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Citation: QU Guangmiao, WEI Jijun, YU Tao, DING Wei, SUN Ying, SHI Peng, LIU Hongbin, DONG Zhilong. Characterization and Surface Property of A Series of Sulfo-butane Betaines[J]. Chinese Journal of Applied Chemistry, ;2011, 28(6): 716-721. doi: 10.3724/SP.J.1095.2011.00438 shu

Characterization and Surface Property of A Series of Sulfo-butane Betaines

1.
College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318

Corresponding author: YU Tao,
Received Date: 29 July 2010
Available Online: 27 September 2010
Fund Project: 黑龙江省大庆市高新区创新基金(QGX08YF034)资助项目 (QGX08YF034)

Three kinds of sulfo-butane betaines(SB_m-4) are characterized by FT-IR,¹H NMR and elemental analysis.Surface property,foaming property and emulsifying property of these compounds are studied.The results show that the critical micelle concentration(cmc) for SB_12-4 is 2.20×10-3 mol/L,γ_cmc is 31.48 mN/m;while the cmc for SB_14-4 is 2.80×10^-4 mol/L,γ_cmc is 29.68 mN/m;and the cmc for SB_16-4 is 2.30×10^-5 mol/L,γ_cmc is 32.06 mN/m.The cmc decreases for the three kinds of sulfo-butane betaines as the alkyl chain length increases,while γ_cmc first decreases and then increases.As the mass concentration of three kinds of surfactants raised,the foaming power increased firstly,and reached to a certain value essentially unchanged.The foam stability was enhanced gradually with increasing the concentration.As the temperature increased,the foaming power was heightened slowly,while foam stability decreased.As the concentration was increased,the emulsifying power of three kinds of surfactants increased firstly and then decreased.
- sulfo-butane betaines,
- surface property,
- foaming property,
- emulsifying property
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