用于铜离子和草甘膦检测的萘酰亚胺类席夫碱荧光探针的合成及应用

刘洋 吴绵园 由君 武文菊 喻艳超

引用本文: 刘洋, 吴绵园, 由君, 武文菊, 喻艳超. 用于铜离子和草甘膦检测的萘酰亚胺类席夫碱荧光探针的合成及应用[J]. 分析化学, 2022, 50(5): 772-780. doi: 10.19756/j.issn.0253-3820.210829 shu
Citation:  LIU Yang,  WU Mian-Yuan,  YOU Jun,  WU Wen-Ju,  YU Yan-Chao. Synthesis and Application of Naphthalimide Schiff Base Fluorescent Probe for Detection of Copper Ion and Glyphosate[J]. Chinese Journal of Analytical Chemistry, 2022, 50(5): 772-780. doi: 10.19756/j.issn.0253-3820.210829 shu

用于铜离子和草甘膦检测的萘酰亚胺类席夫碱荧光探针的合成及应用

    通讯作者: 喻艳超,E-mail:yychao136@163.com
  • 基金项目:

    国家自然科学基金项目(No.21908034)和黑龙江省自然科学基金项目(No.LH2021H001)资助。

摘要: 以4-溴-1,8-萘二甲酸酐为原料,合成了一种萘酰亚胺类席夫碱荧光探针L,采用核磁共振(1H NMR,13C NMR)、红外光谱(IR)和高分辨质谱(HRMS)进行了结构表征。探针L在CH3CN-H2O (75∶25,V/V,20 mmol/L HEPES,pH=7.4)溶液中,可实现对Cu2+的专一性识别,检出限低至0.37 μmol/L。探针L与Cu2+形成1∶1配合物L-Cu2+,此配合物通过配体置换作用可实现对草甘膦的特异性检测,方法具有选择性好、抗干扰能力强、检出限低(0.56 μmol/L,0.09 μg/mL)、可实现可视化检测等优点。配合物L-Cu2+体系被成功应用于实际水样中草甘膦的检测,为环境样品中草甘膦的检测提供了新方法。

English


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  • 收稿日期:  2021-11-06
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