Citation: XIE Kai-Xin, LIU Chang, LI Meng-Fan, LI Zhuan, XIAO Xiu-Xian. Enhancement Effect of Gold Nanorods on Surface Plasmon Coupled Emission[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(10): 1560-1566. doi: 10.19756/j.issn.0253-3820.221176 shu

Enhancement Effect of Gold Nanorods on Surface Plasmon Coupled Emission

College of Chemistry and Materials, Taiyuan Normal University, Jinzhong 030600, China

Corresponding author: XIE Kai-Xin, xiekaixin@tynu.edu.cn
Received Date: 10 April 2022
Revised Date: 10 June 2022

Fund Project: Supported by the National Natural Science Foundation of China (No.21804098), the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi Province (No.2021L402) and the Key Laboratory of Spectrochemical Analysis and Instrumentation (Xiamen University), Ministry of Education (No.SCAI2003).

Surface plasmon coupled emission (SPCE), a novel surface enhanced fluorescence technique, can generate directional and amplified radiation by the intense interaction between fluorophores and surface plasmon of metallic nanofilm. Strong interaction between localized and propagating surface plasmon and "hot spot" structure is important to enhance electromagnetic field while providing special optical phenomena. This unique plasmonic effect has the potential to optimize the performance of SPCE based system. Herein, gold nanorods (AuNRs) were introduced through electrostatic adsorption to achieve an enhanced fluorescence system. After introduction of AuNRs, the fluorescence signal enhancement was realized by factors over 40 and 150 compared with the normal SPCE and free space emission, respectively. The unique enhancement of SPCE by the AuNRs effectively overcame the signal quenching and this enhancement was proven to be triggered by the enhanced electromagnetic field induced by the AuNRs assembly, which provided an opportunity to increase the detection sensitivity and established an optimal plasmonic enhancement system. The amplified SPCE system was employed for multi-wavelength detection through different emission angles, which could broaden the application of SPCE in multi-wavelength simultaneous enhancement and detection.
- Surface plasmon,
- Gold nanorods,
- Fluorescence enhancement,
- Wavelength resolution,
- Coupled emission
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