制备Cu/CuO/ZnO/PPy异质结材料用于海水中Hg2+抗干扰检测

李铭 李正明 董晓桐 贾良宾 朱美燕 马晔 赵明岗 崔洪芝

引用本文: 李铭, 李正明, 董晓桐, 贾良宾, 朱美燕, 马晔, 赵明岗, 崔洪芝. 制备Cu/CuO/ZnO/PPy异质结材料用于海水中Hg2+抗干扰检测[J]. 分析化学, 2021, 49(9): 1497-1505. doi: 10.19756/j.issn.0253-3820.211214 shu
Citation:  LI Ming,  LI Zheng-Ming,  DONG Xiao-Tong,  JIA Liang-Bin,  ZHU Mei-Yan,  MA Ye,  ZHAO Ming-Gang,  CUI Hong-Zhi. Fabrication of Cu/CuO/ZnO/PPy Heterojunction Materials for Anti-interference Detection of Hg2+ in Seawater[J]. Chinese Journal of Analytical Chemistry, 2021, 49(9): 1497-1505. doi: 10.19756/j.issn.0253-3820.211214 shu

制备Cu/CuO/ZnO/PPy异质结材料用于海水中Hg2+抗干扰检测

    通讯作者: 赵明岗,E-mail:zhaomg@ouc.edu.cn
  • 基金项目:

    中央高校基本科研业务费专项资金项目(Nos.202042009,201964011)和国家自然科学基金项目(No.52072353)资助。

摘要: Hg2+污染对人类健康和生态环境构成重大威胁,但目前仍缺乏直接、灵敏的Hg2+检测技术。本研究通过碱性氧化法和水热法制备了Cu/CuO/ZnO丝,采用电化学聚合的方法将聚吡咯(PPy)覆盖到材料表面。利用p-n结势垒驱动电化学信号响应的原理将材料用于Hg2+的直接电化学检测,进行了微分脉冲伏安法测试。复合材料在200~1600 nmol/L的Hg2+浓度范围内具有良好的线性关系,以及超高灵敏度(1010.82 μA·L/(nmol·cm2))和超低检出限(2.1 pmol/L)。基于界面势垒的新型传感模式消除了其它离子的干扰,在自来水、河水以及海水中的Hg2+的加标回收率为97.3%~105.0%,RSD为1.8%~5.6%。这种利用p-n结势垒的方法可推广至其它检测重金属离子的传感器的开发研究。

English


    1. [1]

      LI C P, NIU Q F, WANG J G, WEI T, Li T D, CHEN J B, QIN X Y, YANG Q X. Spectrochim. Acta, Part A, 2020, 233:118208.LI C P, NIU Q F, WANG J G, WEI T, Li T D, CHEN J B, QIN X Y, YANG Q X. Spectrochim. Acta, Part A, 2020, 233:118208.

    2. [2]

      COUNTER S A, BUCHANAN L H. Toxicol. Appl. Pharmacol., 2004, 198(2):209-230.COUNTER S A, BUCHANAN L H. Toxicol. Appl. Pharmacol., 2004, 198(2):209-230.

    3. [3]

      LI X Y, DU Z H, LIN S H, TIAN J J, TIAN H T, XU W T. Food Chem., 2020, 316:126303.LI X Y, DU Z H, LIN S H, TIAN J J, TIAN H T, XU W T. Food Chem., 2020, 316:126303.

    4. [4]

      ZHANG H, LEI Z X, FU X, DENG X C, WANG Q, GU D Y. Sens. Actuators, B, 2017, 246:896-903.ZHANG H, LEI Z X, FU X, DENG X C, WANG Q, GU D Y. Sens. Actuators, B, 2017, 246:896-903.

    5. [5]

      ZHANG M, GE L, GE S G, YAN M, YU J H, HUANG J D, LIU S. Biosens. Bioelectron., 2013, 41:544-550.ZHANG M, GE L, GE S G, YAN M, YU J H, HUANG J D, LIU S. Biosens. Bioelectron., 2013, 41:544-550.

    6. [6]

      LI Z B, MIAO X M, XING K, PENG X, ZHU A H, LING L S. Biosens. Bioelectron., 2016, 80:339-343.LI Z B, MIAO X M, XING K, PENG X, ZHU A H, LING L S. Biosens. Bioelectron., 2016, 80:339-343.

