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Citation: CAO Jie, CUI Yi, LIU Shu-Ying. Possible Formation Mechanism of Chlorobenzenes' Pollutants in Upper Atmosphere[J]. Chinese Journal of Applied Chemistry, ;2010, 27(3): 249-256. doi: 10.3724/SP.J.1095.2010.90383 shu

Possible Formation Mechanism of Chlorobenzenes' Pollutants in Upper Atmosphere

CAO Jie ^a, ,
CUI Yi ^a ,
LIU Shu-Ying ^b

a. Department of Chemistry, Beijing Institute of Technology, Beijing;
b. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 8 June 2009
Revised Date: 20 August 2009

Research on the gas-phase radical/ion chemistry was briefly summarized.Emphasis was given to the application of mass spectrometric technique to ion-molecule reactions between halocarbocations and aromatic compounds which gave rise to chlorobenzenes as one of the targeted products.That chlorobenzenes were readily formed in the mass spectrometer implied that chlorobenzenes in the atmosphere should not exclude the possibility of ion/radical chemistry reactions.The environmental significance of such reactions was also explored.
- chlorobenzenes,
- mass spectrometry,
- gas phase ion-molecule reactions
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