采用不同活化剂制备分级多孔碳用于二羟基苯异构体的电化学传感分析

韦良 黄信龙 王彦力 杨晶 闫飞燕 宁德娇 唐莉 罗丽红 韦宇宁 牙禹

引用本文: 韦良, 黄信龙, 王彦力, 杨晶, 闫飞燕, 宁德娇, 唐莉, 罗丽红, 韦宇宁, 牙禹. 采用不同活化剂制备分级多孔碳用于二羟基苯异构体的电化学传感分析[J]. 分析化学, 2022, 50(6): 899-911. doi: 10.19756/j.issn.0253-3820.221048 shu
Citation:  WEI Liang,  HUANG Xin-Long,  WANG Yan-Li,  YANG Jing,  YAN Fei-Yan,  NING De-Jiao,  TANG Li,  LUO Li-Hong,  WEI Yu-Ning,  YA Yu. Preparation of Hierarchically Porous Carbon Using Different Activators and Its Electrochemical Sensing of Dihydroxybenzene Isomers[J]. Chinese Journal of Analytical Chemistry, 2022, 50(6): 899-911. doi: 10.19756/j.issn.0253-3820.221048 shu

采用不同活化剂制备分级多孔碳用于二羟基苯异构体的电化学传感分析

    通讯作者: 牙禹,E-mail:yayu1026@163.com
  • 基金项目:

    国家自然科学基金项目(No.21862004)、广西自然科学基金项目(Nos.2018GXNSFAA281230,2018GXNSFAA281228)、“科技先锋队‘强农富民’‘六个一’专项行动”桂科盟项目(No.202216)、广西农科院优势学科团队项目(No.2021YT136)和广西研究生教育创新计划项目(YCSW2020193)资助。

摘要: 以壳聚糖(CS)为碳源,分别以NaCl、Na2CO3和NaOH为活化剂,制备了分级多孔碳材料,采用扫描电镜、X射线衍射、拉曼光谱、N2吸附-脱附等技术对其形貌、结构、比表面积及孔径分布进行研究;采用电化学技术研究不同碳材料修饰电极的电化学性能,探究材料的形貌结构和理化参数与碳材料电化学传感性能之间的构效关系。研究结果表明,以Na2CO3为活化剂制备的分级多孔碳材料(CS-Na2CO3)修饰电极具有更大的电化学活性面积和更快的电子转移速率,并对3种二羟基苯异构体(对苯二酚、邻苯二酚和间苯二酚)表现出更优异的电催化性能。基于CS-Na2CO3的电化学信号增强作用,构建了一种对苯二酚、邻苯二酚和间苯二酚连续测定的电化学传感平台,3种分析物的氧化峰电流与浓度分别在0.050~1.5 μmol/L、0.050~1.5 μmol/L和0.50~15 μmol/L范围内呈线性关系,检出限(3σ)分别为0.012、0.017和0.29 μmol/L。将本传感平台用于江水样品分析,展示出良好的准确度。

English


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  • 收稿日期:  2022-01-24
  • 修回日期:  2022-03-30
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