表面增强红外光谱电化学揭示电极-电解质界面处的抗衡离子效应

程晓伟 李姗姗 武烈 姜秀娥

引用本文: 程晓伟, 李姗姗, 武烈, 姜秀娥. 表面增强红外光谱电化学揭示电极-电解质界面处的抗衡离子效应[J]. 分析化学, 2022, 50(3): 365-374. doi: 10.19756/j.issn.0253-3820.210873 shu
Citation:  CHENG Xiao-Wei,  LI Shan-Shan,  WU Lie,  JIANG Xiu-E. Study on Counter Ion Effect at Electrode/Electrolyte Interface by Surface-enhanced Infrared Absorption Spectroelectrochemistry[J]. Chinese Journal of Analytical Chemistry, 2022, 50(3): 365-374. doi: 10.19756/j.issn.0253-3820.210873 shu

表面增强红外光谱电化学揭示电极-电解质界面处的抗衡离子效应

    通讯作者: 武烈,E-mail:lwu@ciac.ac.cn; 姜秀娥,E-mail:jiangxiue@ciac.ac.cn
  • 基金项目:

    中国科学院青年创新促进会项目(No.2020233)、国家自然科学基金项目(Nos.22025406,22074138)和吉林省科技发展计划项目(No.20200703021ZP)资助。

摘要: 选用4种中性电化学反应体系中常用的电解质,利用表面增强红外吸收光谱电化学技术结合振动斯塔克效应对电极-电解质溶液界面处特殊的抗衡离子效应进行谱学-电化学表征。应用不同分子长度的振动斯塔克探针,揭示了阴离子作为抗衡离子,因与电极表面相互作用强度的差异而在双电层中具有不同的浓度分布,进而对界面局域电场产生不同的屏蔽效应。与电极表面存在特异性相互作用的离子可大量吸附到紧密层,使界面局域有效电场强度显著降低。此外,本研究还提出了定量分析离子与电极界面相互作用程度的方法。本研究结果对进一步理解电化学双电层的结构以及电催化反应的构效关系具有重要意义。

English


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  • 收稿日期:  2021-12-01
  • 修回日期:  2021-12-23
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