基于掺硼金刚石电极的磷酸盐电化学传感器

徐钰豪 卫胜男 王月坤 熊晨雨 谢勇 韩明杰 王日 边超 夏善红

引用本文: 徐钰豪, 卫胜男, 王月坤, 熊晨雨, 谢勇, 韩明杰, 王日, 边超, 夏善红. 基于掺硼金刚石电极的磷酸盐电化学传感器[J]. 分析化学, 2022, 50(6): 889-898. doi: 10.19756/j.issn.0253-3820.221039 shu
Citation:  XU Yu-Hao,  WEI Sheng-Nan,  WANG Yue-Kun,  XIONG Chen-Yu,  XIE Yong,  HAN Ming-Jie,  WANG Ri,  BIAN Chao,  XIA Shan-Hong. Electrochemical Sensor Based on Boron-Doped Diamond Electrode for Determination of Phosphate[J]. Chinese Journal of Analytical Chemistry, 2022, 50(6): 889-898. doi: 10.19756/j.issn.0253-3820.221039 shu

基于掺硼金刚石电极的磷酸盐电化学传感器

    通讯作者: 边超,E-mail:cbian@mail.ie.ac.cn; 夏善红,E-mail:shxia@mail.ie.ac.cn
  • 基金项目:

    国家重点研发计划项目(No.2020YFB2009003)资助。

摘要: 磷污染是导致水体富营养化的主要因素之一,磷酸盐已成为我国地表水质标准中的一个重要指标。针对磷酸盐检测需求,本研究研制了一种基于掺硼金刚石电极的磷酸盐电化学传感器,通过检测磷酸盐与钼酸盐络合物的电化学还原反应,实现了对水中磷酸盐的检测。本传感器采用方波脉冲伏安法,可在较宽的浓度范围内实现对磷酸盐的检测,在0.4~5.0μmol/L和5.0~80.0μmol/L范围内呈分段线性关系,灵敏度分别为301和97 nA·L/μmol,具有较低的检出限(0.1μmol/L)。本电化学传感器对磷酸盐检测表现出较好的抗干扰性,检测实际水样的回收率为93.8%~104.5%。研制的掺硼金刚石电极无需修饰和还原试剂即可对磷钼酸盐络合物表现出较强的催化还原性能,与现有磷酸盐检测方法相比减少了反应试剂使用量,检测过程更绿色环保,具有长期在线监测的应用潜力。

English


    1. [1]

      SMITH V H. Environ. Sci. Pollut. Res., 2003, 10(2):126-139.SMITH V H. Environ. Sci. Pollut. Res., 2003, 10(2):126-139.

    2. [2]

      TIESSEN H. Phosphorus in the Global Environment, 2008:1-7.TIESSEN H. Phosphorus in the Global Environment, 2008:1-7.

    3. [3]

      GB 3838-2002. Environmental Quality Standards for Surface Water. National Standards of the People's Republic of China.地表水环境质量标准.中华人民共和国国家标准. GB 3838-2002.

    4. [4]

      RUIZ-CALERO V, GALCERAN M T. Talanta, 2005, 66(2):376-410.RUIZ-CALERO V, GALCERAN M T. Talanta, 2005, 66(2):376-410.

    5. [5]

      KROECKEL L, LEHMANN H, WIEDUWILT T, SCHMIDT M A. Talanta, 2014, 125:107-113.KROECKEL L, LEHMANN H, WIEDUWILT T, SCHMIDT M A. Talanta, 2014, 125:107-113.

    6. [6]

      LIU W, DU Z, QIAN Y, LI F. Sens. Actuators, B, 2013, 176:927-931.LIU W, DU Z, QIAN Y, LI F. Sens. Actuators, B, 2013, 176:927-931.

    7. [7]

      UDNAN Y, MCKELVIE I D, GRACE M R, JAKMUNEE J, GRUDPAN K. Talanta, 2005, 66(2):461-466.UDNAN Y, MCKELVIE I D, GRACE M R, JAKMUNEE J, GRUDPAN K. Talanta, 2005, 66(2):461-466.

    8. [8]

      GB/T 11893-1989. Water Quality-Determination of Total Phosphorus-Ammonium Molybdate Spectrophotometric Method. National Standards of the People's Republic of China.水质总磷的测定钼酸铵分光光度法.中华人民共和国国家标准. GB/T 11893-1989.

    9. [9]

      MURPHY J, RILEY J P. Anal. Chim. Acta, 1962, 26(1):31.MURPHY J, RILEY J P. Anal. Chim. Acta, 1962, 26(1):31.

    10. [10]

      LI Y, JIANG T, YU X, YANG H. J. Electrochem. Soc., 2016, 163(9):B479-B484.LI Y, JIANG T, YU X, YANG H. J. Electrochem. Soc., 2016, 163(9):B479-B484.

    11. [11]

      KARGOSHA K, HEMMATKHAH P, AHMADI S H. Anal. Bioanal. Electrochem., 2017, 9(5):521-534.KARGOSHA K, HEMMATKHAH P, AHMADI S H. Anal. Bioanal. Electrochem., 2017, 9(5):521-534.

