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Citation: LIU Shangchun, HUANG Yawen, YANG Junxiao, ZHU Fanghua, LI Bo, ZHANG Lin. New Route to Synthesis of 1,2-Diaryl Ethylene Derivatives by Heck Reaction[J]. Chinese Journal of Applied Chemistry, ;2011, 28(5): 526-530. doi: 10.3724/SP.J.1095.2011.00391 shu

New Route to Synthesis of 1,2-Diaryl Ethylene Derivatives by Heck Reaction

LIU Shangchun ^a ,
HUANG Yawen ^a ,
YANG Junxiao ^a,c,, ,
ZHU Fanghua ^b ,
LI Bo ^b ,
ZHANG Lin ^b

1.
a School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010;
2.
b Chinese Academy of Engineering Physics, Mianyang 621900;
3.
c State Key Laboratory Cultivation Base for Nonmetal Composite and Functional Materials, Southwest University of Science and Technology, Mianyang 621010

Corresponding author: YANG Junxiao,
Received Date: 2 July 2010
Available Online: 26 August 2010
Fund Project: 国家自然科学基金委员会-中国工程物理研究院联合资金资助项目(NSFC-NSAF10976024) (NSFC-NSAF10976024)

Heck reaction was employed to synthesize stilbene derivatives by utilizing 1,3-divinyl-1,1,3,3-tetramethyldisiloxane(DVS) as the ethylene source.The effects of the starting material molar ratio,reaction temperature and reaction time on the yield were investigated.A possible reaction mechanism was proposed.The results show that in DMF/H₂O at 120℃,with the starting material molar ratio of R-Br:DVS at 5:1,and reaction time=48 h,the reaction produces 4-vinyl-bis-benzocyclobutene(V-bisBCB) and 1,2-diphenylethene(V-bisPh) with a yield of 45.1% and 48.6%,respectively.
- diaryl ethylene derivatives,
- Heck reaction,
- divinyltetramethyldisiloxane
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