Citation: Tian-hua YANG, Jia-xing LIU, Bing-shuo LI, Ying-mei ZHAI, Jian WANG, Bo-lin TONG. Effect of Ca modified HZSM-5 zeolites on catalytic pyrolysis of oil shale[J]. Journal of Fuel Chemistry and Technology, ;2021, 49(2): 137-144. doi: 10.19906/j.cnki.JFCT.2021033 shu

Effect of Ca modified HZSM-5 zeolites on catalytic pyrolysis of oil shale

College of Energy and Environment, Shenyang Aerospace University, Shenyang 110136, China

Corresponding author: Tian-hua YANG, thyang@sau.edu.cn
Received Date: 11 December 2019
Revised Date: 17 November 2020

Figures(8)

The catalytic behaviors of Ca-modified HZSM-5 during oil shale pyrolysis process were investigated in a tubular rector and by TG-MS-FTIR. The physicochemical properties of the molecular sieve were characterized by BET, NH₃-TPD, and TG. The results show that the molecular sieve can significantly increase yields of C₁₋₄ aliphatic hydrocarbons and reduce their evolution temperatures. After modified, Ca/HZSM-5 can reduce yields of CO₂, increase yields of shale oil and decrease lengths of aliphatic chains in shale oil. But Ca/HZSM-5 has a strong catalytic effect on aromatization. Brönsted acid sites have an obvious catalytic effect on aliphatic hydrocarbons, while Lewis acid sites are more targeted at aromatization process of pyrolysis products.
- oil shale,
- catalytic pyrolysis,
- HZSM-5,
- metal modified.
1. [1]
  YOU Y Y, HAN X X, WANG X Y, JIANG X M. Evolution of gas and shale oil during oil shale kerogen pyrolysis based on structural characteristics[J]. J Anal Appl Pyrolsis,2019,138:203−210.
2. [2]
  TARIK S, LIN Q Y, BRANKOB, MARTIN J B. Microstructural imaging and characterization of oil shale before and after pyrolysis[J]. Fuel,2017,197:562−574.
3. [3]
  LIU T L, CAO J P, ZHAO X, WANG J, REN X, FAN X, ZHAO Y, WEI X. In situ upgrading of Shengli lignite pyrolysis vapors over metal-loaded HZSM-5 catalyst[J]. Fuel Process Technol,2017,160:19−26.
4. [4]
  SHI W J, WANG Z, SONG W L, LI S G, LI X Y. Pyrolysis of Huadian oil shale under catalysis of shale ash[J]. J Anal Appl Pyrolsis,2017,123:160−164.
5. [5]
  ZHANG H, LIU J, KANG Z Q, YANG D. Experimental research of the pyrolytic properties and mineral components of Bogda oil shale, China[J]. Oil Shale,2018,35(3):214.
6. [6]
  CHEN H, CHENG H, ZHOU F, CHEN K Q, QIAO K, LU X Y, OUYANG P K, FU J. Catalytic fast pyrolysis of rice straw to aromatic compounds over hierarchical HZSM-5 produced by alkali treatment and metal-modification[J]. J Anal Appl Pyrolsis,2018,131:76−84.
7. [7]
  ZHANG C D, GEUNJAE K, HAEGU P, KIWON J, LEE Y, SEOK C K, SUNGTAK K. Light hydrocarbons to BTEX aromatics over hierarchical HZSM-5: Effects of alkali treatment on catalytic performance[J]. Microporous Mesoporous Mater,2019,276:292−301.
8. [8]
  ZHANG Z Z, CHANG H, GAO T, ZHANG J B, SUN M, XU L, MA X X. Catalytic upgrading of coal pyrolysis volatiles over metal-loaded HZSM-5 catalysts in a fluidized bed reactor[J]. J Anal Appl Pyrolsis,2019,139:31−39.
9. [9]
  DAI M Q, YU Z S, FANG S W, MA X Q. Behaviors, product characteristics and kinetics of catalytic co-pyrolysis spirulina and oil shale[J]. Energ Convers Manage,2019,192:1−10.
10. [10]
  ZHANG B, ZHONG Z P, CHEN P, RUAN R. Microwave-assisted catalytic fast co-pyrolysis of Ageratinaadenophora and kerogen with CaO and ZSM-5[J]. J Anal Appl Pyrolsis,2017,127:246−257.
