Citation: Chang-ming LIANG, An-dong ZAHNG, Zhi-he LI, Yu-feng LI, Shao-qing WANG, Wei-ming YI. Hydrogen production from wood vinegar reforming over cobalt modified nickel-based catalyst[J]. Journal of Fuel Chemistry and Technology, ;2021, 49(2): 168-177. doi: 10.19906/j.cnki.JFCT.2021016 shu

Hydrogen production from wood vinegar reforming over cobalt modified nickel-based catalyst

Chang-ming LIANG ^{1, 2,} ,
An-dong ZAHNG ^{1, 2} ,
Zhi-he LI ^{1, 2,,} ,
Yu-feng LI ^{1, 2} ,
Shao-qing WANG ^{1, 2} ,
Wei-ming YI ^{1, 2}

1.
College of Agricultural Engineering and Food Science, Shandong University of Technology, Zibo 255000, China
2.
Shandong Research Center of Engineering & Technology for Clean Energy, Zibo 255000, China

Corresponding author: Zhi-he LI, lizhihe@sdut.edu.cn
Received Date: 15 October 2020
Revised Date: 20 November 2020

Figures(13)

In order to realize high value utilization of wood vinegar, a series of Ni based catalysts with different Co contents prepared by impregnation method were tested in a fixed bed reactor. The effects of liquid space-time velocity, reaction temperature and Ni/Co ratio on hydrogen production, carbon conversion, H₂ selectivity and carbon deposition were investigated. The catalysts were characterized by XRF, H₂-TPR, SEM and elemental analysis. The results show that the gas production increases with the increase of space-time velocity of liquid, but the catalyst deactivation is accelerated when the space-time velocity of liquid is too high. High temperature is conducive to the catalytic reforming of wood vinegar to produce hydrogen. When the temperature reaches 900 °C, the hydrogen yield is the highest. With the increase of cobalt content, the carbon deposition and hydrogen yield decrease. Therefore, when the liquid space velocity is 60 h⁻¹ and the temperature is 800 °C, the Ni-0.5Co/Al₂O₃ catalyst is most conducive to the hydrogen production experiment of wood vinegar.
- wood vinegar,
- hydrogen from reforming,
- nickel-based catalyst,
- carbon deposition
1. [1]
  SHARMA S, GHOSHAL S K. Hydrogen the future transportation fuel: From production to applications[J]. Renewable Sustainable Energy Rev,2015,43:1151−1158. doi: 10.1016/j.rser.2014.11.093
2. [2]
  WU Q, ZHANG S, HOU B. Study on the preparation of wood vinegar from biomass residues by carbonization process[J]. Bioresour Technol,2015,179:98−103. doi: 10.1016/j.biortech.2014.12.026
3. [3]
  WANG Hai-ying, YANG Guo-ting, ZHOU Dan. Research situation and comprehensive utilization of wood vinegar[J]. J Northeast For Univ,2004,9(5):55−57. doi: 10.3969/j.issn.1000-5382.2004.05.020
4. [4]
  ORAMAHI H A, YOSHIMURA T. Antifungal and antitermitic activities of wood vinegar from Vitex pubescens Vahl[J]. J Wood Sci,2013,59(4):344−350. doi: 10.1007/s10086-013-1340-8
5. [5]
  MUNGKUNKAMCHAO T, KESMALA T, PIMRATCH S, TOOMSAN B, JOTHITYANGKOON D. Wood vinegar and fermented bioextracts: Natural products to enhance growth and yield of tomato (Solanum lycopersicum L.)[J]. Sci Hortic,2013,154:66−72. doi: 10.1016/j.scienta.2013.02.020
