铜离子介导的草甘膦荧光传感器的构建及应用

吴绵园 喻艳超 由君 武文菊

引用本文: 吴绵园, 喻艳超, 由君, 武文菊. 铜离子介导的草甘膦荧光传感器的构建及应用[J]. 分析化学, 2023, 51(1): 130-138. doi: 10.19756/j.issn.0253-3820.221213 shu
Citation:  WU Mian-Yuan,  YU Yan-Chao,  YOU Jun,  WU Wen-Ju. Construction of Fluorescence Sensor for Detection of Glyphosate Based on Copper Ion[J]. Chinese Journal of Analytical Chemistry, 2023, 51(1): 130-138. doi: 10.19756/j.issn.0253-3820.221213 shu

铜离子介导的草甘膦荧光传感器的构建及应用

    通讯作者: 喻艳超,E-mail:yychao136@163.com
  • 基金项目:

    国家自然科学基金项目(No.21908034)和黑龙江省自然科学基金项目(No.LH2021H001)资助。

摘要: 以7-二乙氨基香豆素为荧光基团,设计并合成了一种香豆素酰腙类荧光探针CPS。研究结果表明,在甲醇溶液中,探针CPS对Cu2+呈特异性的荧光猝灭响应,且与Cu2+形成分子比为2∶1的络合物CPS-Cu2+。此络合物作为荧光传感器实现了草甘膦的特异性识别,具有较高的灵敏度,检出限可低至64.8nmol/L(10.95ng/mL)。通过Job's plot曲线、摩尔比法及质谱等手段,推测了荧光传感器检测草甘膦的作用机制。实际水样的加标回收实验证明了此荧光传感器检测草甘膦具有良好的实用性。

English


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  • 收稿日期:  2022-05-04
  • 修回日期:  2022-08-06
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