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基于晶体生长法的磁性石墨化碳黑的制备及在茶叶农药残留检测中的应用

周书威 ,  傅红 ,  薛晓康 ,  柯秋璇 ,  常巧英 ,  杨方

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引用本文: 周书威, 傅红, 薛晓康, 柯秋璇, 常巧英, 杨方. 基于晶体生长法的磁性石墨化碳黑的制备及在茶叶农药残留检测中的应用[J]. 分析化学, 2022, 50(3): 472-481. doi: 10.19756/j.issn.0253-3820.210844 shu
Citation:  ZHOU Shu-Wei,  FU Hong,  XUE Xiao-Kang,  KE Qiu-Xuan,  CHANG Qiao-Ying,  YANG Fang. Preparation of Magnetic Graphitized Carbon Black Based on Crystal Growth Method and Its Application in Detection of Pesticide Residues in Tea[J]. Chinese Journal of Analytical Chemistry, 2022, 50(3): 472-481. doi: 10.19756/j.issn.0253-3820.210844 shu

基于晶体生长法的磁性石墨化碳黑的制备及在茶叶农药残留检测中的应用

  • 1福州大学生物科学与工程学院, 福州 350108;

  • 2福州海关技术中心, 福州 350001;

  • 3中国农业大学食品科学与营养工程学院, 北京 100083

    • 通讯作者: 杨方,E-mail:964890740@qq.com
  • 基金项目:

    国家重点研发计划专项项目（No.2017YFF0211304）和福建省自然科学基金项目（No.2020J1098）资助。

摘要: 基于晶体生长法制备了一种均匀稳定的四氧化三铁负载石墨化碳黑磁性纳米材料（GCB/Fe3O4），通过扫描电镜、傅里叶变换红外光谱仪、X射线衍射仪和振动磁强计对GCB/Fe3O4的表面形貌、晶体结构、磁学性能进行了分析，并以儿茶素、姜黄素、槲皮素、叶绿素铜钠和β-胡萝卜素为对象，研究了GCB/Fe3O4对色素、多酚等干扰物质的吸附性能。结果显示，所制备的磁性纳米材料GCB/Fe3O4保留了GCB原有的吸附特性并具备磁性，对儿茶素、姜黄素、槲皮素、叶绿素铜钠和β-胡萝卜素的饱和吸附量分别为7.87、9.19、5.65、3.35和6.13 mg/g，较GCB的饱和吸附量分别提高了187.2%、28.9%、55.2%、52.3%和4.6%。以GCB/Fe3O4为磁性吸附剂，用于茶叶中405种农药残留检测的净化，相比现行的固相萃取法或QuEChERs法，操作更简便快速，净化时间至少可节约15%；茶叶中393种农药残留的回收率为60%-120%，相对标准偏差为2.6%-14.6%。实验结果表明，GCB/Fe3O4具备良好的吸附性能，且稳定性好，可用于茶叶中多种农药残留检测的样品前处理过程。

English


    1. [1]

      XU Dun-Ming, LU Sheng-Yu, CHEN Da-Jie, LAN Jin-Chang, ZHANG Zhi-Gang, YANG Fang, ZHOU Yu. Chin. J. Chromatogr., 2013, 31(3):218-222. 徐敦明, 卢声宇, 陈达捷, 蓝锦昌, 张志刚, 杨方, 周昱.色谱, 2013, 31(3):218-222.

    2. [2]

      ZHANG Xin-Zhong, LUO Feng-Jian, CHEN Zong-Mao, LIU Guang-Ming, LOU Zheng-Yun, WANG Fang,WU Lu-Chao. Chin. J. Anal. Chem., 2013, 41(2):215-222. 张新忠, 罗逢健, 陈宗懋, 刘光明, 楼正云, 王方, 吴鲁超. 分析化学, 2013, 41(2):215-222.

    3. [3]

      JIA Wei, HUANG Jun-Rong, LING Yun, FENG Feng, ZHENG Yue-Ming, CHU Xiao-Gang. J. Instrum. Anal., 2013, 32(1):9-22. 贾玮, 黄峻榕, 凌云, 冯峰, 郑月明, 储晓刚. 分析测试学报, 2013, 32(1):9-22.

    4. [4]

      SHIRAI N. J. Oleo Sci., 2019, 68(12):1271-1277.SHIRAI N. J. Oleo Sci., 2019, 68(12):1271-1277.