11. [11]
  GU B, CAO J P, WEI F, ZHAO X Y, REN X Y, ZHU C, GUO Z X, BAI J, SHEN W Z, WEI X Y. Nitrogen migration mechanism and formation of aromatics during catalytic fast pyrolysis of sewage sludge over metal-loaded HZSM-5[J]. Fuel,2019,244:151−158.
12. [12]
  CHEN L, ZENG C, GUO X, MAO Y, ZHANG Y, ZHANG X, LI W H, LONG Y, ZHU H, B EITENEER, VLADIMIR M Z. Gas evolution kinetics of two coal samples during rapid pyrolysis[J]. Fuel Process Technol,2010,91:848−852.
13. [13]
  SHI L, LIU Q Y, ZHOU B, GUO X J, LI Z K, CHENG X J, YANG R, LIU Z Y. Interpretation of methane and hydrogen evolution in coal pyrolysis from the bond cleavage perspective[J]. Energy Fuels,2017,31(1):429−437.
14. [14]
  PORADA S. The reactions of formation of selected gas products during coal pyrolysis[J]. Fuel,2004,83:1191−1196.
15. [15]
  HOU X, NI N, WANG Y, ZHU W J, QIU Y, DIAO Z H, LIU G Z, ZHANG X W. Roles of the free radical and carbenium ion mechanisms in pentane cracking to produce light olefins[J]. J Anal Appl Pyrolsis,2019,138:270−280.
16. [16]
  ILIOPOULOU E F, STEFANIDIS S D, KALOGIANNIS K G, DELIMITIS A, LAPPAS A A, TRIANTAFYLLIDIS K S. Catalytic upgrading of biomass pyrolysis vapors using transition metal-modified ZSM-5 zeolite[J]. Appl Catal B: Environ,2012,127:281−290.
17. [17]
  MA YUE, LI SHU-YUAN, WANG JUAN, FANG CHAO-HE. Mechanism of oil shale pyrolysis under high water[J]. J Fuel Chem Technol,2011,39(12):881−886. doi: 10.3969/j.issn.0253-2409.2011.12.001
18. [18]
  REN X, CAO J, ZHAO X, YANG Z, LIU T, FAN X, ZHAO Y, WEI X. Catalytic upgrading of pyrolysis vapors from lignite over mono/bimetal-loaded mesoporous HZSM-5[J]. Fuel,2018,218:33−40.
19. [19]
  TRIPATHI A K, OJHA D K, VINU R. Selective production of valuable hydrocarbons from waste motorbike engine oils via catalytic fast pyrolysis using zeolites[J]. J Anal Appl pyrolsis,2015,114:281−292.
20. [20]
  JI X, LIU B, MA W, CHEN G, YAN B, CHENG Z. Effect of MgO promoter on Ni-Mg/ZSM-5 catalysts for catalytic pyrolysis of lipid-extracted residue of Tribonema minus[J]. J Anal Appl Pyrolsis,2017,123:278−283.
21. [21]
  YOU Y, HAN X, LIU J, JIANG X. Structural characteristics and pyrolysis behaviors of huadian oil shale kerogens using solid-state 13 C NMR, Py-GCMS and TG[J]. J Therm Anal Calorim,2017,131:1−11.
22. [22]
  LI S, CHEN J, HAO T, LIANG W, LIU X, SUN M, MA X. Pyrolysis of Huang Tu Miao coal over faujasite zeolite and supported transition metal catalysts[J]. J Anal Appl Pyrolsis,2013,102:161−169.
23. [23]
  BILIGETU T, WANG Y, NISHITOBA T, OTOMO R, PARK S, MOCHIZUKI H, KONDO J N, TASTUMI T, YOKOI T. Al distribution and catalytic performance of ZSM-5 zeolites synthesized with various alcohols[J]. J Catal,2017,353:1−10.
1. [1]
  Yi RU , Tao MENG , Zhaoteng XUE , Dongsen MAO . Synergistic catalysis of Al distribution and pore structure in ZSM-5 zeolite for bioethanol-to-propylene. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 247-262. doi: 10.11862/CJIC.20250255
2. [2]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
3. [3]
  Huiwei Ding , Bo Peng , Zhihao Wang , Qiaofeng Han . Advances in Metal or Nonmetal Modification of Bismuth-Based Photocatalysts. Acta Physico-Chimica Sinica, 2024, 40(4): 2305048-0. doi: 10.3866/PKU.WHXB202305048
4. [4]
