注册 English

微波辅助GO/Fe3O4/ZIF-8磁固相萃取-气相色谱-质谱联用分析薰衣草中的挥发性成分

陈萍 ,  李丹丹 ,  符继红 ,  蒋欣幸

downloadPDF
引用本文: 陈萍, 李丹丹, 符继红, 蒋欣幸. 微波辅助GO/Fe3O4/ZIF-8磁固相萃取-气相色谱-质谱联用分析薰衣草中的挥发性成分[J]. 分析化学, 2022, 50(5): 747-756. doi: 10.19756/j.issn.0253-3820.210764 shu
Citation:  CHEN Ping,  LI Dan-Dan,  FU Ji-Hong,  JIANG Xin-Xing. Microwave-assisted GO/Fe3O4/ZIF-8 Magnetic Solid Phase Extraction Combined with Gas Chromatography-Mass Spectrometry for Determination of Volatile Components in Lavender[J]. Chinese Journal of Analytical Chemistry, 2022, 50(5): 747-756. doi: 10.19756/j.issn.0253-3820.210764 shu

微波辅助GO/Fe3O4/ZIF-8磁固相萃取-气相色谱-质谱联用分析薰衣草中的挥发性成分

  • 新疆大学化工学院, 乌鲁木齐 830046

    • 通讯作者: 符继红,E-mail:fjh.518@163.com
  • 基金项目:

    新疆维吾尔自治区自然科学基金项目（No.2020D01C032）和国家自然科学基金项目（No.21565024）资助。

摘要: 建立了一种微波辅助氧化石墨烯/四氧化三铁/2-甲基咪唑锌盐（GO/Fe3O4/ZIF-8）磁固相萃取（MSPE）的新型样品前处理技术（GO/Fe3O4/ZIF-8-MSPE），结合气相色谱-质谱联用（GC-MS）实现了对薰衣草中挥发性成分的快速分析。合成的磁性材料GO/Fe3O4/ZIF-8中，Fe3O4纳米粒子具有磁性分离和微波吸收的双重作用，极大地提高了GO/Fe3O4/ZIF-8的萃取效率。优化了GO/Fe3O4/ZIF-8-MSPE的萃取参数，获得的最佳萃取条件为：5 mg GO/Fe3O4/ZIF-8为吸附材料、乙酸乙酯为解吸附溶剂、微波功率600 W和微波提取时间10 min。对GO/Fe3O4/ZIF-8-MSPE结合GC-MS的方法进行方法学考察，检测薰衣草挥发性成分的线性范围为0.01~1.20 mg/mL，相关系数（R2）大于0.9988，检出限（LOD）为0.15~0.56 ng，定量限（LOQ）为4.00~4.29 ng。在最佳萃取条件下，对2012年和2017年两个不同采摘批次的21个薰衣草的挥发性成分进行分析，共鉴定出49种化合物。采用主成分分析（PCA）进行了分析，结果表明，GO/Fe3O4/ZIF-8-MSPE提取、GC-MS检测结合PCA可快速有效地鉴别不同采摘年份的薰衣草样品。实验结果表明，GO/Fe3O4/ZIF-8-MSPE萃取方法是一种快速、灵敏、简单的样品前处理技术，适合于分析天然产物中的挥发性成分。

English


    1. [1]

      YOLANDE D, SANDRINE M, CATHERINE S, FREDERIC J, BERNARD P, JEANMARIE B, CAMILLE N, SYLVIE B, FLORENCE N. Plants, 2020, 9(12):1640.YOLANDE D, SANDRINE M, CATHERINE S, FREDERIC J, BERNARD P, JEANMARIE B, CAMILLE N, SYLVIE B, FLORENCE N. Plants, 2020, 9(12):1640.

    2. [2]

      PORTO C D, DECORTI D, KIKIC I. Food Chem., 2008, 112(4):1072-1078.PORTO C D, DECORTI D, KIKIC I. Food Chem., 2008, 112(4):1072-1078.

    3. [3]

      XIAO Z B, LI Q, NIU Y W, ZHOU X, LIU J H, XU Y B, XU Z Q. Ind. Crops Prod., 2017, 108:748-755.XIAO Z B, LI Q, NIU Y W, ZHOU X, LIU J H, XU Y B, XU Z Q. Ind. Crops Prod., 2017, 108:748-755.

    4. [4]

      PENG Y Y, BISHOP K S, QUEK S Y. Molecules, 2019, 24(11):2053.PENG Y Y, BISHOP K S, QUEK S Y. Molecules, 2019, 24(11):2053.

