Citation: LI Han-Wei, JIANG Ji-Chun, YANG Ming, FAN Zhi-Gang, ZHANG Bai-Mao, TIAN Di, HUA Lei, LI Hai-Yang. Development of Ion Funnel Focusing Photoionization Mass Spectrometry and Its Application in Online Monitoring of Atmospheric Benzene Series[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(10): 1456-1464. doi: 10.19756/j.issn.0253-3820.221209 shu

Development of Ion Funnel Focusing Photoionization Mass Spectrometry and Its Application in Online Monitoring of Atmospheric Benzene Series

LI Han-Wei ¹ ,
JIANG Ji-Chun ^2,, ,
YANG Ming ⁴ ,
FAN Zhi-Gang ^2,3 ,
ZHANG Bai-Mao ^2,3 ,
TIAN Di ^1,, ,
HUA Lei ² ,
LI Hai-Yang ²

1.
College of Instrumentation & Electrical Engineering, Jilin University, Changchun 130061, China;
2.
CAS Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;
3.
University of Chinese Academy of Sciences, Beijing 100049, China;
4.
College of Environmental and Chemical Engineering, Dalian University, Dalian 116023, China

Corresponding author: JIANG Ji-Chun, TIAN Di,
Received Date: 29 April 2022
Revised Date: 26 May 2022

Fund Project: Supported by the National Natural Science Foundation of China (Nos.22027804, 22174142) and Innovative Funds from Dalian Institute of Chemical Physics, Chinese Academy of Sciences (Nos.DICP I202144, DICP I202123).

Atmospheric benzene series have high photochemical reactivity and biological toxicity, and have been one of the most important atmospheric volatile organic pollutants. However, their low concentration and rapid temporal and spatial changes make real-time and accurate quantitative monitoring extremely challenging. Vacuum ultraviolet photoionization (VUV-PI) mass spectrometry is a commonly used analytical method for online monitoring of benzene series, but the currently commonly used VUV-PI ionization source cannot effectively utilize the generated ions, which restricts the further improvement of sensitivity. In this study, a novel ion funnel focused photoionization time-of-flight mass spectrometer (IFPI-TOFMS) was developed. By introducing a radio frequency ion funnel into the photoionization source, the ion transmission efficiency in the source was increased by 26-37 times, and the limits of detection (LODs) of IFPI-TOFMS for isoprene, benzene, toluene, styrene, p-xylene, trimethylbenzene, and limonene reached 34.3×10^-12, 7.9×10^-12, 7.0×10^-12, 9.4×10^-12, 7.7×10^-12, 10.6×10^-12 and 13.7×10^-12(V/V) within 5 s, respectively. Linear range of 2-3 orders of magnitude were achieved with the linear correlation coefficients (R²) greater than 0.99. The relative standard deviation (RSD) during 12 h monitoring was less than 3%, which exhibited good stability of IFPI-TOFMS. IFPI-TOFMS was utilized to carry out real-time online monitoring of atmospheric benzene series in Dalian urban area. The results showed that benzene series in the atmosphere down to 10^-12 (V/V) could be quantitatively monitored in real-time and online by IFPI-TOFMS, which indicated that IFPI-TOFMS had potential application value and broad development prospects in the field of atmospheric environment monitoring.
- Photoionization,
- Time-of-flight mass spectrometry,
- Ion funnel,
- Atmospheric benzene series,
- Online monitoring
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