    12. [12]

      KOLLIOPOULOS A V, KAMPOURIS D K, BANKS C E. Anal. Chem., 2015, 87(8):4269-4274.KOLLIOPOULOS A V, KAMPOURIS D K, BANKS C E. Anal. Chem., 2015, 87(8):4269-4274.

    13. [13]

      TALARICO D, ARDUINI F, AMINE A, MOSCONE D, PALLESCHI G. Talanta, 2015, 141:267-272.TALARICO D, ARDUINI F, AMINE A, MOSCONE D, PALLESCHI G. Talanta, 2015, 141:267-272.

    14. [14]

      CINTI S, TALARICO D, PALLESCHI G, MOSCONE D, ARDUINI F. Anal. Chim. Acta, 2016, 919:78-84.CINTI S, TALARICO D, PALLESCHI G, MOSCONE D, ARDUINI F. Anal. Chim. Acta, 2016, 919:78-84.

    15. [15]

      KABIR M, RAHMAN M, GURUNG A, QIAO Q. IEEE Sens. J., 2018, 18(9):3480-3485.KABIR M, RAHMAN M, GURUNG A, QIAO Q. IEEE Sens. J., 2018, 18(9):3480-3485.

    16. [16]

      MATSUNAGA K, KUDO I, YANADA M, HASEBE K. Anal. Chim. Acta, 1986, 185:355-358.MATSUNAGA K, KUDO I, YANADA M, HASEBE K. Anal. Chim. Acta, 1986, 185:355-358.

    17. [17]

      BERCHMANS S, KARTHIKEYAN R, GUPTA S, POINERN G E J, ISSA T B, SINGH P. Sens. Actuators, B, 2011, 160(1):1224-1231.BERCHMANS S, KARTHIKEYAN R, GUPTA S, POINERN G E J, ISSA T B, SINGH P. Sens. Actuators, B, 2011, 160(1):1224-1231.

    18. [18]

      JONCA J, LEON FERNANDEZ V, THOURON D, PAULMIER A, GRACO M, GARCON V. Talanta, 2011, 87:161-167.JONCA J, LEON FERNANDEZ V, THOURON D, PAULMIER A, GRACO M, GARCON V. Talanta, 2011, 87:161-167.

    19. [19]

      BAI Y, TONG J, WANG J, BIAN C, XIA S. IET Nanobiotechnol., 2014, 8(1):31-36.BAI Y, TONG J, WANG J, BIAN C, XIA S. IET Nanobiotechnol., 2014, 8(1):31-36.

    20. [20]

      SATOH H, MIYAZAKI Y, TANIUCHI S, OSHIKI M, RATHNAYAKE R M L D, TAKAHASHI M, OKABE S.Anal. Sci., 2017, 33(7):825-830.SATOH H, MIYAZAKI Y, TANIUCHI S, OSHIKI M, RATHNAYAKE R M L D, TAKAHASHI M, OKABE S.Anal. Sci., 2017, 33(7):825-830.

    21. [21]

      TOPCU C, CAGLAR B, ONDER A, COLDUR F, CAGLAR S, GUNER E, CUBUK O, TABAK A. Mater. Res.Bull., 2018, 98:288-299.TOPCU C, CAGLAR B, ONDER A, COLDUR F, CAGLAR S, GUNER E, CUBUK O, TABAK A. Mater. Res.Bull., 2018, 98:288-299.

    22. [22]

      OGABIELA E, ADELOJU S B, CUI J, WU Y, CHEN W. Biosens. Bioelectron., 2015, 71:278-285.OGABIELA E, ADELOJU S B, CUI J, WU Y, CHEN W. Biosens. Bioelectron., 2015, 71:278-285.

    23. [23]

      HE B, LIU H. Sens. Actuators, B, 2020, 304:127303.HE B, LIU H. Sens. Actuators, B, 2020, 304:127303.

    24. [24]

      LUONG J H T, MALE K B, GLENNON J D. Analyst, 2009, 134:1965-1979.LUONG J H T, MALE K B, GLENNON J D. Analyst, 2009, 134:1965-1979.

    25. [25]

      PEREIRA G F, ANDRADE L S, ROCHA-FILHO R C, BOCCHI N, BIAGGIO S R. Electrochim. Acta, 2012, 82:3-8.PEREIRA G F, ANDRADE L S, ROCHA-FILHO R C, BOCCHI N, BIAGGIO S R. Electrochim. Acta, 2012, 82:3-8.

    26. [26]

      BROCENSCHI R F, SILVA T A, LOURENCAO B C, FATIBELLO-FILHO O, ROCHA-FILHO R C. Electrochim.Acta, 2017, 243:374-381.BROCENSCHI R F, SILVA T A, LOURENCAO B C, FATIBELLO-FILHO O, ROCHA-FILHO R C. Electrochim.Acta, 2017, 243:374-381.