    7. [7]

      WANG N, LIN M, DAI H X, MA H Y. Biosens. Bioelectron., 2016, 79:320-326.WANG N, LIN M, DAI H X, MA H Y. Biosens. Bioelectron., 2016, 79:320-326.

    8. [8]

      ZHUANG Y P, ZHAO M G, HE Y, CHENG F, CHEN S G. J. Electroanal. Chem., 2018, 826:90-95.ZHUANG Y P, ZHAO M G, HE Y, CHENG F, CHEN S G. J. Electroanal. Chem., 2018, 826:90-95.

    9. [9]

      CHAIVO S, CHAILAPAKUL O, SIANGPROH W. Anal. Chim. Acta, 2014, 852:55-62.CHAIVO S, CHAILAPAKUL O, SIANGPROH W. Anal. Chim. Acta, 2014, 852:55-62.

    10. [10]

      CUI L, WU J, JU H X. Biosens. Bioelectron., 2015, 63:276-286.CUI L, WU J, JU H X. Biosens. Bioelectron., 2015, 63:276-286.

    11. [11]

      SYSHCHYK O, SKRYSHEVSKY V A, SOLDATKIN O O, SOLDATKIN A P.Biosens. Bioelectron., 2015, 66:89-94.SYSHCHYK O, SKRYSHEVSKY V A, SOLDATKIN O O, SOLDATKIN A P.Biosens. Bioelectron., 2015, 66:89-94.

    12. [12]

      MARTINIANO L C, ABRANTES V R, NETO S Y, MARQUES E P, FONSECA T C O, PAIM L L, SOUZA A G, STRADIOTTO N R, AUCELIO R Q, CAVALCANTE G H R, MARQUES A L B. Fuel, 2013, 103:1164-1167.MARTINIANO L C, ABRANTES V R, NETO S Y, MARQUES E P, FONSECA T C O, PAIM L L, SOUZA A G, STRADIOTTO N R, AUCELIO R Q, CAVALCANTE G H R, MARQUES A L B. Fuel, 2013, 103:1164-1167.

    13. [13]

      JIA J, DU X, ZHANG Q Q, LIU E Z, FAN J. Appl. Surf. Sci., 2019, 492:527-539.JIA J, DU X, ZHANG Q Q, LIU E Z, FAN J. Appl. Surf. Sci., 2019, 492:527-539.

    14. [14]

      JIANG Y, LIAO J F, CHEN H Y, ZHANG H H, LI J Y, WANG X D, KUANG D B. Chem, 2020, 6(3):766-780.JIANG Y, LIAO J F, CHEN H Y, ZHANG H H, LI J Y, WANG X D, KUANG D B. Chem, 2020, 6(3):766-780.

    15. [15]

      DAEMI S, GHASEMI S, ASHKARRAN A A. J. Colloid Interface Sci., 2019, 550:180-189.DAEMI S, GHASEMI S, ASHKARRAN A A. J. Colloid Interface Sci., 2019, 550:180-189.

    16. [16]

      WANG L, TAHIR M, CHEN H, SAMBUR J B. Nano Lett., 2019, 19(12):9084-9094.WANG L, TAHIR M, CHEN H, SAMBUR J B. Nano Lett., 2019, 19(12):9084-9094.

    17. [17]

      QIAO S L, ZHAO J, ZHANG B Y, LIU C H, LI Z, HU S Z, LI Q. Int. J. Hydrogen Energy, 2019, 44(60):32019-32029.QIAO S L, ZHAO J, ZHANG B Y, LIU C H, LI Z, HU S Z, LI Q. Int. J. Hydrogen Energy, 2019, 44(60):32019-32029.

    18. [18]

      SHANG J H, ZHAO M G, QU H Y, LI H, GAO R J, CHEN S G. J. Electroanal. Chem., 2019, 855:113624.SHANG J H, ZHAO M G, QU H Y, LI H, GAO R J, CHEN S G. J. Electroanal. Chem., 2019, 855:113624.

