基于Nafion管-高场不对称波形离子迁移谱的环境湿度下硫化氢快速检测方法

引用本文: 李山, 陈圳, 刘昌杰, 金娇, 王晗, 胡俊, 马贺, 史家亮, 任谦, 程玉鹏, 刘友江, 陈池来. 基于Nafion管-高场不对称波形离子迁移谱的环境湿度下硫化氢快速检测方法[J]. 分析化学, 2022, 50(6): 924-931. doi: 10.19756/j.issn.0253-3820.221019 shu

Citation: LI Shan, CHEN Zhen, LIU Chang-Jie, JIN Jiao, WANG Han, HU Jun, MA He, SHI Jia-Liang, REN Qian, CHENG Yu-Peng, LIU You-Jiang, CHEN Chi-Lai. Rapid Detection of Hydrogen Sulfide Gas at Ambient Humidity Based on Nafion-High-Field Asymmetric Waveform Ion Mobility Spectrometry Technology[J]. Chinese Journal of Analytical Chemistry, 2022, 50(6): 924-931. doi: 10.19756/j.issn.0253-3820.221019 shu

基于Nafion管-高场不对称波形离子迁移谱的环境湿度下硫化氢快速检测方法

李山 ^1,2, ,
陈圳 ^1,2, ,
刘昌杰 ^1, ,
金娇 ^1,2, ,
王晗 ^1,2, ,
胡俊 ^1,2, ,
马贺 ^1,2, ,
史家亮 ^3, ,
任谦 ^3, ,
程玉鹏 ^1,2, ,
刘友江 ^{1,
,} ,
陈池来 ^{1,
,}

1.
中国科学院合肥物质科学研究院, 合肥 230031;
2.
中国科学技术大学, 合肥 230026;
3.
中国石化北京燕山分公司, 北京 102500

通讯作者: 刘友江,E-mail:liuyoujiang@iim.ac.cn; 陈池来,E-mail:chlchen@iim.ac.cn

基金项目:
国家自然科学基金项目（Nos.61871367，41805017）、中国科学院青年创新促进会项目（No.2013213）、中央高校基本科研业务费专项资金项目（No.WK5290000002）和中国科学院合肥物质科学院双创基金项目（No.KY-2021-SC-05）资助。

摘要: 高场不对称波形离子迁移谱（FAIMS）是一种快速、灵敏度高的现场检测技术，但利用其检测极性物质时极易受湿度的影响。Nafion管可选择性地快速滤除水汽，基于此本研究提出了适用于环境湿度下硫化氢（H₂S）气体快速检测的nafion-FAIMS技术。采用自制的nafion-FAIMS装置，研究了不同湿度条件下nafion-FAIMS技术检测H₂S的稳定性，以及典型环境干扰物存在条件下的H₂S分离识别能力、定量检测线性度和检出限。结果表明，当相对湿度为5%~50%时，H₂S的nafion-FAIMS谱图峰位置和峰高RSD分别小于0.4%和0.2%，比单一的FAIMS技术分别小10倍和250倍，表现出极高的识别和定量检测稳定性。在分离电压为1200 V条件下，苯与H₂S混合气体谱图的峰高和峰位置与单一物质的相对偏差仅为0.7%和2.0%，说明nafion-FAIMS技术对现场混合物检测具有良好的适应性。利用nafion-FAIMS技术检测浓度为0.08~0.46 mg/m³的H₂S气体样品，其信号线性度达到0.98，检出限低至0.04 mg/m³。

关键词:

English

Rapid Detection of Hydrogen Sulfide Gas at Ambient Humidity Based on Nafion-High-Field Asymmetric Waveform Ion Mobility Spectrometry Technology

1.
Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, China;
2.
University of Science and Technology of China, Hefei 230026, China;
3.
INOPEC Beijing Yanshan Company, Beijing 102500, China

Corresponding author: LIU You-Jiang, ; CHEN Chi-Lai,

Received Date: 12 January 2022
Revised Date: 21 March 2022
Fund Project:
Supported by the National Natural Science Foundation of China(Nos. 61871367, 41805017), the Youth Innovation Promotion Association of Chinese Academy of Sciences(No. 2013213), the Fundamental Research Funds for the Central Universities(No. WK5290000002), and the Chinese Academy of Sciences Hefei Institute of Material Science Double Innovation Fund(No. KY-2021-SC-05).

