Citation: Wei-jun QIAO, Guo-peng XIAO, Lei ZHANG, Shao-jun QING, Ying-qi ZHAO, Zhong-xing GENG, Zhi-xian GAO. Catalytic performance of CuO/La_1−xCe_xCrO₃ in the steam reforming of methanol[J]. Journal of Fuel Chemistry and Technology, ;2021, 49(2): 205-210. doi: 10.19906/j.cnki.JFCT.2021012 shu

Catalytic performance of CuO/La_1−xCe_xCrO₃ in the steam reforming of methanol

1.
School of Petrochemical Engineering, Liaoning Shihua University, Fushun　113001, China
2.
Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan　030001, China

Corresponding author: Lei ZHANG, lnpuzhanglei@163.com
Received Date: 3 September 2020
Revised Date: 6 October 2020

Figures(7)

A series of supported CuO/La_1−xCe_xCrO₃ catalysts were prepared by the sol-gel method and the effect of Ce doping in the A site on their structure, properties and catalytic performance in the steam reforming of methanol were investigated. The results indicate that the Ce doping impacts mainly on the reduction performance of CuO and the interaction between the perovskite support and CuO, which in turn influences the catalytic performance of CuO/La_1−xCe_xCrO₃ in methanol steam reforming. In particular, the CuO/La_0.8Ce_0.2CrO₃ catalyst demonstrates adequate performance in methanol steam reforming; over it, the methanol conversion reaches 100% under 280 °C, water/methanol molar ratio of 1.2 and methanol gas hourly space velocity of 800 h⁻¹.
- perovskite,
- methanol steam reforming,
- hydrogen,
- sol-gel method
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Catalytic performance of CuO/La1−xCexCrO3 in the steam reforming of methanol

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通讯作者: 陈斌, bchen63@163.com

Catalytic performance of CuO/La_1−xCe_xCrO₃ in the steam reforming of methanol