6. [6]
  LU Xin-cheng, JIANG Jian-chun, SUN Kang, SUN Yun-juan. Review on preparation and application of wood vinegar[J]. Chem Ind Forest Prod,2017,37(3):1−9. doi: 10.3969/j.issn.0253-2417.2017.03.001
7. [7]
  JIANG En-chen, ZHAO Chen-xi, QIN Li-yuan, CHEN Ai-hui. Experiment of wood vinegar produced from pine nut shell continuous pyrolysis[J]. Trans CSAE,2014,30(5):262−269. doi: 10.3969/j.issn.1002-6819.2014.05.033
8. [8]
  XU X, JIANG E, LI B, WANG M. Hydrogen production from wood vinegar of camellia oleifera shell by Ni/M/γ-A1₂O₃ catalyst[J]. Catal Commun,2013,39:106−114. doi: 10.1016/j.catcom.2013.04.024
9. [9]
  MEDRANO J A, OLIVA M, RUIZ J. Hydrogen from aqueous fraction of biomass pyrolysis liquids by catalytic steam reforming in ﬂuidized bed[J]. Energy,2011,36:2215−2224. doi: 10.1016/j.energy.2010.03.059
10. [10]
  XU X, JIANG E, SUN Y, LI Z. Influence of mixed supports on the steam catalytic reforming of wood vinegar[J]. Energy Fuels,2017,31(2):1678−1688. doi: 10.1021/acs.energyfuels.6b03000
11. [11]
  FU P, ZHANG A, LUO S, YI W, HU S, ZHANG Y. Catalytic steam reforming of biomass-derived acetic acid over two supported Ni catalysts for hydrogen-rich syngas production[J]. ACS Omega,2019,4(8):13585−13593. doi: 10.1021/acsomega.9b01985
12. [12]
  ZHANG A, LI Z, YI W, FU P, WANG L, LIANG C, LUO S. Study the reaction mechanism of catalytic reforming of acetic acid through the instantaneous gas production[J]. Int J Hydrogen Energy,2019,44(39):21279−21289. doi: 10.1016/j.ijhydene.2019.06.060
13. [13]
  LI L, JIANG B, TANG D, ZHANG Q, ZHEG Z. Hydrogen generation by acetic acid steam reforming over Ni-based catalysts derived from La_1−x Ce_xNiO₃ perovskite[J]. Int J Hydrogen Energy,2018,43(14):6795−6803. doi: 10.1016/j.ijhydene.2018.02.128
14. [14]
  SIANG J, LEE C, WANG C. Hydrogen production from steam reforming of ethanol using a ceria-supported iridium catalyst: effect of different ceria supports[J]. Int J Hydrogen Energy,2010,35(8):3456−3462. doi: 10.1016/j.ijhydene.2010.01.067
15. [15]
  ZHANG B, TANG X, LI Y. Steam reforming of bio-ethanol for the production of hydrogen over ceria-supported Co, Ir and Ni catalysts[J]. Catal Commun,2006,7(6):367−372. doi: 10.1016/j.catcom.2005.12.014
16. [16]
  HE S, MEI Z, LIU N. Ni/SBA-15 catalysts for hydrogen production by ethanol steam reforming: Effect of nickel precursor[J]. Int J Hydrogen Energy,2017,42(21):14429−14438. doi: 10.1016/j.ijhydene.2017.02.115
17. [17]
  XIE H Q, YU Q B, YAO X. Hydrogen production via steam reforming of bio-oil model compounds over supported nickel catalysts[J]. J Energy Chem,2015,24(3):299−308. doi: 10.1016/S2095-4956(15)60315-1
18. [18]
  CONSTANTINOU D A, EFSTATHIOU A M. Low-temperature purification of gas streams from phenol by steam reforming over novel supported-Rh catalysts[J]. Appl Catal B: Environ,2010,96(3/4):276−289. doi: 10.1016/j.apcatb.2010.02.007
19. [19]
  ARTETXE M, NAHIL M A, OLAZAR M, WILLIAMSP T. Steam reforming of phenol as biomass tar model compound over Ni/Al₂O₃ catalyst[J]. Fuel,2016,184:629−636. doi: 10.1016/j.fuel.2016.07.036