    27. [27]

      SCREMIN J, SARTORI E R. Can. J. Chem., 2018, 96(1):1-7.SCREMIN J, SARTORI E R. Can. J. Chem., 2018, 96(1):1-7.

    28. [28]

      HONORIO G G, AZEVEDO G C, COSTA MATOS M A, DE OLIVEIRA M A L, MATOS R C. Food Control, 2014, 36(1):42-48.HONORIO G G, AZEVEDO G C, COSTA MATOS M A, DE OLIVEIRA M A L, MATOS R C. Food Control, 2014, 36(1):42-48.

    29. [29]

      GUO Y, HUANG N, YANG B, WANG C, ZHUANG H, TIAN Q, ZHAI Z, LIU L, JIANG X. Sens. Actuators, B, 2016, 231:194-202.GUO Y, HUANG N, YANG B, WANG C, ZHUANG H, TIAN Q, ZHAI Z, LIU L, JIANG X. Sens. Actuators, B, 2016, 231:194-202.

    30. [30]

      MCLAUGHLIN M H S, PAKPOUR-TABRIZI A C, JACKMAN R B. Electroanalysis, 2019, 31(9):1775-1782.MCLAUGHLIN M H S, PAKPOUR-TABRIZI A C, JACKMAN R B. Electroanalysis, 2019, 31(9):1775-1782.

    31. [31]

      ASAI K, IVANDINI T A, FALAH M M, EINAGA Y. Electroanalysis, 2016, 28(1):177-182.ASAI K, IVANDINI T A, FALAH M M, EINAGA Y. Electroanalysis, 2016, 28(1):177-182.

    32. [32]

      PRAYIKAPUTRI P U, GUNLAZUARDI J, IVANDINI T A. International Symposium on Current Progress in Functional Materialsed. Bali, INDONESIA 2016.PRAYIKAPUTRI P U, GUNLAZUARDI J, IVANDINI T A. International Symposium on Current Progress in Functional Materialsed. Bali, INDONESIA 2016.

    33. [33]

      YANG Z, LI M, LI H, LI H, LI C, YANG B. Anal. Chim. Acta, 2020, 1135:73-82.YANG Z, LI M, LI H, LI H, LI C, YANG B. Anal. Chim. Acta, 2020, 1135:73-82.

    34. [34]

      GAO Cheng-Yao, TONG Jian-Hua, BIAN Chao, SUN Ji-Zhou, LI Yang, WANG Jin-Fen, GONG Shun, HUI Yun, XU Yu-Hao, WANG Xiao-Qing, XIE Hu-Cheng, XIA Shan-Hong. Chin. J. Anal. Chem., 2018, 46(2):217-224.高成耀, 佟建华, 边超, 孙楫舟, 李洋, 王晋芬, 龚顺, 惠允, 徐钰豪, 王晓青, 谢虎成, 夏善红.分析化学, 2018, 46(2):217-224.

    35. [35]

      WARWICK C, GUERREIRO A, SOARES A. Biosens. Bioelectron., 2013, 41:1-11.WARWICK C, GUERREIRO A, SOARES A. Biosens. Bioelectron., 2013, 41:1-11.

    36. [36]

      LU G, WU X, LAN Y, YAO S. Talanta, 1999, 49(3):511-515.LU G, WU X, LAN Y, YAO S. Talanta, 1999, 49(3):511-515.

    37. [37]

      TORREZANI L, SACZK A A, DE OLIVEIRA M F, STRADIOTTO N R, OKUMURA L L. Electroanalysis, 2011, 23(10):2456-2461.TORREZANI L, SACZK A A, DE OLIVEIRA M F, STRADIOTTO N R, OKUMURA L L. Electroanalysis, 2011, 23(10):2456-2461.

    38. [38]

      TALARICO D, CINTI S, ARDUINI F, AMINE A, MOSCONE D, PALLESCHI G. Environ. Sci. Technol., 2015, 49(13):7934-7939.TALARICO D, CINTI S, ARDUINI F, AMINE A, MOSCONE D, PALLESCHI G. Environ. Sci. Technol., 2015, 49(13):7934-7939.

    39. [39]

      ARVAS M B, GURSU H, GENCTEN M, SAHIN Y. Anal. Methods, 2018, 10(35):4282-4291.ARVAS M B, GURSU H, GENCTEN M, SAHIN Y. Anal. Methods, 2018, 10(35):4282-4291.

    40. [40]

      QUINTANA J C, IDRISSI L, PALLESCHI G, ALBERTANO P, AMINE A, EL RHAZI M, MOSCONE D. Talanta, 2004, 63(3):567-574.QUINTANA J C, IDRISSI L, PALLESCHI G, ALBERTANO P, AMINE A, EL RHAZI M, MOSCONE D. Talanta, 2004, 63(3):567-574.

  • 加载中
计量
  • PDF下载量:  1
  • 文章访问数:  224
  • HTML全文浏览量:  37
文章相关
  • 收稿日期:  2022-01-20
  • 修回日期:  2022-04-02
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章