    19. [19]

      GAI P P, YU W, ZHAO H, QI R L, LI F, LIU L B, LV F T, WANG S. Angew. Chem., Int. Ed. 2020, 59:7224-7229.GAI P P, YU W, ZHAO H, QI R L, LI F, LIU L B, LV F T, WANG S. Angew. Chem., Int. Ed. 2020, 59:7224-7229.

    20. [20]

      ZHAO M G, SHANG J H, QU H Y, GAO R J, LI H, CHEN S G. Anal. Chim. Acta, 2019, 1095:93-98.ZHAO M G, SHANG J H, QU H Y, GAO R J, LI H, CHEN S G. Anal. Chim. Acta, 2019, 1095:93-98.

    21. [21]

      SINGH J, SONI R K. Appl. Surf. Sci., 2020, 521:146420.SINGH J, SONI R K. Appl. Surf. Sci., 2020, 521:146420.

    22. [22]

      KAVIYARASU K, MAGDALANE C M, ANAND K, MANIKANDAN E, MAAZA M. Spectrochim. Acta, Part A, 2015, 142:405-409.KAVIYARASU K, MAGDALANE C M, ANAND K, MANIKANDAN E, MAAZA M. Spectrochim. Acta, Part A, 2015, 142:405-409.

    23. [23]

      ANEESIYA K R, LOUIS C. J. Alloys Compd., 2020, 829:154497.ANEESIYA K R, LOUIS C. J. Alloys Compd., 2020, 829:154497.

    24. [24]

      XIA W, WANG Y, WANG Q, YAN Y Z, JIANG Y J. Appl. Surf. Sci., 2019, 506:145008.XIA W, WANG Y, WANG Q, YAN Y Z, JIANG Y J. Appl. Surf. Sci., 2019, 506:145008.

    25. [25]

      REZAEI B, BOROUJENI M K L, ENSAFI A A. Biosens. Bioelectron., 2014, 60:77-83.REZAEI B, BOROUJENI M K L, ENSAFI A A. Biosens. Bioelectron., 2014, 60:77-83.

    26. [26]

      CHANDRA V, KIM K S. Chem. Commun., 2011, 47(13):3942-3944.CHANDRA V, KIM K S. Chem. Commun., 2011, 47(13):3942-3944.

    27. [27]

      KHANNA P K, BHANOTH S, DHANWE V, KSHIRSAGAR A, MORE P. RSC Adv., 2015, 5(113):92818-92828.KHANNA P K, BHANOTH S, DHANWE V, KSHIRSAGAR A, MORE P. RSC Adv., 2015, 5(113):92818-92828.

    28. [28]

      JAFARIAN M, AFGHAHI S S S, ATASSI Y, LORIAMINI A. J. Magn. Magn. Mater., 2019, 493:165680.JAFARIAN M, AFGHAHI S S S, ATASSI Y, LORIAMINI A. J. Magn. Magn. Mater., 2019, 493:165680.

    29. [29]

      OLAD A, RASHIDZADEH A, AMINI M. Adv. Polym. Technol., 2013, 32(2):21337OLAD A, RASHIDZADEH A, AMINI M. Adv. Polym. Technol., 2013, 32(2):21337

    30. [30]

      NOEI H, QIU H S, WANG Y M, LOFFLER E, WOLL C, MUHLER M. Phys. Chem. Chem. Phys., 2008, 10(47):7092-7097.NOEI H, QIU H S, WANG Y M, LOFFLER E, WOLL C, MUHLER M. Phys. Chem. Chem. Phys., 2008, 10(47):7092-7097.

    31. [31]

      HUANG J H, YANG Z H, YANG B, WANG R J, WANG T T. J. Power Sources, 2014, 271:143-151.HUANG J H, YANG Z H, YANG B, WANG R J, WANG T T. J. Power Sources, 2014, 271:143-151.

    32. [32]

      YIN Z G, FAN W B, DING Y H, LI J X, GUAN L H, ZHENG Q D. ACS Sustainable Chem. Eng., 2015, 3(3):507-517.YIN Z G, FAN W B, DING Y H, LI J X, GUAN L H, ZHENG Q D. ACS Sustainable Chem. Eng., 2015, 3(3):507-517.

    33. [33]

      WANG W, XU L H, ZHANG R F, XU J L, XIAN F L, SU J, YANG F. Chem. Phys. Lett., 2019, 721:57-61.WANG W, XU L H, ZHANG R F, XU J L, XIAN F L, SU J, YANG F. Chem. Phys. Lett., 2019, 721:57-61.