  Mengxiu Li , Jiahui Mao , Jiangfeng Ni , Liang Li . Three birds with one stone: modification of Li₅FeO₄ with thermal induction of Lewis acid. Acta Physico-Chimica Sinica, 2026, 42(4): 100189-0. doi: 10.1016/j.actphy.2025.100189
5. [5]
  Qinhui Guan , Yuhao Guo , Na Li , Jing Li , Tingjiang Yan . Molecular sieve-mediated indium oxide catalysts for enhancing photocatalytic CO₂ hydrogenation. Acta Physico-Chimica Sinica, 2025, 41(11): 100133-0. doi: 10.1016/j.actphy.2025.100133
6. [6]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . High-Stable Aqueous Zinc Metal Anodes Enabled by an Oriented ZnQ Zeolite Protective Layer with Facile Ion Migration Kinetics. Acta Physico-Chimica Sinica, 2025, 41(1): 100003-0. doi: 10.3866/PKU.WHXB202309003
7. [7]
  Zhaohong Zuo , Wenhao Qiu , Kehan Peng , Haowen Luo , Yihan Wang , Yunren Shi . 聚乙烯热解的AI辅助ReaxFF动力学虚拟仿真实验. University Chemistry, 2026, 41(10): 296-308. doi: 10.12461/PKU.DXHX202510010
8. [8]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
9. [9]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-0. doi: 10.3866/PKU.WHXB202408005
10. [10]
  Rohit Kumar , Anita Sudhaik , Aftab Asalam Pawaz Khan , Van Huy Neguyen , Archana Singh , Pardeep Singh , Sourbh Thakur , Pankaj Raizada . Designing tandem S-scheme photo-catalytic systems: Mechanistic insights, characterization techniques, and applications. Acta Physico-Chimica Sinica, 2025, 41(11): 100150-0. doi: 10.1016/j.actphy.2025.100150
11. [11]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
12. [12]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
13. [13]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
14. [14]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-0. doi: 10.3866/PKU.WHXB202406012
15. [15]
  Yong Shu , Xing Chen , Sai Duan , Rongzhen Liao . How to Determine the Equilibrium Bond Distance of Homonuclear Diatomic Molecules: A Case Study of H₂. University Chemistry, 2024, 39(7): 386-393. doi: 10.3866/PKU.DXHX202310102
16. [16]
  Fangyu Leng , Jian Zhang , Yuwen Zhang , Yuchun Jiang , Xiaohong Chang , Jie Wei . 以废治废：回收锌锰电池负极材料催化糖解PET塑料的综合实验教学. University Chemistry, 2026, 41(5): 319-329. doi: 10.12461/PKU.DXHX202510077
17. [17]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
18. [18]
  Wenwei Zhang , Yiru Wang , Chanzi Ruan , Juanjuan Song , Yongxian Fan , Houjin Li , Dongcheng Liu , Yanping Ren , Xiuqiong Zeng , Faqiong Zhao , Mei Shi , Min Hu , Wan Li , Xiuyun Wang , Weihong Li , Xiaohang Qiu , Yong Fan , Jianrong Zhang , Shuyong Zhang . Suggestions on Heating and Heating Instruments (Part III): Indirect Heating and the Use of Thermal Baths (Water Bath, Oil Bath, Metal Bath and Sand Bath). University Chemistry, 2026, 41(3): 163-171. doi: 10.12461/PKU.DXHX202507039
19. [19]
  Ziying YUAN , Zhen DUAN , Dan LIU , Jingrui NIU , Feiyan LAI , Xiaohui ZHANG , Guangchang YANG . Modification of O3-type Na_0.86Ni_1/3Fe_1/3Mn_1/3O₂ cathode material via Ti⁴⁺/P⁵⁺ dual-site co-doping. Chinese Journal of Inorganic Chemistry, 2026, 42(8): 1647-1657. doi: 10.11862/CJIC.20260041
20. [20]
  Ziwen Lei , Mingyin Liu , Jiayi Shi , Yahan Shan , Qi Zhang . 当超分子二肽遇上酸碱指示剂：热响应水凝胶的智能可视化. University Chemistry, 2026, 41(8): 210-219. doi: 10.12461/PKU.DXHX202508014

Get Citation

PDF

XML

Metrics

PDF Downloads(29)
Abstract views(4088)
HTML views(589)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142