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Citation: RONG Li-Xia, HE Kai, FANG Yan-Xiong, JI Hong-Bing, ZHANG Kun. Oxidation of Benzyl Alcohol Catalyzed by Chloridized Metallic Porphyrin Immobilized in Ionic Liquid[J]. Chinese Journal of Applied Chemistry, ;2010, 27(10): 1124-1128. doi: 10.3724/SP.J.1095.2010.90396 shu

Oxidation of Benzyl Alcohol Catalyzed by Chloridized Metallic Porphyrin Immobilized in Ionic Liquid

a. Faculty of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006;
b. Guangdong Maoming Huayue Group Co., Ltd, Maoming;
c. College of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510006

Received Date: 11 June 2009
Revised Date: 25 December 2009

The direct oxidation of benzyl alcohol to phenyl aldehyde was studied with chloridized metallic porphyrin(MnTPPCl)/ionic liquid(ILs)/oxidant catalysts. The effects of temperature,MnTPPCl,various oxidation agents and the role of axial ligands on the yield were examined. The results showed that the yield and the selectivity of phenyl aldehyde can be both more than 99% in half an hour under the novel catalytic system MnTPPCl/[Bmim]HSO₄/K₂S₂O₈. The catalytic system without any organic solvents can be reused for many times and get a good performance.
- metallic porphyrin,
- ionic liquids,
- benzyl alcohol,
- catalytic oxidation
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