    34. [34]

      XU L H, ZHOU Y, WU Z J, ZHENG G G, HE J J, ZHOU Y J. J. Phys. Chem. Solids, 2017, 106:29-36.XU L H, ZHOU Y, WU Z J, ZHENG G G, HE J J, ZHOU Y J. J. Phys. Chem. Solids, 2017, 106:29-36.

    35. [35]

      LI B X, WANG Y F. Superlattices Microstruct., 2010, 47(5):615-623.LI B X, WANG Y F. Superlattices Microstruct., 2010, 47(5):615-623.

    36. [36]

      CHANDRA V, KIM K S. Chem. Commun., 2011, 47(13):3942-3944.CHANDRA V, KIM K S. Chem. Commun., 2011, 47(13):3942-3944.

    37. [37]

      GONG J M, ZHOU T, SONG D D, ZHANG L Z. Sens. Actuators, B, 2010, 150(2):491-497.GONG J M, ZHOU T, SONG D D, ZHANG L Z. Sens. Actuators, B, 2010, 150(2):491-497.

    38. [38]

      ZHANG X R, LI Y, SU H R, ZHANG S S. Biosens. Bioelectron., 2010, 25(6):1338-1343.ZHANG X R, LI Y, SU H R, ZHANG S S. Biosens. Bioelectron., 2010, 25(6):1338-1343.

    39. [39]

      XIE Y L, ZHAO S Q, YE H L, YUAN J, SONG P, HU S Q. J. Electroanal. Chem., 2015, 757:235-242.XIE Y L, ZHAO S Q, YE H L, YUAN J, SONG P, HU S Q. J. Electroanal. Chem., 2015, 757:235-242.

    40. [40]

      WEN G L, ZHAO W, CHEN X, LIU J Q, WANG Y, ZHANG Y, HUANG Z J, WU Y C. Electrochim. Acta, 2018, 291:95-102.WEN G L, ZHAO W, CHEN X, LIU J Q, WANG Y, ZHANG Y, HUANG Z J, WU Y C. Electrochim. Acta, 2018, 291:95-102.

    41. [41]

      SHARMA V V, TONELLI D, GUADAGNINI L, GAZZANO M. Sens. Actuators, B, 2017, 238:9-15.SHARMA V V, TONELLI D, GUADAGNINI L, GAZZANO M. Sens. Actuators, B, 2017, 238:9-15.

    42. [42]

      ZHAO Z Q, CHEN X, YANG Q, LIU J H, HUANG X J. Chem. Commun., 2012, 48(16):2180-2182.ZHAO Z Q, CHEN X, YANG Q, LIU J H, HUANG X J. Chem. Commun., 2012, 48(16):2180-2182.

    43. [43]

      MA L F, ZHANG X Y, IKRAM M, ULLAH M, WU H Y, SHI K Y. Chem. Eng. J., 2020, 395:125216.MA L F, ZHANG X Y, IKRAM M, ULLAH M, WU H Y, SHI K Y. Chem. Eng. J., 2020, 395:125216.

    44. [44]

      LI Z B, MIAO X M, XING K, PENG X, ZHU A H, LING L S. Biosens. Bioelectron., 2016, 80:339-343.LI Z B, MIAO X M, XING K, PENG X, ZHU A H, LING L S. Biosens. Bioelectron., 2016, 80:339-343.

    45. [45]

      ZHANG L X, FENG L P, LI P, CHEN X, JIANG J T, ZHANG S, ZHANG C X, ZHANG A C, CHEN G F, WANG H. Chem. Eng. J., 2020, 395:125072.ZHANG L X, FENG L P, LI P, CHEN X, JIANG J T, ZHANG S, ZHANG C X, ZHANG A C, CHEN G F, WANG H. Chem. Eng. J., 2020, 395:125072.

    46. [46]

      GE L, HONG Q, LI H, LIU C, LI F. Adv. Funct. Mater. 2019, 29:1904000.GE L, HONG Q, LI H, LIU C, LI F. Adv. Funct. Mater. 2019, 29:1904000.

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  • 收稿日期:  2021-03-17
  • 修回日期:  2021-07-04
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