    5. [5]

      YUAN Xin-Ya, YAO Jing, CHEN Yan-Feng, ZHAO Lan. Chin. J. Health Lab. Technol., 2019, 29(20):2555-2558. 苑欣娅, 姚晶, 陈彦凤, 赵岚. 中国卫生检验杂志, 2019, 29(20):2555-2558.

    6. [6]

      YANG Song, LIU Shang-Ke, ZHANG Jun-Jie, HU Pei-Jie, CAO Chang-Peng, ZOU Nan. Chin. J. Anal. Chem., 2021, 49(5):830-838. 杨松, 刘尚可, 张俊杰, 胡佩杰, 曹常鹏, 邹楠. 分析化学, 2021, 49(5):830-838.

    7. [7]

      LIU Z Z, QI P P, WAGN X Y, WANG Z W, XU X H, CHEN W X, WU L Y, ZHANG H, WANG Q, WANG X Q. Food Chem., 2017, 230:423-431.LIU Z Z, QI P P, WAGN X Y, WANG Z W, XU X H, CHEN W X, WU L Y, ZHANG H, WANG Q, WANG X Q. Food Chem., 2017, 230:423-431.

    8. [8]

      ZHANG M, CHEN H, ZHU L, WANG C, MA G, LIU X. J. Sep. Sci., 2016, 39(5):910-917.ZHANG M, CHEN H, ZHU L, WANG C, MA G, LIU X. J. Sep. Sci., 2016, 39(5):910-917.

    9. [9]

      WU C C. Food Chem., 2017, 229:580-587.WU C C. Food Chem., 2017, 229:580-587.

    10. [10]

      LIAO Ying-Min, HUANG Xiao-Jia, WANG Zhuo-Zhuo, GAN Rui. Chin. J. Chromatogr., 2021, 39(4):368-375. 廖颖敏, 黄晓佳, 王卓卓, 甘蕊. 色谱, 2021, 39(4):368-375.

    11. [11]

      ZHAO Q, LI G L, NING Y F, ZHOU T, MEI Y, GUO Z Z, FENG Y Q. Microchem. J., 2019, 147:67-74.ZHAO Q, LI G L, NING Y F, ZHOU T, MEI Y, GUO Z Z, FENG Y Q. Microchem. J., 2019, 147:67-74.

    12. [12]

      ZHOU D B, XIAO Y B, HAN F, LV Y N, DING L, SONG W, LIU Y X, ZHENG P, CHEN D. J. Chromatogr. A, 2021, 1654:462465.ZHOU D B, XIAO Y B, HAN F, LV Y N, DING L, SONG W, LIU Y X, ZHENG P, CHEN D. J. Chromatogr. A, 2021, 1654:462465.

    13. [13]

      WANG X, ZHU Y Y, ZHOU L, ZHAO P F, XIONG Z L, JIA Y. Food Chem., 2022, 370:131056.WANG X, ZHU Y Y, ZHOU L, ZHAO P F, XIONG Z L, JIA Y. Food Chem., 2022, 370:131056.

    14. [14]

      ZHANG Wen-Min, FENG Zun-Mei, HUANG Chuan-Hui, GAO Jia, ZHANG Lan. Chin. J. Chromatogr., 2020, 38(3):332-340. 张文敏, 冯遵梅, 黄川辉, 高佳, 张兰. 色谱, 2020, 38(3):332-340.

    15. [15]

      WANG H, ZHAO X, XU J W, SHANG Y Z, WANG H, WANG P, HE X T, TAN J. J. Chromatogr. A, 2021, 1651:462286.WANG H, ZHAO X, XU J W, SHANG Y Z, WANG H, WANG P, HE X T, TAN J. J. Chromatogr. A, 2021, 1651:462286.

    16. [16]

      MANOUSI N, DELIYANNI E A, ROSENBERG E, ZACHARIADIS G A. J. Chromatogr. A, 2021, 1645:462104.MANOUSI N, DELIYANNI E A, ROSENBERG E, ZACHARIADIS G A. J. Chromatogr. A, 2021, 1645:462104.

    17. [17]

      DUO H X, WANG S, LU X F, WANG L C, LIANG X J, GUO Y. J. Chromatogr. A, 2021, 1645:462074.DUO H X, WANG S, LU X F, WANG L C, LIANG X J, GUO Y. J. Chromatogr. A, 2021, 1645:462074.

    18. [18]

      LIU S X, YU B, WANG S, SHEN Y, CONG Y. Adv. Colloid Interface Sci., 2020, 281(5):102165.LIU S X, YU B, WANG S, SHEN Y, CONG Y. Adv. Colloid Interface Sci., 2020, 281(5):102165.

    19. [19]

      AMSTAD E, GILLICH T, BILECKA I, TEXTOR M, REIMHULT E. Nano Lett., 2009, 9(12):4042-4048.AMSTAD E, GILLICH T, BILECKA I, TEXTOR M, REIMHULT E. Nano Lett., 2009, 9(12):4042-4048.

    20. [20]

      ZHANG W L, ZHANG L Y, ZHAO X J, ZHOU Z Q. J. Mol. Liq., 2016, 222:995-1002.ZHANG W L, ZHANG L Y, ZHAO X J, ZHOU Z Q. J. Mol. Liq., 2016, 222:995-1002.

    21. [21]

      PIOVESANA S, CAPRIOTTI A L, CAVALIERE C, FERRARIS F, IGLESIAS D, MARCHESAN S, LAGANÀ A. Anal. Chem., 2016, 88(24):12043-12050.PIOVESANA S, CAPRIOTTI A L, CAVALIERE C, FERRARIS F, IGLESIAS D, MARCHESAN S, LAGANÀ A. Anal. Chem., 2016, 88(24):12043-12050.

    22. [22]

      AHMAD Y, DISA E, GUÉRIN K, DUBOIS M, PETIT E, HAMWI A, THOMAS P, MANSOT J L. J. Fluorine Chem., 2014, 168:163-172.AHMAD Y, DISA E, GUÉRIN K, DUBOIS M, PETIT E, HAMWI A, THOMAS P, MANSOT J L. J. Fluorine Chem., 2014, 168:163-172.

    23. [23]

      PIOVESANA S, CAPRIOTTI A L, CAVALIERE C, BARBERA G L, SAMPERI R, CHIOZZIR Z, LAGANÀ A. Anal. Bioanal. Chem., 2017, 409(17):4181-4194.PIOVESANA S, CAPRIOTTI A L, CAVALIERE C, BARBERA G L, SAMPERI R, CHIOZZIR Z, LAGANÀ A. Anal. Bioanal. Chem., 2017, 409(17):4181-4194.

    24. [24]

      NODEH H R, SERESHTI H, AFSHARIAN E Z, NOURI N. J. Environ. Manage., 2017, 197:265-274.NODEH H R, SERESHTI H, AFSHARIAN E Z, NOURI N. J. Environ. Manage., 2017, 197:265-274.

    25. [25]

      KNOX J H, KAUR B, MILLWARD G R. J. Chromatogr. A, 1986, 352(1):3-25.KNOX J H, KAUR B, MILLWARD G R. J. Chromatogr. A, 1986, 352(1):3-25.

    26. [26]

      GB/T 23204-2008. Determination of Residues of 519 Pesticides and Related Chemicals in Tea. GC-MS Method National Standards of the People's Republic of China. 茶叶中519种农药及相关化学品残留量的测定. 气相色谱-质谱法. 中华人民共和国国家标准. GB/T 23204-2008.

    27. [27]

      HAN Q, WANG Z H, XIA J F, CHEN S, ZHANG X Q, DING M Y. Talanta, 2012, 101:388-395.HAN Q, WANG Z H, XIA J F, CHEN S, ZHANG X Q, DING M Y. Talanta, 2012, 101:388-395.

    28. [28]

      HOU Yuan, WU Yi-Wen, WU Xiao-Liang, ZHU Wen-Guang, ZHANG Bang-Wen. Phys. Test. Chem. Anal., Part A, 2021, 57(7):1-5. 侯渊, 吴益文, 武晓亮, 朱文广, 张邦文. 理化检验-物理分册, 2021, 57(7):1-5.

    29. [29]

      GE Yao, CHEN Wen-Wei, JIA Zhen-Bao, JIANG Jia-Xin. China Food Addit., 2008, (1):51-53. 葛尧, 陈文伟, 贾振宝, 蒋家新. 中国食品添加剂, 2008, (1):51-53.

    30. [30]

      GB 2763-2021. National Food Safety Standard-Maximum Residue Limits of Pesticides in Food. National Standards of the People's Republic of China. 食品安全国家标准-食品中农药最大残留限量. 中华人民共和国国家标准. GB 2763-2021.

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  • 收稿日期:  2021-11-18
  • 修回日期:  2021-12-30
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