Home

Citation: ZHANG Jin-Yan, XIAO Xiao-Ming, JIANG Yan, TAN Nian-Yuan. Synthesis of Chromium(Ⅲ) Complex of 2,6-Di(2'-imidazoline-2'-yl) Pyridine and Its Interaction with DNA[J]. Chinese Journal of Applied Chemistry, ;2010, 27(9): 1032-1037. doi: 10.3724/SP.J.1095.2010.90729 shu

Synthesis of Chromium(Ⅲ) Complex of 2,6-Di(2'-imidazoline-2'-yl) Pyridine and Its Interaction with DNA

a. College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081;
b. College of Chemistry and Chemical Engineering, Hunan Institute of Engineering, Xiangtan

Received Date: 6 November 2009
Revised Date: 29 January 2010

2,6-Di(2'-imidazoline-2'-yl) pyridine(L) was synthesized from pyridine 2,6-dicarboxylic acid and ethylenediamine under microwave irradiation without catalyst.Its chromium complex[CrL₂] [NO₃]₃ was synthesized by the conventional method.The complex was characterized by IR spectrometry,elemental analysis,¹H NMR,TG-DSC and molar conductivity.The bindings of these two compounds to DNA were investigated by UV spectrometry and viscosity measurement.It is believed that the ligand may bind to DNA by hydrogen bonding and groove-face binding and the complex bind to DNA by hydrogen bonding and external electrostatic binding.The calculation results from density functional theory (DFT) with hybrid functional B3LYP is good agreement with the experimental phenomena.
- di(imidazolineyl)pyridine,
- chromium(Ⅲ) complex,
- DNA,
- microwave irradiation,
- DFT
1. [1]
  Xiaofen GUAN , Yating LIU , Jia LI , Yiwen HU , Haiyuan DING , Yuanjing SHI , Zhiqiang WANG , Wenmin WANG . Synthesis, crystal structure, and DNA-binding of binuclear lanthanide complexes based on a multidentate Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2486-2496. doi: 10.11862/CJIC.20240122
2. [2]
  Yingyue ZHANG , Liuqing KANG , Yating YANG , Xiaofen GUAN , Wenmin WANG . Crystal structure and antibacterial activity of two Gd₂ complexes based on polydentate Schiff-base ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1867-1877. doi: 10.11862/CJIC.20250100
3. [3]
  Tsegaye Tadesse Tsega , Jiantao Zai , Chin Wei Lai , Xin-Hao Li , Xuefeng Qian . Earth-abundant CuFeS2 nanocrystals@graphite felt electrode for high performance aqueous polysulfide/iodide redox flow batteries. Chinese Journal of Structural Chemistry, 2024, 43(1): 100192-100192. doi: 10.1016/j.cjsc.2023.100192
4. [4]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-0. doi: 10.3866/PKU.WHXB202312010
5. [5]
  Rohit Kumar , Anita Sudhaik , Aftab Asalam Pawaz Khan , Van Huy Neguyen , Archana Singh , Pardeep Singh , Sourbh Thakur , Pankaj Raizada . Designing tandem S-scheme photo-catalytic systems: Mechanistic insights, characterization techniques, and applications. Acta Physico-Chimica Sinica, 2025, 41(11): 100150-0. doi: 10.1016/j.actphy.2025.100150
6. [6]
  Ya Ren , Cong Zhang , Haiyan Wang , Jin-Xia Liang , Chun Zhu , Han-Shi Hu , Jun Li . Defective Ru1@Mo2COx Single-Atom Catalyst for Efﬁcient Thermal Catalysis for Ammonia Synthesis. Chinese Journal of Structural Chemistry, 2025, 44(8): 100649-100649. doi: 10.1016/j.cjsc.2025.100649
7. [7]
  Honglin Chen , Rupeng Wang , Zixiang He , Shih-Hsin Ho . Data-driven insights into nonradical activation mechanisms for biochar inverse design: A synergistic approach using DFT and machine learning with meta-analysis. Chinese Chemical Letters, 2026, 37(2): 111372-. doi: 10.1016/j.cclet.2025.111372
8. [8]
  Chunyan Yang , Qiuyu Rong , Fengyin Shi , Menghan Cao , Guie Li , Yanjun Xin , Wen Zhang , Guangshan Zhang . Rationally designed S-scheme heterojunction of BiOCl/g-C₃N₄ for photodegradation of sulfamerazine: Mechanism insights, degradation pathways and DFT calculation. Chinese Chemical Letters, 2024, 35(12): 109767-. doi: 10.1016/j.cclet.2024.109767
9. [9]
  Run-Han Li , Tian-Yi Dang , Wei Guan , Jiang Liu , Ya-Qian Lan , Zhong-Min Su . Evolution exploration and structure prediction of Keggin-type group IVB metal-oxo clusters. Chinese Chemical Letters, 2024, 35(5): 108805-. doi: 10.1016/j.cclet.2023.108805
10. [10]
  Chaozheng He , Jia Wang , Ling Fu , Wei Wei . Nitric oxide assists nitrogen reduction reaction on 2D MBene: A theoretical study. Chinese Chemical Letters, 2024, 35(5): 109037-. doi: 10.1016/j.cclet.2023.109037
11. [11]
  Ting-Ting Huang , Jin-Fa Chen , Juan Liu , Tai-Bao Wei , Hong Yao , Bingbing Shi , Qi Lin . A novel fused bi-macrocyclic host for sensitive detection of Cr₂O₇²⁻ based on enrichment effect. Chinese Chemical Letters, 2024, 35(7): 109281-. doi: 10.1016/j.cclet.2023.109281
12. [12]
  Sanmei Wang , Yong Zhou , Hengxin Fang , Chunyang Nie , Chang Q Sun , Biao Wang . Constant-potential simulation of electrocatalytic N₂ reduction over atomic metal-N-graphene catalysts. Chinese Chemical Letters, 2025, 36(3): 110476-. doi: 10.1016/j.cclet.2024.110476
13. [13]
  Sanmei Wang , Dengxin Yan , Wenhua Zhang , Liangbing Wang . Graphene-supported isolated platinum atoms and platinum dimers for CO₂ hydrogenation: Catalytic activity and selectivity variations. Chinese Chemical Letters, 2025, 36(4): 110611-. doi: 10.1016/j.cclet.2024.110611
14. [14]
  Chen Chen , Jinzhou Zheng , Chaoqin Chu , Qinkun Xiao , Chaozheng He , Xi Fu . An effective method for generating crystal structures based on the variational autoencoder and the diffusion model. Chinese Chemical Letters, 2025, 36(4): 109739-. doi: 10.1016/j.cclet.2024.109739
15. [15]
  Wenzheng Chen , Weiyun Chen , Bin Chen , Mingbao Feng . Deciphering the electron-shuttling role of iron(Ⅲ) porphyrin in modulating the reductive UV/S(Ⅳ) system into the oxidative strategy for micropollutant abatement. Chinese Chemical Letters, 2025, 36(10): 110743-. doi: 10.1016/j.cclet.2024.110743
16. [16]
  Yu Su , Jinbo Hu , Laiqiang Xu , Xinwen Jiang , Gonggang Liu , Yuanjuan Bai , Yuanyuan Liao , Shanshan Chang , Xiaowei Cheng . Tannin-derived sulfur-doped carbon with tunable porosity and dilated interlayer spacing for reversible Na-ion diffusion. Chinese Chemical Letters, 2026, 37(2): 111210-. doi: 10.1016/j.cclet.2025.111210
17. [17]
  Xinwan Zhao , Yue Cao , Minjun Lei , Zhiliang Jin , Tsubaki Noritatsu . Constructing S-scheme heterojunctions by integrating covalent organic frameworks with transition metal sulfides for efficient noble-metal-free photocatalytic hydrogen evolution. Acta Physico-Chimica Sinica, 2025, 41(12): 100152-0. doi: 10.1016/j.actphy.2025.100152
18. [18]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258
19. [19]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
20. [20]
  Jia JI , Tengqi YAO , Wenqian DENG , Wenjing SHI , Xuan LÜ , Lin TIAN , Xiaoyan XIN , Yinling HOU . Structures, antibacterial activities, and interactions with DNA of two nickel complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 78-86. doi: 10.11862/CJIC.20250141

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(452)
HTML views(21)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return