Citation: WEI Liang, HUANG Xin-Long, WANG Yan-Li, YANG Jing, YAN Fei-Yan, NING De-Jiao, TANG Li, LUO Li-Hong, WEI Yu-Ning, YA Yu. Preparation of Hierarchically Porous Carbon Using Different Activators and Its Electrochemical Sensing of Dihydroxybenzene Isomers[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(6): 899-911. doi: 10.19756/j.issn.0253-3820.221048 shu

Preparation of Hierarchically Porous Carbon Using Different Activators and Its Electrochemical Sensing of Dihydroxybenzene Isomers

WEI Liang ¹ ,
HUANG Xin-Long ¹ ,
WANG Yan-Li ² ,
YANG Jing ¹ ,
YAN Fei-Yan ² ,
NING De-Jiao ² ,
TANG Li ² ,
LUO Li-Hong ² ,
WEI Yu-Ning ² ,
YA Yu ^2,,

1.
College of Chemistry and Materials Science, Nanning Normal University, Nanning 530001, China;
2.
Institute for Agricultural Product Quality Safety and Testing Technology, Guangxi Academy of Agricultural Sciences, Nanning 530007, China

Corresponding author: YA Yu, yayu1026@163.com
Received Date: 24 January 2022
Revised Date: 30 March 2022

Fund Project: Supported by the National Natural Science Foundation of China(No. 21862004), the Natural Science Foundation of Guangxi, China(Nos. 2018GXNSFAA281230, 2018GXNSFAA281228), the Guangxi Agricultural Science and Technology Union Project(No. 202216), the Dominant Research Team Project of Guangxi Academy of Agricultural Sciences(No. 2021YT136), and the Innovation Project of Guangxi Graduate Education(No.YCSW2020193)

The hierarchically porous carbon materials were prepared with chitosan(CS) as carbon source, and NaCl, NaOH and Na₂CO₃ as activators. The morphology, porous structure, specific surface area and pore size distribution of the prepared carbon materials were characterized by scanning electron microscopy, X-ray diffraction, Raman spectrum and nitrogen adsorption-desorption isotherms,respectively. And the electrochemical properties of different carbon materials-modified electrode were studied by electrochemical techniques. Thus, structure-activity relationship between the morphology,structural and physicochemical parameters of different carbon materials and their electrochemical sensing properties were explored. The results showed that the hierarchically porous carbon material(CS-Na₂CO₃,prepared using Na₂CO₃ as activator) modified electrode had larger electrochemical active area, faster electron transfer rate and better electrocatalytic performance for three dihydroxybenzene isomers. A highperformance electrochemical sensing platform for simultaneous determination of hydroquinone, catechol and resorcinol was constructed based on the signal enhancement effect of CS-Na₂CO₃. The linear ranges for simultaneous determination of hydroquinone, catechol and resorcinol were 0.050-1.5 μmol/L,0.050-1.5 μmol/L and 0.50-15 μmol/L, and the detection limits (3σ) were calculated to be 0.012, 0.017 and 0.29 μmol/L, respectively. The prepared sensing platform demonstrated good accuracy in detection of dihydroxybenzene isomers in river water samples.
- Activators,
- Hierarchically porous carbon materials,
- Electrochemical sensing,
- Structure-activity relationship,
- Dihydroxybenzene isomers
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