用于铜离子和草甘膦检测的萘酰亚胺类席夫碱荧光探针的合成及应用

引用本文: 刘洋, 吴绵园, 由君, 武文菊, 喻艳超. 用于铜离子和草甘膦检测的萘酰亚胺类席夫碱荧光探针的合成及应用[J]. 分析化学, 2022, 50(5): 772-780. doi: 10.19756/j.issn.0253-3820.210829 shu

Citation: LIU Yang, WU Mian-Yuan, YOU Jun, WU Wen-Ju, YU Yan-Chao. Synthesis and Application of Naphthalimide Schiff Base Fluorescent Probe for Detection of Copper Ion and Glyphosate[J]. Chinese Journal of Analytical Chemistry, 2022, 50(5): 772-780. doi: 10.19756/j.issn.0253-3820.210829 shu

用于铜离子和草甘膦检测的萘酰亚胺类席夫碱荧光探针的合成及应用

哈尔滨理工大学材料科学与化学工程学院, 绿色化工技术黑龙江省高校重点实验室, 哈尔滨 150080

通讯作者: 喻艳超,E-mail:yychao136@163.com

基金项目:
国家自然科学基金项目（No.21908034）和黑龙江省自然科学基金项目（No.LH2021H001）资助。

摘要: 以4-溴-1，8-萘二甲酸酐为原料，合成了一种萘酰亚胺类席夫碱荧光探针L，采用核磁共振（¹H NMR，¹³C NMR）、红外光谱（IR）和高分辨质谱（HRMS）进行了结构表征。探针L在CH₃CN-H₂O （75∶25，V/V，20 mmol/L HEPES，pH=7.4）溶液中，可实现对Cu²⁺的专一性识别，检出限低至0.37 μmol/L。探针L与Cu²⁺形成1∶1配合物L-Cu²⁺，此配合物通过配体置换作用可实现对草甘膦的特异性检测，方法具有选择性好、抗干扰能力强、检出限低（0.56 μmol/L，0.09 μg/mL）、可实现可视化检测等优点。配合物L-Cu²⁺体系被成功应用于实际水样中草甘膦的检测，为环境样品中草甘膦的检测提供了新方法。

关键词:

English

Synthesis and Application of Naphthalimide Schiff Base Fluorescent Probe for Detection of Copper Ion and Glyphosate

Key Laboratory of Green Chemical Engineering and Technology of College of Heilongjiang Province, College of Materials Science and Chemical Engineering, Harbin University of Science and Technology, Harbin 150080, China

Corresponding author: YU Yan-Chao, yychao136@163.com

Received Date: 06 November 2021
Revised Date: 07 February 2022
Fund Project:
Supported by the the National Natural Science Foundation of China (No.21908034) and the Natural Science Foundation of Heilongjiang Province, China (No.LH2021H001).

Abstract: A naphthalimide Schiff base fluorescent probe L was designed and synthesized with 4-bromo-1,8-naphthalene dicarboxylic anhydride as raw material. Its structure was characterized by ¹H nuclear magnetic resonance (NMR),¹³C NMR, infrared (IR) spectroscopy and high resolution mass spectrometry (HRMS). In the CH₃CN-H₂O (75:25, V/V, 20 mmol/L HEPES, pH=7.4) solution, the probe possessed good selectivity and sensitivity to Cu²⁺ and with a detection limit as low as 0.37 μmol/L. The stoichiometric ratio of L to Cu²⁺ was 1:1, and the complex L-Cu²⁺ had high selectivity, good sensitivity, low detection limit of 0.56 μmol/L (0.09 μg/mL) and naked eye recognition for detection of glyphosate by ligand replacement menthod. In addition, the L-Cu²⁺ was succesfully used in detection of glyphosate in actual water samples, which indicated that the proposed probe had potential application in the field of environmental detection.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

用于铜离子和草甘膦检测的萘酰亚胺类席夫碱荧光探针的合成及应用

通讯作者: 喻艳超,E-mail:yychao136@163.com

English

Synthesis and Application of Naphthalimide Schiff Base Fluorescent Probe for Detection of Copper Ion and Glyphosate

Corresponding author: YU Yan-Chao, yychao136@163.com

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

用于铜离子和草甘膦检测的萘酰亚胺类席夫碱荧光探针的合成及应用

通讯作者: 喻艳超,E-mail:yychao136@163.com

English

Synthesis and Application of Naphthalimide Schiff Base Fluorescent Probe for Detection of Copper Ion and Glyphosate

Corresponding author: YU Yan-Chao, yychao136@163.com

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

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