钴-钴普鲁士蓝类似物衍生的SnCoO<sub>x</sub>中空纳米立方体的制备及电化学检测氯氮平的性能研究

引用本文: 王强明, 蒋成, 赵继华, 方建. 钴-钴普鲁士蓝类似物衍生的SnCoO_x中空纳米立方体的制备及电化学检测氯氮平的性能研究[J]. 分析化学, 2022, 50(3): 392-404. doi: 10.19756/j.issn.0253-3820.210608 shu

Citation: WANG Qiang-Ming, JIANG Cheng, ZHAO Ji-Hua, FANG Jian. Preparation of Prussian Blue Analogues-derived SnCoO_x Hollow Nanocubes and Study on Performance of Electrochemical Detection of Clozapin[J]. Chinese Journal of Analytical Chemistry, 2022, 50(3): 392-404. doi: 10.19756/j.issn.0253-3820.210608 shu

钴-钴普鲁士蓝类似物衍生的SnCoO_x中空纳米立方体的制备及电化学检测氯氮平的性能研究

兰州大学化学化工学院, 兰州 730000

通讯作者: 赵继华,E-mail:zhaojihua@lzu.edu.cn; 方建,E-mail:fangj@lzu.edu.cn

基金项目:
国家自然科学基金项目（Nos.21773097，21403098）资助。

摘要: 通过化学沉淀法合成了钴-钴普鲁士蓝类似物（CoCo-PBA）纳米立方前驱体，掺杂Sn⁴⁺后，将其在空气中高温热解，制备中空多孔SnCoO_x，然后通过超声将SnCoO_x固定在石墨毡（GF）上，制成复合电极（SnCoO_x/GF）。利用X-射线衍射（XRD）、傅里叶变换红外光谱（FT-IR）、X-射线光电子能谱（XPS）、扫描电子显微镜（SEM）和透射电子显微镜（TEM）以及电化学工作站对电极材料的结构和形貌进行了表征，并测试了其电化学性能。将SnCoO_x/GF复合电极用于检测药物分子氯氮平（CLZ），结果表明，复合电极对CLZ氧化表现出良好的电催化活性（催化速率常数k_cat=1.04×10⁵ L/（mol·s）），线性检测范围为0.01~100 μmol/L，灵敏度为6.02（A·L）/mol，检出限（LOD，S/N=3）为0.7 nmol/L。SnCoO_x/GF复合电极具有良好的稳定性、较强的抗干扰性及实用性，为电化学检测CLZ提供了一种新方法。

关键词:

English

Preparation of Prussian Blue Analogues-derived SnCoO_x Hollow Nanocubes and Study on Performance of Electrochemical Detection of Clozapin

College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: ZHAO Ji-Hua, ; FANG Jian,

Received Date: 05 July 2021
Revised Date: 29 December 2021
Fund Project:
Supported by the National Natural Science Foundation of China (Nos.21773097, 21403098).

Abstract: Cobalt oxide, as a transition metal oxide, is widely used in the field of electrochemical sensors and electrocatalysis due to its unique properties. Moreover, metal doping is the main methods to improve the electrochemical performance of electrochemical sensors. In this work, hollow porous SnCoO_x nanocubes were prepared by pyrolysis of Sn-doped CoCo-Prussian blue analogues (PBA), and then SnCoO_x/graphite felt (GF) composite electrode was prepared by fixing SnCoO_x on GF ultrasonically. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), transmission electron microscope (TEM) and electrochemical method were applied to characterize the structure, morphology and electrochemical performance of electrode materials. The composite electrode exhibited excellent electrocatalytic activity for detection of clozapine (CLZ). The electrocatalytic rate constant was k_cat=1.04×10⁵L/(mol·s), the linear detection range was 0.01-100 μmol/L, the sensitivity was 6.02 (A·L)/mol, and the limit of detection (LOD, S/N=3) was 0.7 nmol/L. The SnCoO_x/GF electrode as an electrochemical sensor for detecting CLZ had perfect anti-interference property, strong stability and practicality, which provided a feasible method for electrochemical detection of CLZ.

