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Citation: LU Qi, WANG Xianhong, WANG Fosong. Synthesis of Ferrocene-based Oligo(p-phenylene ethynylene)s Molecular Wires[J]. Chinese Journal of Applied Chemistry, ;2011, 28(2): 136-141. doi: 10.3724/SP.J.1095.2011.00318 shu

Synthesis of Ferrocene-based Oligo(p-phenylene ethynylene)s Molecular Wires

LU Qi ^a,b ,
WANG Xianhong ^a,, ,
WANG Fosong ^a

1.
a Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022;
2.
b Graduate School of Chinese Academy of Sciences, Beijing

Corresponding author: WANG Xianhong,
Received Date: 28 May 2010
Available Online: 25 July 2010
Fund Project: 国家自然科学基金(20225414)资助项目 (20225414)

Three novel ferrocene-based oligo(phenylene ethynylene)s molecular wires were prepared by the Sonogashira coupling reaction of 1,1'-diiodoferrocene with different acetylenic compounds.The structures of all the products were confirmed by ¹H NMR,¹³C NMR and MS.The electronic structures of these molecular wires were forecasted by a quantum chemistry calculation,which indicated that they might contain favorable charge transport properties due to their abnormal LUMO energy level continuous attenuation.
- ferrocene,
- oligo (phenylene ethynylene) s,
- molecular wires
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