Citation: ZHONG Shi-Long, ZHANG Ling-Ling, LIU Jing, LIU Xiang-Jun, CHANG Tian-Jun, SHANGGUAN Di-Hua. Carbon Quantum Dots-based Mesoporous Nanomaterials for Detection of Copper Ion[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(1): 47-53. doi: 10.19756/j.issn.0253-3820.211101 shu

Carbon Quantum Dots-based Mesoporous Nanomaterials for Detection of Copper Ion

1.
Department of Biology, Institute of Resources and Environment, Henan Polytechnic University, Jiaozuo 454000, China;
2.
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Analytical Chemistry for Living Biosystems, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;
3.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: LIU Xiang-Jun, CHANG Tian-Jun,
Received Date: 4 February 2021
Revised Date: 15 October 2021

Fund Project: Supported by the National Natural Science Foundation of China (Nos.21877115, U1704241).

Carbon quantum dots-based mesoporous mesoporous silica nanomaterials (CD-MSN) was designed and prepared for detection and adsorption of Cu²⁺. The fluorescence of CD-MSN could be selectively quenched by Cu²⁺, therefore, a fluorescence method was established for detection of Cu²⁺. A linear response range was found in the Cu²⁺ concentration range from 1.0 to 10.0 μmol/L, with limit of detection (LOD, S/N=3) of 0.22 μmol/L. Meanwhile, the maximal adsorption capacity of CD-MSN for Cu²⁺ was determined as 5.71 mg/g by inductively coupled plasma optical emission spectrometry (ICP-OES). In addition, the CD-MSN was successfully applied to detect Cu²⁺ in real tap water samples. The results suggested that the synthesized CD-MSN had the potential in detection of Cu²⁺ in real water samples.
- Carbon quantum dots,
- Mesoporous nanomaterials,
- Fluorescence,
- Copper ion
1. [1]
2. [2]
  ARAYA M, OLIWARES M, PIZARRO F. Int. J. Environ. Health, 2007, 1(4):608-620.
3. [3]
  BARNHAM K J, MASTERS C L, BUSH A I. Nat. Rev. Drug Discovery, 2004, 3(3):205-214.
4. [4]
5. [5]
  GU W, ZHU X. Microchim. Acta, 2017, 184(11):4279-4286.
6. [6]
  DOBROWOLSKA J, DEHNHARDT M, MATUSCH A, ZORITY M, PPALOMERO-GALLAGHER N, KSCIELNAK P, ZILLES K, BECKER J S. Talanta, 2008, 74(4):717-723.
7. [7]
  GHAEDI M, AHMADI F, SHOKROLLAHI A. J. Hazard. Mater., 2007, 142(1-2):272-278.
8. [8]
  KARAYIGIT B, COLAK N, OZOGUL F, GUNDOGDU A, INCEER H, BILGICLI N, AYAZ F A. Food Biosci., 2020, 37:100676.
9. [9]
  PIZARRO J, FLORES E, JIMENEZ V, MALDONADO T, SAITA C, VEGA A, GODOY F, SEGURA R. Sens. Actuators, B, 2019, 281:115-122.
10. [10]
  QUANG D T, KIM J S. Chem. Rev., 2010, 110(10):6280-6301.
11. [11]
  LI Z, XU Y, XU H, CUI M, LIU T, REN X, SUN J, DENG D, GU Y, WANG P. Spectrochim. Acta, Part A, 2021, 244:118819.
12. [12]
  LI X, ZHOU L, WEI Y, EL-TONI A M, ZHANG F, ZHAO D. J. Am. Chem. Soc., 2014, 136(42):15086-15092.
13. [13]
  PAN L, LIU J, HE Q, SHI J. Adv. Mater., 2014, 26(39):6742-6748.
14. [14]
15. [15]
  BHATT M, BHATT S, VYAS G, RAVAL I H, HALDAR S, PAUL P. ACS Appl. Nano Mater., 2020, 3(7):7096-7104.
16. [16]
  CHANG D, LI L, SHI L, YANG Y. Analyst, 2020, 145(24):8030-8037.
17. [17]
18. [18]
  DONG W, WANG R, GONG X, LIANG W, FAN L, SONG S, DONG C. Microchim. Acta, 2020, 187(5):2443-2456.
19. [19]
  JIN M, LIU X, ZHANG X, WANG L, BING T, ZHANG N, ZHANG Y, SHANGGUAN D. ACS Appl. Mater. Interfaces, 2018, 10(30):25166-25173.
20. [20]
  GHOSH S, GHOSAL K, MOHAMMAD S A, SARKAR K. Chem. Eng. J., 2019, 373:468-484.
21. [21]
  MA X, LIN S, DANG Y, DAI Y, ZHANG X, XIA F. Anal. Bioanal. Chem., 2019, 411(25):6645-6653.
22. [22]
  LIU X, ZHANG N, BING T, SHANGGUAN D. Anal. Chem., 2014, 86(5):2289-2296.
23. [23]
24. [24]
  ZHAO L, LI H, XU Y, LIU H, ZHOU T, HUANG N, DING L. Anal. Bioanal. Chem., 2018, 410:4301-4309.
25. [25]
  ZOU C, FODA M F, TAN X, SHAO K, WU L, LU Z, BAHLOL H S, HAN H. Anal. Chem., 2016, 88(14):7395-7403.
26. [26]
  SONG J, MA Q, LIU Y, GUO Y, FENG F, SHUANG S. RSC Adv., 2019, 9(66):38568-38575.
1. [1]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
2. [2]
  Qi WANG , Ying CHENG , Yuyan WANG , Yibing XIAO , Haozhe LU , Yansong ZHANG , Shengling LI , Jiazi TANTAI , Na SUN , Lifeng DING , Jinqin GUO , Peng JIN . "Shining dot" in vinegar—Extraction of carbon quantum dots and the fluorescence properties analysis. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 87-96. doi: 10.11862/CJIC.20250127
