. [18]
  Zongyuan Chen , ChunSheng Shi , Yiwen Li , Ganlin Zu , Qiang Jin , Haishan Wang , Fujun Wang , Dekun Yan , Zhijun Guo , Wangsuo Wu . Measurement of Uranium Isotopes in Environmental Water Samples by Alpha-Spectroscopy: Design of an Undergraduate Radiochemistry Experiment. University Chemistry, 2025, 40(4): 353-358. doi: 10.12461/PKU.DXHX202406103
19. [19]
  Lingbang Qiu , Jiangmin Jiang , Libo Wang , Lang Bai , Fei Zhou , Gaoyu Zhou , Quanchao Zhuang , Yanhua Cui . In Situ Electrochemical Impedance Spectroscopy Monitoring of the High-Temperature Double-Discharge Mechanism of Nb₁₂WO₃₃ Cathode Material for Long-Life Thermal Batteries. Acta Physico-Chimica Sinica, 2025, 41(5): 100040-0. doi: 10.1016/j.actphy.2024.100040
20. [20]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . Electrochemical CO₂ Reduction to C₂₊ Products with Ampere-Level Current on Carbon-Modified Copper Catalysts. Acta Physico-Chimica Sinica, 2025, 41(3): 100024-0. doi: 10.3866/PKU.WHXB202404012

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(869)
HTML views(191)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return

GC-MS Analysis and Determination of Chemical Components of the Extracts from Ligusticum Chuanxiong Hort.by Steam Distillation and Supercritical CO2 Extraction

Metrics

通讯作者: 陈斌, bchen63@163.com

GC-MS Analysis and Determination of Chemical Components of the Extracts from Ligusticum Chuanxiong Hort.by Steam Distillation and Supercritical CO₂ Extraction