Citation: Wei-jun QIAO, Guo-peng XIAO, Lei ZHANG, Shao-jun QING, Ying-qi ZHAO, Zhong-xing GENG, Zhi-xian GAO. Catalytic performance of CuO/La_1−xCe_xCrO₃ in the steam reforming of methanol[J]. Journal of Fuel Chemistry and Technology, ;2021, 49(2): 205-210. doi: 10.19906/j.cnki.JFCT.2021012 shu

Catalytic performance of CuO/La_1−xCe_xCrO₃ in the steam reforming of methanol

1.
School of Petrochemical Engineering, Liaoning Shihua University, Fushun　113001, China
2.
Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan　030001, China

Corresponding author: Lei ZHANG, lnpuzhanglei@163.com
Received Date: 3 September 2020
Revised Date: 6 October 2020

Figures(7)

A series of supported CuO/La_1−xCe_xCrO₃ catalysts were prepared by the sol-gel method and the effect of Ce doping in the A site on their structure, properties and catalytic performance in the steam reforming of methanol were investigated. The results indicate that the Ce doping impacts mainly on the reduction performance of CuO and the interaction between the perovskite support and CuO, which in turn influences the catalytic performance of CuO/La_1−xCe_xCrO₃ in methanol steam reforming. In particular, the CuO/La_0.8Ce_0.2CrO₃ catalyst demonstrates adequate performance in methanol steam reforming; over it, the methanol conversion reaches 100% under 280 °C, water/methanol molar ratio of 1.2 and methanol gas hourly space velocity of 800 h⁻¹.
- perovskite,
- methanol steam reforming,
- hydrogen,
- sol-gel method
1. [1]
  ZAICENKO V M, SHPILRAIN E E, SHTERENBERG V Y. Hydrogen energy: Present state and lines of future development[J]. Teploenergetika,2003,1(5):61−67.
2. [2]
  HERDEM M S, SINAKI M Y, FARHAD S, HAMDULLAHPUR F. An overview of the methanol reforming process: comparison of fuels, catalysts, reformers, and systems[J]. Int J Hydrogen Energy,2019,43:5076−5085.
3. [3]
  CLAUDE L. From hydrogen production by water electrolysis to its utilization in a PEM fuel cell or in a SO fuel cell: Some considerations on the energy efficiencies[J]. Int J Hydrogen Energy,2016,41(34):15415−15425. doi: 10.1016/j.ijhydene.2016.04.173
4. [4]
  HOSSAIN M A, JEWARATNAM J, GANESAN P. Prospect of hydrogen production from oil palm biomass by thermochemical process-A review[J]. Int J Hydrogen Energy,2016,41(38):16637−16655. doi: 10.1016/j.ijhydene.2016.07.104
5. [5]
  SA S, SILVA H, BRANDAO L, SOUSA J M, MENDES A. Catalysts for methanol steam reforming—A review[J]. Appl Catal B: Environ,2010,99(1-2):43−57. doi: 10.1016/j.apcatb.2010.06.015
6. [6]
  LYTKINA A A, ZHILYAEVA N A, ERMILOVA M M, OREKHOVA N V, YAROSLAVTSEV A B. Influence of the support structure and composition of Ni-Cu-based catalysts on hydrogen production by methanol steam reforming[J]. Int J Hydrogen Energy,2015,40(31):9677−9684. doi: 10.1016/j.ijhydene.2015.05.094
7. [7]
  HE J P, YANG Z X, ZHANG L, LI Y, PAN L W. Cu supported on ZnAl-LDHs precursor prepared by in-situ synthesis method on γ-Al₂O₃ as catalytic material with high catalytic activity for methanol steam reforming[J]. Int J Hydrogen Energy,2017,42(15):9930−9937. doi: 10.1016/j.ijhydene.2017.01.229
8. [8]
  WANG Z J, WANG C X, CHEN S Q, LIU Y. Co-Ni bimetal catalyst supported on perovskite-type oxide for steam reforming of ethanol to produce hydrogen[J]. Int J Hydrogen Energy,2014,39(11):5644−5652. doi: 10.1016/j.ijhydene.2014.01.151
9. [9]
  GLISENTI A, GALENDA A, NATILE M M. Steam reforming and oxidative steam reforming of methanol and ethanol: The behaviour of LaCo_0.7Cu_0.3O₃[J]. Appl Catal A: Gen,2013,453:102−112. doi: 10.1016/j.apcata.2012.11.031
10. [10]
