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Citation: LI Haichao, LIU Jinyan, ZHANG Yingchun. Interaction of Sodium Dodecyl Benzene Sulfonate and TritonX-100 Studied by Intrinsic Fluorescence[J]. Chinese Journal of Applied Chemistry, ;2011, 28(1): 113-117. doi: 10.3724/SP.J.1095.2011.00243 shu

Interaction of Sodium Dodecyl Benzene Sulfonate and TritonX-100 Studied by Intrinsic Fluorescence

1.
a College of Chemistry and Chemical Engineering, Inner Mongolia University of Science & Technology, Baotou 014010;
2.
b Department of Material Science and Technology, Northeast Forestry University, Harbin

Corresponding author: LIU Jinyan,
Received Date: 26 April 2010
Available Online: 6 July 2010
Fund Project: 内蒙古高等学校科学研究基金(NJZY07104) (NJZY07104)内蒙古自然科学基金(2008080404MS0210) (2008080404MS0210)黑龙江省自然科学基金项目(4240065-4-08163)资助项目 (4240065-4-08163)

Using the chromophore base of benzene sulfonate in sodium dodecyl benzene sulfonate(SDBS), the aggregation property of SDBS with non-ionic surfactant TritonX-100 in aqueous solution was studied by fluorescence. Results show there are two turning points in the variation curve of fluorescence intensity I as a function of concentration, which is the critical micelle concentration and the concentration at which the micelle shape changed, respectively. The interaction parameter β^M between SDBS and TritonX-100 was calculated by the formula of mixed micelle interaction. The results show there is synergism and strong interaction between them.
- intrinsic fluorescence,
- interaction,
- mixed micelle,
- critical micelle concentration,
- surface tension
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