3. [3]
  Li'na ZHONG , Jingling CHEN , Qinghua ZHAO . Synthesis of multi-responsive carbon quantum dots from green carbon sources for detection of iron ions and L-ascorbic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 709-718. doi: 10.11862/CJIC.20240280
4. [4]
  Zehui JIA , Bin WEN , Shuting ZHANG , Zhengliang ZHAO , Hongfei HAN , Chuntao WANG , Caimei FAN . Mechanism of carbon quantum dots-modified BiOCl/diatomite composites for ciprofloxacin degradation under visible light irradiation. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 317-330. doi: 10.11862/CJIC.20250199
5. [5]
  Feng Lu , Tao Wang , Qi Wang . Preparation and Characterization of Water-Soluble Silver Nanoclusters: A New Design and Teaching Practice in Materials Chemistry Experiment. University Chemistry, 2025, 40(4): 375-381. doi: 10.12461/PKU.DXHX202406005
6. [6]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
7. [7]
  Lingqi Zhang , Hairong Huang , Jialin Li , Li Ji , Yufan Pan , Meiling Ye , Cuixue Chen , Shunü Peng . 桂花碳量子点的绿色制备及科普应用方案. University Chemistry, 2025, 40(8): 298-306. doi: 10.12461/PKU.DXHX202409138
8. [8]
  Tong WANG , Qinyue ZHONG , Qiong HUANG , Weimin GUO , Xinmei LIU . Mn-doped carbon quantum dots/Fe-doped ZnO flower-like microspheres heterojunction: Construction and photocatalytic performance. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1589-1600. doi: 10.11862/CJIC.20250011
9. [9]
  Shuting Zhuang , Lida Zhao . Teaching through Research: A Comprehensive Experiment on Carbon Quantum Dots from Microplastic Waste. University Chemistry, 2025, 40(10): 217-224. doi: 10.12461/PKU.DXHX202412010
10. [10]
  Wenwei Zeng , Qingyu Sun , Mengxiang Liang , Lirong Lin , Laiying Zhang . Unveiling Anti-Counterfeiting Secrets: Excitation-Dependent Luminescence in Sb³⁺-Doped Perovskite Materials. University Chemistry, 2026, 41(2): 375-384. doi: 10.12461/PKU.DXHX202503036
11. [11]
  Yihan Xue , Xue Han , Jie Zhang , Xiaoru Wen . NCQDs修饰FeOOH基复合材料的制备及其电容脱盐性能. Acta Physico-Chimica Sinica, 2025, 41(7): 100072-0. doi: 10.1016/j.actphy.2025.100072
12. [12]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-0. doi: 10.3866/PKU.WHXB202403005
13. [13]
  Shiyi Chen , Jialong Fu , Jianping Qiu , Guoju Chang , Shiyou Hao . Waste medical mask-derived carbon quantum dots enhance the photocatalytic degradation of polyethylene terephthalate (PET) over BiOBr/g-C₃N₄ S-scheme heterojunction. Acta Physico-Chimica Sinica, 2026, 42(1): 100135-0. doi: 10.1016/j.actphy.2025.100135
14. [14]
  Kuaibing Wang , Feifei Mao , Weihua Zhang , Bo Lv . Design and Practice of a Comprehensive Teaching Experiment for Preparing Biomass Carbon Dots from Rice Husk. University Chemistry, 2025, 40(5): 342-350. doi: 10.12461/PKU.DXHX202407042
15. [15]
  Yuecheng ZHANG , Fan YANG , Shiyu ZHANG , Chengjun MA , Rui TIAN , Xuehua SUN , Haoyu LI , Lingbo SUN , Hongyan MA . B-doped carbon quantum dots with long-afterglow room-temperature phosphorescence: Applications in information encryption and humidity sensing. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1361-1370. doi: 10.11862/CJIC.20240415
16. [16]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
17. [17]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035
18. [18]
  Qin Li , Kexin Yang , Qinglin Yang , Xiangjin Zhu , Xiaole Han , Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, 2024, 39(9): 359-368. doi: 10.3866/PKU.DXHX202309059
19. [19]
  Zehua Zhang , Haitao Yu , Yanyu Qi . Design Strategy for Thermally Activated Delayed Fluorescence Materials with Multiple Resonance Effect. Acta Physico-Chimica Sinica, 2025, 41(1): 100006-0. doi: 10.3866/PKU.WHXB202309042
20. [20]
  Chengcheng Si , Linshan Chai , Huiyuan Liu , Liye Sun , Shijian Cheng , Hailing Li , Wenyun Wang , Fang Liu , Qing Feng , Min Liu . Harry Potter China Tour Themed Innovative Science Popularization Experiment: Chemistry Magic Meets the Real World at Wuhan Station. University Chemistry, 2024, 39(9): 283-287. doi: 10.12461/PKU.DXHX202401069

Get Citation

PDF

XML

Metrics

PDF Downloads(23)
Abstract views(1584)
HTML views(305)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142