    5. [5]

      JING C L, HUANG R H, SU Y, LI Y Q, ZHANG C S. Biomolecules, 2019, 9(10):518.JING C L, HUANG R H, SU Y, LI Y Q, ZHANG C S. Biomolecules, 2019, 9(10):518.

    6. [6]

      WANG Z, WANG L, LI T, ZHOU X, DING L, YU Y, YU A, ZHANG H. Anal. Bioanal. Chem., 2006, 386(6):1863-1868.WANG Z, WANG L, LI T, ZHOU X, DING L, YU Y, YU A, ZHANG H. Anal. Bioanal. Chem., 2006, 386(6):1863-1868.

    7. [7]

      XU M, LIU M, SUN M, CHEN K, CAO X, HU Y. Talanta, 2016, 150:125-134.XU M, LIU M, SUN M, CHEN K, CAO X, HU Y. Talanta, 2016, 150:125-134.

    8. [8]

      SONG Wei, ZHOU Dian-Bing, GUO Chun-Li, HAN Fang, DING Lei, LYU Ya-Ning, JIA Xue-Ying, ZHENG Ping, DENG Xiao-Jun. Chin. J. Anal. Chem., 2021, 49(9):1587-1596. 宋伟, 周典兵, 郭春丽, 韩芳, 丁磊, 吕亚宁, 贾学颖, 郑平, 邓晓军. 分析化学, 2021, 49(9):1587-1596.

    9. [9]

      WU J R, ZHAO H Y, XIAO D L, CHUONG P H, HE J, HE H. J.Chromatogr. A, 2016, 1454:1-8.WU J R, ZHAO H Y, XIAO D L, CHUONG P H, HE J, HE H. J.Chromatogr. A, 2016, 1454:1-8.

    10. [10]

      GUO C, XIA F, WANG Z, ZHANG L, XI L, ZUO Y. J. Alloy Compd., 2015, 631:183-191.GUO C, XIA F, WANG Z, ZHANG L, XI L, ZUO Y. J. Alloy Compd., 2015, 631:183-191.

    11. [11]

      KAUSHIK A, SOLANKI P R, ANSARI A A, AHMAD S, MALHOTRA B D. Electrochem. Commun., 2008, 10:1364-1368.KAUSHIK A, SOLANKI P R, ANSARI A A, AHMAD S, MALHOTRA B D. Electrochem. Commun., 2008, 10:1364-1368.

    12. [12]

      SONG S, RAO R, YANG H, LIU H, ZHANG A. Nanotechnology, 2010, 21:185602.SONG S, RAO R, YANG H, LIU H, ZHANG A. Nanotechnology, 2010, 21:185602.

    13. [13]

      HUANG D N, WANG X Y, DENG C H, SONG G X, CHENG H F, ZHANG X M. J. Chromatogr. A, 2014, 1325:65-71.HUANG D N, WANG X Y, DENG C H, SONG G X, CHENG H F, ZHANG X M. J. Chromatogr. A, 2014, 1325:65-71.

    14. [14]

      LI Z B, HUANG D N, FU C F, WEI B W, YU W J, DENG C H, ZHANG X M. J. Chromatogr. A, 2011, 1218:6232-6239.LI Z B, HUANG D N, FU C F, WEI B W, YU W J, DENG C H, ZHANG X M. J. Chromatogr. A, 2011, 1218:6232-6239.

    15. [15]

      ZHAO J, CHEN H, YE H, ZHANG B, XU L. Soft Matter, 2019, 15(45):9224-9232.ZHAO J, CHEN H, YE H, ZHANG B, XU L. Soft Matter, 2019, 15(45):9224-9232.

    16. [16]

      ZHANG Wen-Min, LI Qing-Qing, FANG Min, GAO Jia, CHEN Zong-Bao, ZHANG Lan. Chin. J. Chromatogr., 2021, 39(9):941-949. 张文敏, 李青青, 方敏, 高佳, 陈宗保, 张兰. 色谱, 2021, 39(9):941-949.

    17. [17]

      QIAN Hai-Long, YAN Xiu-Ping. Chin. J. Chromatogr., 2020, 38(1):22-27. 钱海龙, 严秀平. 色谱, 2020, 38(1):22-27.

    18. [18]

      CHEN G, WANG Z G, DENAGAMAGE S, ZHENG S Y. ACS Appl. Mater. Interfaces, 2016, 8(16):10234-10242.CHEN G, WANG Z G, DENAGAMAGE S, ZHENG S Y. ACS Appl. Mater. Interfaces, 2016, 8(16):10234-10242.

    19. [19]

      MACIEL E V S, TOFFOLI A L D, NETO E S, NAZARIO C E D, LANCAS F M. TrAC-Trends Anal. Chem., 2019, 119:115633.MACIEL E V S, TOFFOLI A L D, NETO E S, NAZARIO C E D, LANCAS F M. TrAC-Trends Anal. Chem., 2019, 119:115633.