Abstract: High-field asymmetric waveform ion mobility spectrometry(FAIMS) is a fast and sensitive field detection technology, but the detection of polar substances using FAIMS is easily affected by humidity. Based on that nafion tube could selectively and quickly filter water gas, a nafion-FAIMS technology was proposed for rapid detection of environmental hydrogen sulfide(H₂S) gas under ambient humidity in this work. The self-made nafion-FAIMS device was used to study the stability of nafionFAIMS in detection of H₂S under different humidity conditions, the separation and identification ability of H₂S in the presence of typical environmental interferents, the linearity and the detection limit. The results showed that when the relative humidity was 5%-50%, the relative standard deviations(RSDs) of peak position and peak height of H₂S spectrum were less than 0.4% and 0.2%, respectively, which were 10 times and 250 times smaller than that of single FAIMS, showing high recognition and quantitative stability. When the dispersion voltage was 1200 V, the relative deviation of peak height and peak position between benzene and H₂S mixed gas spectrum and single substance were only 0.7% and 2%, indicating the adaptability of nafion-FAIMS to mixture detection. The signal linearity reached 98% in the H₂S concentration range of 0.08-0.46 mg/m³, and the detection limit was 0.04 mg/m³.

Key words:

Hydrogen sulfide
/ High-field asymmetric waveform ion mobility spectrometry
/ Humidity
/ Field detection

1. [1]
  CHEN Zhong-Hui, CHEN Yu, WENG Ai-Bin, LUO Fang, GUO Long-Hua, QIU Bin, LIN Zhen-Yu, CHEN GuoNan. Chin. J. Anal. Chem., 2019, 47(10):1572-1579.陈仲辉, 陈宇, 翁爱彬, 罗芳, 郭隆华, 邱彬, 林振宇, 陈国南.分析化学, 2019, 47(10):1572-1579.
2. [2]
  MARUTANI E, ICHINOSE F. Intensive Care Med. Exp., 2020, 8(1):5.MARUTANI E, ICHINOSE F. Intensive Care Med. Exp., 2020, 8(1):5.
3. [3]
  GUO Zai-Fu, DENG Yun-Feng, JIANG Tian-Han, WANG Jian-Guang, XI Xue-Jun. J. Saf. Sci. Technol., 2008, 4(3):18-21.郭再富, 邓云峰, 江田汉, 王建光, 席学军.中国安全生产科学技术, 2008, 4(3):18-21.
4. [4]
  ZHAO C, GUO L, DONG J Y, CAI Z W. The Innovation, 2021, 2(4):100151.ZHAO C, GUO L, DONG J Y, CAI Z W. The Innovation, 2021, 2(4):100151.
5. [5]
  ZHI Jian-Ning, LI Yan-Ru. Chin. J. Anal. Lab., 2016, 35(6):713-716.智建宁, 李雁如.分析试验室, 2016, 35(6):713-716.
6. [6]
  PANDEY S K, KIM K H, TANG K T. TrAC-Trends Anal. Chem., 2012, 32:87-99.PANDEY S K, KIM K H, TANG K T. TrAC-Trends Anal. Chem., 2012, 32:87-99.
7. [7]
  ALI F I M, AWWAD F, GREISH Y E, MAHMOUD S T. IEEE Sens. J., 2019, 19(7):2394-2407.ALI F I M, AWWAD F, GREISH Y E, MAHMOUD S T. IEEE Sens. J., 2019, 19(7):2394-2407.
8. [8]
  KUMAR V, MAJHI S M, KIM K H, KIM H W, KWON E E. Chem. Eng. J., 2021, 404:126472.KUMAR V, MAJHI S M, KIM K H, KIM H W, KWON E E. Chem. Eng. J., 2021, 404:126472.
9. [9]
  DU X X, MOU J H, ZENG H D, ZENG R S, JIANG Y R, LI H. Anal. Lett., 2021, 54(8):1377-1388.DU X X, MOU J H, ZENG H D, ZENG R S, JIANG Y R, LI H. Anal. Lett., 2021, 54(8):1377-1388.
10. [10]
  HUO J, XU S, LAM K P. Cells, 2019, 8(6):541.HUO J, XU S, LAM K P. Cells, 2019, 8(6):541.
11. [11]
  KOLAKOWSKII B M, MESTER Z. Analyst, 2007, 132(9):842-864.KOLAKOWSKII B M, MESTER Z. Analyst, 2007, 132(9):842-864.
12. [12]
  EICEMAN G A, KRYLOV E V, KRYLOVA N S. Anal. Chem., 2004, 76(17):4937-4944.EICEMAN G A, KRYLOV E V, KRYLOVA N S. Anal. Chem., 2004, 76(17):4937-4944.
13. [13]
  WANG Q, XIE Y F, ZHAO W J, LI P, QIAN H, WANG X Z. Anal. Methods, 2014, 6(9):2965-2972.WANG Q, XIE Y F, ZHAO W J, LI P, QIAN H, WANG X Z. Anal. Methods, 2014, 6(9):2965-2972.
14. [14]
  SMITH R W, TOUTOUNGI D E, REYNOLDS J C, BRISTOW A W T, RAY A, SAGE A, WILSON I D, WESTON D J, BOYLE B, CREASER C S. J. Chromatogr. A, 2013, 1278:76-81.SMITH R W, TOUTOUNGI D E, REYNOLDS J C, BRISTOW A W T, RAY A, SAGE A, WILSON I D, WESTON D J, BOYLE B, CREASER C S. J. Chromatogr. A, 2013, 1278:76-81.
15. [15]
  CHEN Chi-Lai, ZHAO Cong, WANG Dian-Ling, CHENG Yu-Peng, KONG De-Yi, WANG Huan-Qin, GAO Jun, GAO Li-Sheng, LIN Xin-Hua, WANG Ying-Xian, YIN Shi-Ping, ZHANG Rui. Micronanoelectron. Technol., 2011, 48(2):112-117.陈池来, 赵聪, 王电令, 程玉鹏, 孔德义, 王焕钦, 高钧, 高理升, 林新华, 王英先, 殷世平, 张瑞.微纳电子技术, 2011, 48(2):112-117.
16. [16]
  LI Zhuang, LIN Bing-Tao, CHEN Chi-Lai, LIU Ying, KONG De-Yi, CHENG Yu-Peng, WANG Dian-Ling, WANG Huan-Qin. Chin. J. Anal. Chem., 2011, 39(1):107-110.李庄, 林丙涛, 陈池来, 刘英, 孔德义, 程玉鹏, 王电令, 王焕钦.分析化学, 2011, 39(1):107-110.
17. [17]
  JIANG D D, LI E Y, ZHOU Q H, WANG X, LI H W, JU B Y, GUO L, LIU D S, LI H Y. Anal. Chem., 2018, 90(8):5280-5289.JIANG D D, LI E Y, ZHOU Q H, WANG X, LI H W, JU B Y, GUO L, LIU D S, LI H Y. Anal. Chem., 2018, 90(8):5280-5289.
18. [18]
  DANG M, LIU R D, DONG F S, LIU B, HOU K Y. TrAC-Trends Anal. Chem., 2022, 149:116542.DANG M, LIU R D, DONG F S, LIU B, HOU K Y. TrAC-Trends Anal. Chem., 2022, 149:116542.
19. [19]
  LIU You-Jiang, CHEN Chi-Lai, ZHANG Le-Hua, ZHANG Xiao-Tian, WANG Hong-Wei, KONG De-Yi. Chin.J. Anal. Chem., 2014, 42(9):1259-1263.刘友江, 陈池来, 张乐华, 张晓天, 王泓伟, 孔德义.分析化学, 2014, 42(9):1259-1263.
20. [20]
  LI H, WANG X H, TANG F, YANG J, DING L. Chin. J. Chem. Phys., 2010, 23(2):125-132.LI H, WANG X H, TANG F, YANG J, DING L. Chin. J. Chem. Phys., 2010, 23(2):125-132.