20. [20]
  WANG Yi-shuang, CHEN Ming-qiang, LlU Shao-min, YANG Zhong-lian, SHEN Chao-ping, LIU Ke. Hydrogen production via cataylic steam reforming of bio-oil model compounds over NiO-Fe₂O₃-loaded palygouskite[J]. J Fuel Chem Technol,2015,43(12):1470−1475. doi: 10.3969/j.issn.0253-2409.2015.12.010
21. [21]
  NOGUEIRA F, ASSAF P, CARVALHO H, ASSAF E. Catalytic steam reforming of acetic acid as a model compound of bio-oil[J]. Appl Catal B: Environ,2014,160(7):188−199.
22. [22]
  HE Z, YANG M, WANG X, ZHAO Z, DUAN A. Effect of the transition metal oxide supports on hydrogen production from bio-ethanol reforming[J]. Catal Today,2012,194(1):2−8. doi: 10.1016/j.cattod.2012.05.004
23. [23]
  XU X, ZHANG C, LIU Y, ZHAI Y, ZHANG R, TANG X. Catalytic reforming of acetic acid as a model compound of bio-oil for hydrogen production over Ni-CeO₂-MgO/olivine catalysts[J]. Environ Prog Sustainable Energy,2015,34(3):915−922. doi: 10.1002/ep.12062
24. [24]
  NABGAN W, ABDULLAH T A T, MAT R. Production of hydrogen via steam reforming of acetic acid over Ni and Co supported on La₂O₃ catalyst[J]. Int J Hydrogen Energy,2017,42(14):8975−8985. doi: 10.1016/j.ijhydene.2016.04.176
25. [25]
  ZHANG F, WANG M, ZHU L. A comparative research on the catalytic activity of La₂O₃ and γ-Al₂O₃ supported catalysts for acetic acid steam reforming[J]. Int J Hydrogen Energy,2017,42(6):3667−3675. doi: 10.1016/j.ijhydene.2016.06.264
26. [26]
  WURZLER G T, RABELO-ETO R C, MATTOS L V. Steam reforming of ethanol for hydrogen production over MgO-supported Ni-based catalysts[J]. Appl Catal A: Gen,2016,518:115−128. doi: 10.1016/j.apcata.2015.11.020
27. [27]
  LV Yan-an, ZHAO Xing-ling, SUO Zhang-huai, LIAO Wei-ping, JIN Ming-shan. Low-temperature steam reforming of glycerol for hydrogen production over supported nickel catalysts[J]. J Fuel Chem Technol,2015,43(6):684−691. doi: 10.3969/j.issn.0253-2409.2015.06.007
28. [28]
  MORAES T S, NETO R C R, RIBEIRO M C, MATTOS L V, KOURTELESIS M, LADAS S, VERYKIOS X, BELLOT NORONHA F. The study of the performance of PtNi/CeO₂-nanocube catalysts for low temperature steam reforming of ethanol[J]. Catal Today,2015,242:35−49. doi: 10.1016/j.cattod.2014.05.045
29. [29]
  ZHANG Z M, WANG Y R, SUN K. Steam reforming of acetic acid over Ni-Ba/Al₂O₃ catalysts: Impacts of barium addition on coking behaviors and formation of reaction intermediates[J]. J Energy Chem,2020,43:208−219. doi: 10.1016/j.jechem.2019.08.023
30. [30]
  VICENTE J, MONTERO C, EREÑA J, AZKOITI M J, BILBAO J, GAYUBO A G. Coke deactivation of Ni and Co catalysts in ethanol steam reforming at mild temperatures in a fluidized bed reactor[J]. Int J Hydrogen Energy,2014,39(24):12586−12596. doi: 10.1016/j.ijhydene.2014.06.093
31. [31]
  ZHANG A, LIANG C, WANG L, LI Z, YI W, FU P, WANG S. Study on the trigger mechanism and carbon behavior of catalytic reforming of wood vinegar[J]. Int J Hydrogen Energy,2020,45(29):14669−14678. doi: 10.1016/j.ijhydene.2020.03.196
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