    20. [20]

      LI Y J, MA C C, NIAN P, LIU H O, ZHANG X F. J. Membr. Sci., 2019, 581:344-354.LI Y J, MA C C, NIAN P, LIU H O, ZHANG X F. J. Membr. Sci., 2019, 581:344-354.

    21. [21]

      JAZIREHPOUR M, SEYYED E S A. J. Alloy Compd., 2015, 638:188-196.JAZIREHPOUR M, SEYYED E S A. J. Alloy Compd., 2015, 638:188-196.

    22. [22]

      YAN S, QI T T, CHEN D W, LI Z, LI X J, PAN S Y. J. Chromatog. A, 2014, 1347:30-38.YAN S, QI T T, CHEN D W, LI Z, LI X J, PAN S Y. J. Chromatog. A, 2014, 1347:30-38.

    23. [23]

      ABDI J, VOSSOUGHI M, MAHMOODI N M, ALEMZADEH I. Ultrason. Sonochem., 2017, 39:550-564.ABDI J, VOSSOUGHI M, MAHMOODI N M, ALEMZADEH I. Ultrason. Sonochem., 2017, 39:550-564.

    24. [24]

      GUO Yu-Tong, LI Xin-Yue, GAO Shi-Qian, GU Hai-Dong, ZHANG Zhan-En. J. Instrum. Anal., 2016, 35(11):1384-1389. 郭宇彤, 李欣悦, 高仕谦, 顾海东, 张占恩. 分析测试学报, 2016, 35(11):1384-1389.

    25. [25]

      YAN S, QI T T, CHEN D W, LI Z, LI X J, PAN S Y. J. Chromatogr. A, 2014, 1347:30-38.YAN S, QI T T, CHEN D W, LI Z, LI X J, PAN S Y. J. Chromatogr. A, 2014, 1347:30-38.

    26. [26]

      SOYSAL F, ÇIPLAK Z, GETIREN B, GOKALP C, YILDIZ N. Colloids Surf. A, 2019, 578:123623.SOYSAL F, ÇIPLAK Z, GETIREN B, GOKALP C, YILDIZ N. Colloids Surf. A, 2019, 578:123623.

    27. [27]

      JIANG Shao-Jie, WANG Hong-Wu. Chin. J. Environ. Eng., 2019, 13(10):2347-2356. 蒋绍阶, 王洪武. 环境工程学报, 2019, 13(10):2347-2356.

    28. [28]

      LI N, ZHOU L, JIN X Y, OWENS G, CHEN Z L. J. Hazard. Mater., 2019, 366:563-572.LI N, ZHOU L, JIN X Y, OWENS G, CHEN Z L. J. Hazard. Mater., 2019, 366:563-572.

    29. [29]

      TIAN N, WU J F, WANG J Q, DAI W. J. Chem. Eng. Data, 2019, 64(12):5716-5724.TIAN N, WU J F, WANG J Q, DAI W. J. Chem. Eng. Data, 2019, 64(12):5716-5724.

    30. [30]

      QI Y, CAO X L, ElATY A, CONG M, LI H, JIANG Z J, SHE Y X, WANG S S, WANG J, YANG S X. J. Nanosci. Nanotechnol., 2019, 19(6):3310-3318.QI Y, CAO X L, ElATY A, CONG M, LI H, JIANG Z J, SHE Y X, WANG S S, WANG J, YANG S X. J. Nanosci. Nanotechnol., 2019, 19(6):3310-3318.

    31. [31]

      KATARZYNA T, MARCIN K, EDWARD R, ROBERT S, FRANCESCO C. Molecules, 2019, 24(18):3354-3369.KATARZYNA T, MARCIN K, EDWARD R, ROBERT S, FRANCESCO C. Molecules, 2019, 24(18):3354-3369.

    32. [32]

      SKOLD M, KARLBERG A T, MATURA M, BORJE A. Food Chem. Toxicol., 2005, 44(4):538-545.SKOLD M, KARLBERG A T, MATURA M, BORJE A. Food Chem. Toxicol., 2005, 44(4):538-545.

    33. [33]

      SKOLD M, HARAMBASIC E, KARLBERG A T. Chem. Res. Toxicol., 2004, 17(12):1697-1705.SKOLD M, HARAMBASIC E, KARLBERG A T. Chem. Res. Toxicol., 2004, 17(12):1697-1705.

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  6
  • 文章访问数:  474
  • HTML全文浏览量:  17
文章相关
  • 收稿日期:  2021-09-22
  • 修回日期:  2021-12-20
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net