21. [21]
  AKSENOV A A, PASAMONTES A, PEIRANO D J, ZHAO W X, DANDEKAR A M, FIEHN O, EHSANI R, DAVIS C E. Anal. Chem., 2014, 86(5):2481-2488.AKSENOV A A, PASAMONTES A, PEIRANO D J, ZHAO W X, DANDEKAR A M, FIEHN O, EHSANI R, DAVIS C E. Anal. Chem., 2014, 86(5):2481-2488.
22. [22]
  WANG H, LIU Y, LI S, WANG X, DENG J, CHEN C. Int. J. Mass Spectrom., 2019, 442:7-13.WANG H, LIU Y, LI S, WANG X, DENG J, CHEN C. Int. J. Mass Spectrom., 2019, 442:7-13.
23. [23]
  ZHANG W, HUO F, YIN C. Org. Lett., 2019, 21(13):5277-5280.ZHANG W, HUO F, YIN C. Org. Lett., 2019, 21(13):5277-5280.
24. [24]
  KLEINHEINZ G T, ANGOLF B M. Nat. Environ. Pollut. Technol., 2016, 15(4):1279-1284.KLEINHEINZ G T, ANGOLF B M. Nat. Environ. Pollut. Technol., 2016, 15(4):1279-1284.
25. [25]
  WANG H W, CHRN C L, LIU Y J, ZHANG X T, KONG D Y, WANG X Z, LUO J K. Anal. Methods, 2015, 7(4):1401-1406.WANG H W, CHRN C L, LIU Y J, ZHANG X T, KONG D Y, WANG X Z, LUO J K. Anal. Methods, 2015, 7(4):1401-1406.
26. [26]
  SZCZUREK A, MAZIOEJUK M, MACIEJEWSKA M, PIETRUCHA T, SIKORA T. Sens. Actuators, B, 2017, 240:1237-1244.SZCZUREK A, MAZIOEJUK M, MACIEJEWSKA M, PIETRUCHA T, SIKORA T. Sens. Actuators, B, 2017, 240:1237-1244.
27. [27]
  PENG L Y, JIANG D D, WANG Z Y, HUA L, LI H Y. Talanta, 2016, 153:295-300.PENG L Y, JIANG D D, WANG Z Y, HUA L, LI H Y. Talanta, 2016, 153:295-300.
28. [28]
  FERRARIS A, MESSANA A, AIRALE A G, SISCA L, PINHEIRE H D, ZEVOLA F, CARELLO M. Energies, 2019, 12(9):1773.FERRARIS A, MESSANA A, AIRALE A G, SISCA L, PINHEIRE H D, ZEVOLA F, CARELLO M. Energies, 2019, 12(9):1773.
29. [29]
  JIN Dang-Qin, GONG Ai-Qin, DING Bang-Dong, ZHOU Hui, TIAN Lian-Sheng, HAN Lei, HUANG Wen-Jiang.Phys. Test. Chem. Anal., Part B, 2018, 54(4):393-397.金党琴, 龚爱琴, 丁邦东, 周慧, 田连生, 韩磊, 黄文江.理化检验(化学分册), 2018, 54(4):393-397.
30. [30]
  LEE J Y, DINH T V, KIM D J, CHOI I Y, AHN J W, PARK S Y, KIM J C. Asian J. Atmos. Environ., 2019, 13(4):249-258.LEE J Y, DINH T V, KIM D J, CHOI I Y, AHN J W, PARK S Y, KIM J C. Asian J. Atmos. Environ., 2019, 13(4):249-258.
31. [31]
  LI X, HUANG D D, DU R, ZHANG Z J, CHAN C K, HUANG Z X, ZHOU Z. J. Visualized Exp., 2018, (133):e56465.LI X, HUANG D D, DU R, ZHANG Z J, CHAN C K, HUANG Z X, ZHOU Z. J. Visualized Exp., 2018, (133):e56465.
32. [32]
  MAZIEJUK M, SZCZUREK A, MACIEJEWSKA M, PIETRUCHA T, SZYPOSZYNSKA M. Talanta, 2016, 152:137-146.MAZIEJUK M, SZCZUREK A, MACIEJEWSKA M, PIETRUCHA T, SZYPOSZYNSKA M. Talanta, 2016, 152:137-146.
33. [33]
  FANG P, JI Y L, SILBERN I, VINER R, OELLERICH T, PAN K T, URLAUB H. Anal. Chem., 2021, 93(25):8846-8855.FANG P, JI Y L, SILBERN I, VINER R, OELLERICH T, PAN K T, URLAUB H. Anal. Chem., 2021, 93(25):8846-8855.
34. [34]
  GB14554-1993. Discharge Standards for Malodorous Pollutants. National Standards of the People's Republic of China.恶臭污染物排放标准.中华人民共和国国家标准. GB14554-1993.

扫一扫看文章

计量

PDF下载量: 12
文章访问数: 759
HTML全文浏览量: 160

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

基于Nafion管-高场不对称波形离子迁移谱的环境湿度下硫化氢快速检测方法

通讯作者: 刘友江,E-mail:liuyoujiang@iim.ac.cn; 陈池来,E-mail:chlchen@iim.ac.cn

English

Rapid Detection of Hydrogen Sulfide Gas at Ambient Humidity Based on Nafion-High-Field Asymmetric Waveform Ion Mobility Spectrometry Technology

Corresponding author: LIU You-Jiang, ; CHEN Chi-Lai,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

基于Nafion管-高场不对称波形离子迁移谱的环境湿度下硫化氢快速检测方法

通讯作者: 刘友江,E-mail:liuyoujiang@iim.ac.cn; 陈池来,E-mail:chlchen@iim.ac.cn

English

Rapid Detection of Hydrogen Sulfide Gas at Ambient Humidity Based on Nafion-High-Field Asymmetric Waveform Ion Mobility Spectrometry Technology

Corresponding author: LIU You-Jiang, ; CHEN Chi-Lai,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs