基于Nafion管-高场不对称波形离子迁移谱的环境湿度下硫化氢快速检测方法

李山 陈圳 刘昌杰 金娇 王晗 胡俊 马贺 史家亮 任谦 程玉鹏 刘友江 陈池来

引用本文: 李山, 陈圳, 刘昌杰, 金娇, 王晗, 胡俊, 马贺, 史家亮, 任谦, 程玉鹏, 刘友江, 陈池来. 基于Nafion管-高场不对称波形离子迁移谱的环境湿度下硫化氢快速检测方法[J]. 分析化学, 2022, 50(6): 924-931. doi: 10.19756/j.issn.0253-3820.221019 shu
Citation:  LI Shan,  CHEN Zhen,  LIU Chang-Jie,  JIN Jiao,  WANG Han,  HU Jun,  MA He,  SHI Jia-Liang,  REN Qian,  CHENG Yu-Peng,  LIU You-Jiang,  CHEN Chi-Lai. Rapid Detection of Hydrogen Sulfide Gas at Ambient Humidity Based on Nafion-High-Field Asymmetric Waveform Ion Mobility Spectrometry Technology[J]. Chinese Journal of Analytical Chemistry, 2022, 50(6): 924-931. doi: 10.19756/j.issn.0253-3820.221019 shu

基于Nafion管-高场不对称波形离子迁移谱的环境湿度下硫化氢快速检测方法

    通讯作者: 刘友江,E-mail:liuyoujiang@iim.ac.cn; 陈池来,E-mail:chlchen@iim.ac.cn
  • 基金项目:

    国家自然科学基金项目(Nos.61871367,41805017)、中国科学院青年创新促进会项目(No.2013213)、中央高校基本科研业务费专项资金项目(No.WK5290000002)和中国科学院合肥物质科学院双创基金项目(No.KY-2021-SC-05)资助。

摘要: 高场不对称波形离子迁移谱(FAIMS)是一种快速、灵敏度高的现场检测技术,但利用其检测极性物质时极易受湿度的影响。Nafion管可选择性地快速滤除水汽,基于此本研究提出了适用于环境湿度下硫化氢(H2S)气体快速检测的nafion-FAIMS技术。采用自制的nafion-FAIMS装置,研究了不同湿度条件下nafion-FAIMS技术检测H2S的稳定性,以及典型环境干扰物存在条件下的H2S分离识别能力、定量检测线性度和检出限。结果表明,当相对湿度为5%~50%时,H2S的nafion-FAIMS谱图峰位置和峰高RSD分别小于0.4%和0.2%,比单一的FAIMS技术分别小10倍和250倍,表现出极高的识别和定量检测稳定性。在分离电压为1200 V条件下,苯与H2S混合气体谱图的峰高和峰位置与单一物质的相对偏差仅为0.7%和2.0%,说明nafion-FAIMS技术对现场混合物检测具有良好的适应性。利用nafion-FAIMS技术检测浓度为0.08~0.46 mg/m3的H2S气体样品,其信号线性度达到0.98,检出限低至0.04 mg/m3

English


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  • 收稿日期:  2022-01-12
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