钴-钴普鲁士蓝类似物衍生的SnCoOx中空纳米立方体的制备及电化学检测氯氮平的性能研究

王强明 蒋成 赵继华 方建

引用本文: 王强明, 蒋成, 赵继华, 方建. 钴-钴普鲁士蓝类似物衍生的SnCoOx中空纳米立方体的制备及电化学检测氯氮平的性能研究[J]. 分析化学, 2022, 50(3): 392-404. doi: 10.19756/j.issn.0253-3820.210608 shu
Citation:  WANG Qiang-Ming,  JIANG Cheng,  ZHAO Ji-Hua,  FANG Jian. Preparation of Prussian Blue Analogues-derived SnCoOx Hollow Nanocubes and Study on Performance of Electrochemical Detection of Clozapin[J]. Chinese Journal of Analytical Chemistry, 2022, 50(3): 392-404. doi: 10.19756/j.issn.0253-3820.210608 shu

钴-钴普鲁士蓝类似物衍生的SnCoOx中空纳米立方体的制备及电化学检测氯氮平的性能研究

    通讯作者: 赵继华,E-mail:zhaojihua@lzu.edu.cn; 方建,E-mail:fangj@lzu.edu.cn
  • 基金项目:

    国家自然科学基金项目(Nos.21773097,21403098)资助。

摘要: 通过化学沉淀法合成了钴-钴普鲁士蓝类似物(CoCo-PBA)纳米立方前驱体,掺杂Sn4+后,将其在空气中高温热解,制备中空多孔SnCoOx,然后通过超声将SnCoOx固定在石墨毡(GF)上,制成复合电极(SnCoOx/GF)。利用X-射线衍射(XRD)、傅里叶变换红外光谱(FT-IR)、X-射线光电子能谱(XPS)、扫描电子显微镜(SEM)和透射电子显微镜(TEM)以及电化学工作站对电极材料的结构和形貌进行了表征,并测试了其电化学性能。将SnCoOx/GF复合电极用于检测药物分子氯氮平(CLZ),结果表明,复合电极对CLZ氧化表现出良好的电催化活性(催化速率常数kcat=1.04×105 L/(mol·s)),线性检测范围为0.01~100 μmol/L,灵敏度为6.02(A·L)/mol,检出限(LOD,S/N=3)为0.7 nmol/L。SnCoOx/GF复合电极具有良好的稳定性、较强的抗干扰性及实用性,为电化学检测CLZ提供了一种新方法。

English


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  • 收稿日期:  2021-07-05
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