  XIAO Guo-peng, QIAO Wei-jun, WANG Li-bao, ZHANG Lei, ZHANG Jian, WANG Hong-hao. The effect of LaNiO₃ roasting temperature on CuO/LaNiO₃ catalysts for hydrogen production by methanol steam reforming[J]. J Fuel Chem Technol,2020,48(2):213−240. doi: 10.3969/j.issn.0253-2409.2020.02.011
11. [11]
  KHALESI A, ARANDIYAN H R, PARVARI M. Effects of Lanthanum Substitution by Strontium and Calcium in La-Ni-Al Perovskite Oxides in Dry Reforming of Methane[J]. J Catal,2008,29(10):18−26.
12. [12]
  YANG S Q, ZHOU F, LIU Y J, ZHANG L, YU C, WANG H H, TIAN Y, ZHANG C S, LIU D S. Morphology effect of ceria on the performance of CuO/CeO₂ catalysts for hydrogen production by methanol steam reforming[J]. Int J Hydrogen Energy,2019,44(14):7252−7261. doi: 10.1016/j.ijhydene.2019.01.254
13. [13]
  XI H J, HOU X N, LIU Y J, QING S J, GAO Z X. Cu–Al spinel oxide as an efficient catalyst for methanol steam reforming[J]. Angew Chem Int Ed,2014,126:12080−12083.
14. [14]
  WANG Li-bao, WANG Dong-zhe, ZHANG Lei, QING Shao-jun, HAN Jiao, ZHANG Cai-shun, GAO Zhi-xian, ZHANG Hai-juan, FENG Xu-hao. Effect of cerium source on CuO/CeO₂ catalysts for hydrogen production by methanol steam reforming[J]. J Fuel Chem Technol,2020,48(7):852−859.
15. [15]
  SU Shi-long, ZHANG Lei, ZHANG Yan, LEI Jun-teng, GUI Jian-zhou, LIU Dan, LIU Dao-sheng, PAN Li-wei. Thermodynamic simulation of hydrogen production process from kilowatt PEMFC methanol steam reforming[J]. J Petrochem College,2015,28(2):21−25.
16. [16]
  YANG Shu-qian, HE Jian-ping, ZHANG Na, SUI Xiao-wei, ZHANG Lei, YANG Zhan-xu. Effect of rare-earth element modification on the performance of Cu/ZnAl catalysts derived from hydrotalcite precursor in methanol steam reforming[J]. J Fuel Chem Technol,2018,46(2):179−188. doi: 10.3969/j.issn.0253-2409.2018.02.007
17. [17]
  LIU Yu-juan, WANG Dong-zhe, ZHANG Lei, WANG Hong-hao, CHEN Lin, LIU Dao-sheng, HAN Jiao, ZHANG Cai-shun. Effect of carrier roasting atmosphere on CuO/CeO₂ catalyst for methanol steam reforming[J]. J Fuel Chem Technol,2018,46(8):992−999. doi: 10.3969/j.issn.0253-2409.2018.08.011
18. [18]
  ZHANG L, PAN L W, NI C J, SUN T J, ZHAO S S, WANG S D, WANG A J, HU Y K. CeO₂-ZrO₂-promoted CuO/ZnO catalyst for methanol steam reforming[J]. Int J Hydrogen Energy,2013,38(11):4397−4406. doi: 10.1016/j.ijhydene.2013.01.053
19. [19]
  SONG Q L, MEN Y, WANG J G, LIU S, CHAI S S, AN W, WANG K, LI Y Y, TANG Y H. Methanol steam reforming for hydrogen production over ternary composite Zn_yCe₁Zr₉O_x catalysts[J]. Int J Hydrogen Energy,2020,45(16):9592−9602. doi: 10.1016/j.ijhydene.2020.01.175
1. [1]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
2. [2]
  Wenwei Zeng , Qingyu Sun , Mengxiang Liang , Lirong Lin , Laiying Zhang . Unveiling Anti-Counterfeiting Secrets: Excitation-Dependent Luminescence in Sb³⁺-Doped Perovskite Materials. University Chemistry, 2026, 41(2): 375-384. doi: 10.12461/PKU.DXHX202503036
3. [3]
  Lixing ZHANG , Yaowen WANG , Xu HAN , Junhong ZHOU , Jinghui WANG , Liping LI , Guangshe LI . Research progress in the synthesis of fluorine-containing perovskites and their derivatives. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1689-1701. doi: 10.11862/CJIC.20250007
4. [4]
  Yao Ma , Xin Zhao , Hongxu Chen , Wei Wei , Liang Shen . Progress and Perspective of Perovskite Thin Single Crystal Photodetectors. Acta Physico-Chimica Sinica, 2025, 41(4): 100030-0. doi: 10.3866/PKU.WHXB202309045
5. [5]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
6. [6]
  Nian LIU , Biao ZHENG , Kun WANG , Chunbao ZHENG , Qingyan HAN , Enjie HE , Saidong XUE . Synthesis and spectroscopic performance of double perovskite Li_0.5La_0.5MgSrWO₆∶Mn⁴⁺ phosphors for plant growth lighting. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 129-140. doi: 10.11862/CJIC.20250069
7. [7]
  Runnan Yu , Xirui Liu , Xiangyuan Zheng , Bo Wen , Zhan'ao Tan . Undergraduate experimental design for preparing perovskite quantum dots via room-temperature ligand-assisted reprecipitation and investigating their luminescent properties. University Chemistry, 2026, 41(7): 290-299. doi: 10.12461/PKU.DXHX202506028
8. [8]
  Lihui Liu , Mingguang Li . 基于空穴传输层调控的钙钛矿发光二极管制备及表征综合实验设计. University Chemistry, 2026, 41(9): 337-346. doi: 10.12461/PKU.DXHX202509054
9. [9]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
10. [10]
  Zunyuan Xie , Lijin Yang , Zixiao Wan , Xiaoyu Liu , Yushan He . Exploration of the Preparation and Characterization of Nano Barium Titanate and Its Application in Inorganic Chemistry Laboratory Teaching. University Chemistry, 2024, 39(4): 62-69. doi: 10.3866/PKU.DXHX202310137
11. [11]
  Tongtong Zhao , Yan Wang , Shiyue Qin , Liang Xu , Zhenhua Li . New Experiment Development: Upgrading and Regeneration of Discarded PET Plastic through Electrocatalysis. University Chemistry, 2024, 39(3): 308-315. doi: 10.3866/PKU.DXHX202309003
12. [12]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
13. [13]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Construction of Electron Bridge and Activation of MoS₂ Inert Basal Planes by Ni Doping for Enhancing Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-0. doi: 10.3866/PKU.WHXB202406024
14. [14]
  Haibo NING , Qingkun KONG . Cs₂PdBr₆ microcrystals: Femtosecond transient absorption spectroscopy analysis and photocatalytic CO₂ reduction performance. Chinese Journal of Inorganic Chemistry, 2026, 42(10): 2179-2185. doi: 10.11862/CJIC.20260068
15. [15]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Research on Cu-Based and Pt-Based Catalysts for Hydrogen Production through Methanol Steam Reforming. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-0. doi: 10.1016/j.actphy.2025.100049
16. [16]
  Heyu Li , Lingjiao Li , Haiyu Wang , Bin Liu , Lianfen Chen , Zhiliang Jin . Chirality regulated CdS/Co-doped Ti₃C₂ MXene Schottky heterojunction for microplastic photoreforming to hydrogen and pyruvic acid. Acta Physico-Chimica Sinica, 2026, 42(10): 100350-0. doi: 10.1016/j.actphy.2026.100350
17. [17]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
18. [18]
  Jian Li , Yu Zhang , Rongrong Yan , Kaiyuan Sun , Xiaoqing Liu , Zishang Liang , Yinan Jiao , Hui Bu , Xin Chen , Jinjin Zhao , Jianlin Shi . Highly Efficient, Targeted, and Traceable Perovskite Nanocrystals for Photoelectrocatalytic Oncotherapy. Acta Physico-Chimica Sinica, 2025, 41(5): 100042-0. doi: 10.1016/j.actphy.2024.100042
19. [19]
  Weicheng Feng , Jingcheng Yu , Yilan Yang , Yige Guo , Geng Zou , Xiaoju Liu , Zhou Chen , Kun Dong , Yuefeng Song , Guoxiong Wang , Xinhe Bao . Regulating the High Entropy Component of Double Perovskite for High-Temperature Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2024, 40(6): 2306013-0. doi: 10.3866/PKU.WHXB202306013
20. [20]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . Emerging Irreversible and Reversible Ion Migrations in Perovskites. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-0. doi: 10.3866/PKU.WHXB202311011

Get Citation

PDF

XML

Metrics

PDF Downloads(25)
Abstract views(4061)
HTML views(898)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Catalytic performance of CuO/La1−xCexCrO3 in the steam reforming of methanol

Metrics

通讯作者: 陈斌, bchen63@163.com

Catalytic performance of CuO/La_1−xCe_xCrO₃ in the steam reforming of methanol