Key words:

1. [1]
  CARTER C J. Schizophr. Res., 2006, 86(1-13):1-14.CARTER C J. Schizophr. Res., 2006, 86(1-13):1-14.
2. [2]
  MASHHADIZADEH M H, AFSHAR E. Electrochim. Acta, 2013, 87(9):816-823.MASHHADIZADEH M H, AFSHAR E. Electrochim. Acta, 2013, 87(9):816-823.
3. [3]
  STARK A, SCOTT J. Aust. NZ. J. Psychiat., 2012, 46(9):816-825.STARK A, SCOTT J. Aust. NZ. J. Psychiat., 2012, 46(9):816-825.
4. [4]
  KANE J, HONIGFELD G, SINGER J, MELTZER H. Arch. Gen. Psychiatry, 1988, 45(9):789-796.KANE J, HONIGFELD G, SINGER J, MELTZER H. Arch. Gen. Psychiatry, 1988, 45(9):789-796.
5. [5]
  VARDAKOU I, DONA A, PISTOS C, ALEVISOPOULOS G, ATHANASELIS S, MARAVELIAS C, SPILIOPOULOU C. J. Chromatogr. B:Anal. Technol. Biomed. Life Sci., 2010, 878(25):2327-2332.VARDAKOU I, DONA A, PISTOS C, ALEVISOPOULOS G, ATHANASELIS S, MARAVELIAS C, SPILIOPOULOU C. J. Chromatogr. B:Anal. Technol. Biomed. Life Sci., 2010, 878(25):2327-2332.
6. [6]
  CHOONG E, RUDAZ S, KOTTELAT A, GUILLARME D, VEUTHEY J L, EAP C B. J. Pharm. Biomed. Anal., 2009, 50(5):1000-1008.CHOONG E, RUDAZ S, KOTTELAT A, GUILLARME D, VEUTHEY J L, EAP C B. J. Pharm. Biomed. Anal., 2009, 50(5):1000-1008.
7. [7]
  WASCHGLER R, HUBMANN M, CONCA U P, MOLL W, KÖNIG P. Int. J. Clin. Pharmacol. Ther., 2002, 40(12):554-559.WASCHGLER R, HUBMANN M, CONCA U P, MOLL W, KÖNIG P. Int. J. Clin. Pharmacol. Ther., 2002, 40(12):554-559.
8. [8]
  MERCOLINI L, BUGAMELLI F, KENNDLER E, BONCOMPAGNI G, FRANCHINI L, RAGGI M A. J. Chromatogr. B:Anal. Technol. Biomed. Life Sci., 2007, 846(1):273-280.MERCOLINI L, BUGAMELLI F, KENNDLER E, BONCOMPAGNI G, FRANCHINI L, RAGGI M A. J. Chromatogr. B:Anal. Technol. Biomed. Life Sci., 2007, 846(1):273-280.
9. [9]
  JIN W, XU Q, LI W. Electrophoresis, 2000, 21(7):1415-1420.JIN W, XU Q, LI W. Electrophoresis, 2000, 21(7):1415-1420.
10. [10]
  TAHA E A, SOLIMAN S M, ABDELLATEF H E, AYAD M M. Microchim. Acta, 2002, 140(3-4):175-182.TAHA E A, SOLIMAN S M, ABDELLATEF H E, AYAD M M. Microchim. Acta, 2002, 140(3-4):175-182.
11. [11]
  SHUKLA R P, BEN-YOAV H. ADV. Healthcare Mater., 2019, 8(15):1900462.SHUKLA R P, BEN-YOAV H. ADV. Healthcare Mater., 2019, 8(15):1900462.
12. [12]
  HERNÁNDEZ L, GONZÁLEZ E, HERNÁNDEZ P. Analyst, 1988, 113(11):1715-1718.HERNÁNDEZ L, GONZÁLEZ E, HERNÁNDEZ P. Analyst, 1988, 113(11):1715-1718.
13. [13]
  FARHADI K, KARIMPOUR A. Anal. Sci., 2007, 23(4):479-483.FARHADI K, KARIMPOUR A. Anal. Sci., 2007, 23(4):479-483.
14. [14]
  MANJUNATHA J G, SWAMY B E K, MAMATHA G P, GILBERT O, SHERIGARA B S. Der Pharma Chem., 2011, 3(2):236-249.MANJUNATHA J G, SWAMY B E K, MAMATHA G P, GILBERT O, SHERIGARA B S. Der Pharma Chem., 2011, 3(2):236-249.
15. [15]
  ATTASA S A. Int. J. Electrochem. Sci., 2009, 4(1):20-29.ATTASA S A. Int. J. Electrochem. Sci., 2009, 4(1):20-29.
16. [16]
  ZHAO Y, CHEN S, SUN B, SU D, HUANG X, LIU H, YAN Y, SUN K, WANG G. Sci. Rep., 2015, 5:7629.ZHAO Y, CHEN S, SUN B, SU D, HUANG X, LIU H, YAN Y, SUN K, WANG G. Sci. Rep., 2015, 5:7629.
17. [17]
  SALIMI A, HALLAJ R. J. Solid State Electrochem., 2012, 16(3):1239-1246.SALIMI A, HALLAJ R. J. Solid State Electrochem., 2012, 16(3):1239-1246.
18. [18]
  LI X, LIU L, DONG X, ZHAO G, LI Y, MIAO J, FANG J, CUI M, WEI Q, CAO W. Biosens. Bioelectron., 2019, 126(11):448-454.LI X, LIU L, DONG X, ZHAO G, LI Y, MIAO J, FANG J, CUI M, WEI Q, CAO W. Biosens. Bioelectron., 2019, 126(11):448-454.
19. [19]
  WANG Y G, ZHAO G H, LI X J, LIU L, CAO W, WEI Q. Biosens. Bioelectron., 2018, 101:290-296.WANG Y G, ZHAO G H, LI X J, LIU L, CAO W, WEI Q. Biosens. Bioelectron., 2018, 101:290-296.
20. [20]
  DONG X, ZHAO G, LIU L, LI X, WEI Q, CAO W. Biosens.Bioelectron., 2018, 110:201-206.DONG X, ZHAO G, LIU L, LI X, WEI Q, CAO W. Biosens.Bioelectron., 2018, 110:201-206.
21. [21]
  YANG J, LIU H, MARTENS W N, FROST R L. J. Phys. Chem. C, 2010, 114(1):111-119.YANG J, LIU H, MARTENS W N, FROST R L. J. Phys. Chem. C, 2010, 114(1):111-119.
22. [22]
  SALIMI A, MAMKHEZRI H, HALLAJ R, SOLTANIAN S. Sens. Actuators, B, 2008, 129(1):246-254.SALIMI A, MAMKHEZRI H, HALLAJ R, SOLTANIAN S. Sens. Actuators, B, 2008, 129(1):246-254.
23. [23]
  YAN N, HU L, LI Y, WANG Y, ZHONG H, HU X, CHEN Q. J. Phys. Chem. C, 2012, 116(12):7227-7235.YAN N, HU L, LI Y, WANG Y, ZHONG H, HU X, CHEN Q. J. Phys. Chem. C, 2012, 116(12):7227-7235.
24. [24]
  XU J, LI F, WANG D, NAWAZ M H, AN Q, HAN D, NIU L. Biosens. Bioelectron., 2019, 123:25-29.XU J, LI F, WANG D, NAWAZ M H, AN Q, HAN D, NIU L. Biosens. Bioelectron., 2019, 123:25-29.
25. [25]
  LU Z, ZHONG J, ZHANG Y, SUN M, ZOU P, DU H, WANG X, RAO H, WANG Y. J. Alloys Compd., 2020, 858(20):1016-1027.LU Z, ZHONG J, ZHANG Y, SUN M, ZOU P, DU H, WANG X, RAO H, WANG Y. J. Alloys Compd., 2020, 858(20):1016-1027.
26. [26]
  LI X N, YUAN L Z, WANG J H, JIANG L H, RYKOV A I, NAGY D L, BOGDAN C, AHMED M A, ZHU K Y, SUN G Q, YANG W S. Nanoscale, 2016, 8(4):2333-2342.LI X N, YUAN L Z, WANG J H, JIANG L H, RYKOV A I, NAGY D L, BOGDAN C, AHMED M A, ZHU K Y, SUN G Q, YANG W S. Nanoscale, 2016, 8(4):2333-2342.
27. [27]
  WANG Q, ZHAO J, TRICARD S, FANG J. J. Alloys Compd., 2021, 860:158176.WANG Q, ZHAO J, TRICARD S, FANG J. J. Alloys Compd., 2021, 860:158176.
28. [28]
  ROUQUEROL F, ROUQUEROL J, SING K. Chemical Thermodynamics, Academic Press, 1999:77-84.ROUQUEROL F, ROUQUEROL J, SING K. Chemical Thermodynamics, Academic Press, 1999:77-84.
29. [29]
  KRUK M, JARONIEC M. Chem. Mater., 2001, 13(10):3169-3183.KRUK M, JARONIEC M. Chem. Mater., 2001, 13(10):3169-3183.
30. [30]
  PARK M, KOMARNENI S. Microporous Mesoporous Mater., 1998, 25(1):75-80.PARK M, KOMARNENI S. Microporous Mesoporous Mater., 1998, 25(1):75-80.
31. [31]
  BRUNAUER S, EMMETT P H,TELLER E. J. Am. Chem. Soc., 1938, 60(2):309-319.BRUNAUER S, EMMETT P H,TELLER E. J. Am. Chem. Soc., 1938, 60(2):309-319.
32. [32]
  CHEN W, GHOSH D, CHEN S. J. Mater. Sci., 2008, 43(15):5291-5299.CHEN W, GHOSH D, CHEN S. J. Mater. Sci., 2008, 43(15):5291-5299.
33. [33]
  ABED M, GHASEMI B, OVEISI H, HABIBOLAHZADEH A, ZIRAK M. Mater. Sci. Eng. C, 2021, 264(1):114926-114935.ABED M, GHASEMI B, OVEISI H, HABIBOLAHZADEH A, ZIRAK M. Mater. Sci. Eng. C, 2021, 264(1):114926-114935.
34. [34]
  MORETTI G, GERVAIS C. J. Raman Spectrosc., 2017, 49(7):1198-1204.MORETTI G, GERVAIS C. J. Raman Spectrosc., 2017, 49(7):1198-1204.
35. [35]
  JIANG X, ZHANG L, WANG T, WAN Q. J. Appl. Phys., 2009, 106(10):104316.JIANG X, ZHANG L, WANG T, WAN Q. J. Appl. Phys., 2009, 106(10):104316.
36. [36]
  ZHAO S, LI C, LIU J, LIU N, QIAO S, HAN Y, HUANG H, LIU Y, KANG Z. Carbon, 2015, 92(3):64-73.ZHAO S, LI C, LIU J, LIU N, QIAO S, HAN Y, HUANG H, LIU Y, KANG Z. Carbon, 2015, 92(3):64-73.
37. [37]
  DEVI R K, MUTHUSANKAR G, GOPU G, BERCHMANS L. Colloids Surf., A, 2020, 598:124825.DEVI R K, MUTHUSANKAR G, GOPU G, BERCHMANS L. Colloids Surf., A, 2020, 598:124825.
38. [38]
  XUN S, XU Y, HE J, JIANG D, YANG R, LI D, CHEN M. J. Alloys Compd., 2019, 806(7):1097-1104.XUN S, XU Y, HE J, JIANG D, YANG R, LI D, CHEN M. J. Alloys Compd., 2019, 806(7):1097-1104.
39. [39]
  GUO L, CHEN F, XIE N, WANG C, KOU X, SUN Y, MA J, LIANG X, GAO Y, LU G. J. Colloid Interface Sci., 2018, 528(5):53-62.GUO L, CHEN F, XIE N, WANG C, KOU X, SUN Y, MA J, LIANG X, GAO Y, LU G. J. Colloid Interface Sci., 2018, 528(5):53-62.
40. [40]
  SUPRAJA P, TRIPATHY S, VANJARI S R K, SINGH V, SINGH S G. Biosens. Bioelectron., 2019, 141:111441.SUPRAJA P, TRIPATHY S, VANJARI S R K, SINGH V, SINGH S G. Biosens. Bioelectron., 2019, 141:111441.
41. [41]
  LV Y K, LI Y Y, ZHOU R H, PAN Y P, YAO H C, LI Z J. ACS Appl. Mater. Interfaces, 2020, 12(30):34245-34253.LV Y K, LI Y Y, ZHOU R H, PAN Y P, YAO H C, LI Z J. ACS Appl. Mater. Interfaces, 2020, 12(30):34245-34253.
42. [42]
  TAMMARI E, NEZHADALI A, LOTFI S, VEISI H. Sens. Actuators, B, 2017, 241(11):879-886.TAMMARI E, NEZHADALI A, LOTFI S, VEISI H. Sens. Actuators, B, 2017, 241(11):879-886.
43. [43]
  LU Z, ZHONG J, ZHANG Y, SUN M, ZOU P, DU H, WANG X, RAO H, WANG Y. J. Alloys Compd., 2021, 858(20):1016-1027.LU Z, ZHONG J, ZHANG Y, SUN M, ZOU P, DU H, WANG X, RAO H, WANG Y. J. Alloys Compd., 2021, 858(20):1016-1027.
44. [44]
  WANG L, MENG T, FAN Y, CHEN C, GUO Z, WANG H, ZHANG Y. J. Colloid Interface Sci., 2018, 524(4):1-7.WANG L, MENG T, FAN Y, CHEN C, GUO Z, WANG H, ZHANG Y. J. Colloid Interface Sci., 2018, 524(4):1-7.
45. [45]
  SHUKLA R P, CAZELLES R, KELLY D L, BEN-YOAV H. Talanta, 2020, 209:120560.SHUKLA R P, CAZELLES R, KELLY D L, BEN-YOAV H. Talanta, 2020, 209:120560.
46. [46]
  SHAHROKHIAN S, KAMALZADEH Z, HAMZEHLOEI A. Bioelectrochemistry, 2013, 90(10):36-43.SHAHROKHIAN S, KAMALZADEH Z, HAMZEHLOEI A. Bioelectrochemistry, 2013, 90(10):36-43.
47. [47]
  QU S, PEI S, ZHANG S, SONG P. Mater. Lett., 2013, 102(3):56-58.QU S, PEI S, ZHANG S, SONG P. Mater. Lett., 2013, 102(3):56-58.
48. [48]
  CHEN Y, WANG Z, LIU S, ZHAO G. J. Hazard. Mater., 2021, 412:125174.CHEN Y, WANG Z, LIU S, ZHAO G. J. Hazard. Mater., 2021, 412:125174.
49. [49]
  LIU S, CHEN Y, WANG Y, ZHAO G. Anal. Chem., 2019, 91(12):7639-7647.LIU S, CHEN Y, WANG Y, ZHAO G. Anal. Chem., 2019, 91(12):7639-7647.

扫一扫看文章

计量

PDF下载量: 16
文章访问数: 1212
HTML全文浏览量: 232

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

钴-钴普鲁士蓝类似物衍生的SnCoO_x中空纳米立方体的制备及电化学检测氯氮平的性能研究

通讯作者: 赵继华,E-mail:zhaojihua@lzu.edu.cn; 方建,E-mail:fangj@lzu.edu.cn

English

Preparation of Prussian Blue Analogues-derived SnCoO_x Hollow Nanocubes and Study on Performance of Electrochemical Detection of Clozapin

Corresponding author: ZHAO Ji-Hua, ; FANG Jian,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

钴-钴普鲁士蓝类似物衍生的SnCoOx中空纳米立方体的制备及电化学检测氯氮平的性能研究

通讯作者: 赵继华,E-mail:zhaojihua@lzu.edu.cn; 方建,E-mail:fangj@lzu.edu.cn

English

Preparation of Prussian Blue Analogues-derived SnCoOx Hollow Nanocubes and Study on Performance of Electrochemical Detection of Clozapin

Corresponding author: ZHAO Ji-Hua, ; FANG Jian,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

钴-钴普鲁士蓝类似物衍生的SnCoO_x中空纳米立方体的制备及电化学检测氯氮平的性能研究

Preparation of Prussian Blue Analogues-derived SnCoO_x Hollow Nanocubes and Study on Performance of Electrochemical Detection of Clozapin

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs