基于掺硼金刚石电极的磷酸盐电化学传感器

引用本文: 徐钰豪, 卫胜男, 王月坤, 熊晨雨, 谢勇, 韩明杰, 王日, 边超, 夏善红. 基于掺硼金刚石电极的磷酸盐电化学传感器[J]. 分析化学, 2022, 50(6): 889-898. doi: 10.19756/j.issn.0253-3820.221039 shu

Citation: XU Yu-Hao, WEI Sheng-Nan, WANG Yue-Kun, XIONG Chen-Yu, XIE Yong, HAN Ming-Jie, WANG Ri, BIAN Chao, XIA Shan-Hong. Electrochemical Sensor Based on Boron-Doped Diamond Electrode for Determination of Phosphate[J]. Chinese Journal of Analytical Chemistry, 2022, 50(6): 889-898. doi: 10.19756/j.issn.0253-3820.221039 shu

基于掺硼金刚石电极的磷酸盐电化学传感器

徐钰豪 ^1,2, ,
卫胜男 ^1,2, ,
王月坤 ^1,2, ,
熊晨雨 ^1,2, ,
谢勇 ^1,2, ,
韩明杰 ^1,2, ,
王日 ^1,2, ,
边超 ^{1,
,} ,
夏善红 ^{1,
,}

1.
中国科学院空天信息创新研究院, 传感技术联合国家重点实验室, 北京 100190;
2.
中国科学院大学电子电气与通信工程学院, 北京 100049

通讯作者: 边超,E-mail:cbian@mail.ie.ac.cn; 夏善红,E-mail:shxia@mail.ie.ac.cn

基金项目:
国家重点研发计划项目（No.2020YFB2009003）资助。

摘要: 磷污染是导致水体富营养化的主要因素之一，磷酸盐已成为我国地表水质标准中的一个重要指标。针对磷酸盐检测需求，本研究研制了一种基于掺硼金刚石电极的磷酸盐电化学传感器，通过检测磷酸盐与钼酸盐络合物的电化学还原反应，实现了对水中磷酸盐的检测。本传感器采用方波脉冲伏安法，可在较宽的浓度范围内实现对磷酸盐的检测，在0.4~5.0μmol/L和5.0~80.0μmol/L范围内呈分段线性关系，灵敏度分别为301和97 nA·L/μmol，具有较低的检出限（0.1μmol/L）。本电化学传感器对磷酸盐检测表现出较好的抗干扰性，检测实际水样的回收率为93.8%~104.5%。研制的掺硼金刚石电极无需修饰和还原试剂即可对磷钼酸盐络合物表现出较强的催化还原性能，与现有磷酸盐检测方法相比减少了反应试剂使用量，检测过程更绿色环保，具有长期在线监测的应用潜力。

关键词:

English

Electrochemical Sensor Based on Boron-Doped Diamond Electrode for Determination of Phosphate

1.
State Key Laboratory of Transducer Technology, Aerospace Information Research Institute, Chinese Academy of Sciences, Beijing 100190, China;
2.
School of Electronic, Electrical and Communication Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: BIAN Chao, ; XIA Shan-Hong,

Received Date: 20 January 2022
Revised Date: 02 April 2022
Fund Project:
Supported by the National Key Research and Development Program of China(No. 2020YFB2009003).

Abstract: Phosphorus is an important indicator in surface water quality standards. Excessive phosphate can lead to eutrophication, so it is necessary to develop an accurate and sensitive method for detection of phosphate in water. In this work, an electrochemical sensor based on boron-doped diamond electrode was developed to achieve sensitive detection of phosphate in water through electrochemical reduction of phosphomolybdate. The sensor achieved excellent performances in detection of phosphate, including wide detection range, high sensitivities(0.301 nA·L/μmol in the range of 0.4-5.0 μmol/L, and 97 nA·L/μmol in the range of 5.0-80.0 μmol/L), and low limit of detection(0.1 μmol/L). Meanwhile, the electrochemical sensor showed good anti-interference ability for phosphate detection, and the recoveries of phosphate in tap and lake water sample were 93.8%-104.5%. Compared with standard spectrophotometry, the electrochemical detection process was environmentally friendly with less usage of reagents. The sensor displayed excellent catalytic properties for detection of phosphate without electrode modification, and had potential for long-term online monitoring of phosphate.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

基于掺硼金刚石电极的磷酸盐电化学传感器

通讯作者: 边超,E-mail:cbian@mail.ie.ac.cn; 夏善红,E-mail:shxia@mail.ie.ac.cn

English

Electrochemical Sensor Based on Boron-Doped Diamond Electrode for Determination of Phosphate

Corresponding author: BIAN Chao, ; XIA Shan-Hong,

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CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

基于掺硼金刚石电极的磷酸盐电化学传感器

通讯作者: 边超,E-mail:cbian@mail.ie.ac.cn; 夏善红,E-mail:shxia@mail.ie.ac.cn

English

Electrochemical Sensor Based on Boron-Doped Diamond Electrode for Determination of Phosphate

Corresponding author: BIAN Chao, ; XIA Shan-Hong,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs