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Citation: CHEN Dan-Yun, ZHOU Hui, YANG Xiao-Ke, HE Jian-Ying. Application of Recycled Lamp Tungsten Filament as Catalyst in the Oxidation of Cyclohexanone to Adipic Acid by H₂O₂[J]. Chinese Journal of Applied Chemistry, ;2010, 27(11): 1282-1285. doi: 10.3724/SP.J.1095.2010.00015 shu

Application of Recycled Lamp Tungsten Filament as Catalyst in the Oxidation of Cyclohexanone to Adipic Acid by H₂O₂

Institute of Fine Chemistry and Engineering, Henan University, Kaifeng 475004

Received Date: 7 January 2010
Revised Date: 11 March 2010

Using recycled lamp tungsten filament as the precursor of catalyst,adipic acid was synthesized from the oxidation of cyclohexanone by 30% H₂O₂ without the presence of any organic solvent,acidic additives and phase transfer agents.The IR and TG results indicate that nascent peroxotungstic acid is the active catalytic component obtained from the oxidation of recycled lamp tungsten filament by H₂O₂.It converts to tungstic acid finally.After 6h refluxing,a 63.7% yield of adipic acid could be attained using the above catalyst in optimized reaction system consisting of 100 mmol of cyclohexanone in 50 mL 30% H₂O₂,and with 1.5% molar fraction of catalyst in cyclohexanone.Under identical conditions the yield is 10%~18% higher than those from using tungstic acid or WO₃ as the catalyst.
- recycled lamp tungsten filament,
- nascent peroxotungstic acid,
- catalytic oxidation,
- adipic acid,
- cyclohexanone
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Application of Recycled Lamp Tungsten Filament as Catalyst in the Oxidation of Cyclohexanone to Adipic Acid by H2O2

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通讯作者: 陈斌, bchen63@163.com

Application of Recycled Lamp Tungsten Filament as Catalyst in the Oxidation of Cyclohexanone to Adipic Acid by H₂O₂