银-金双金属纳米管的可控制备及其对汗液中葡萄糖的无创检测

高难 王帅澎 刘旭 夏大成 蔡志伟 常钢 何云斌

引用本文: 高难, 王帅澎, 刘旭, 夏大成, 蔡志伟, 常钢, 何云斌. 银-金双金属纳米管的可控制备及其对汗液中葡萄糖的无创检测[J]. 分析化学, 2021, 49(10): 1640-1648. doi: 10.19756/j.issn.0253-3820.210601 shu
Citation:  GAO Nan,  WANG Shuai-Peng,  LIU Xu,  XIA Da-Cheng,  CAI Zhi-Wei,  CHANG Gang,  HE Yun-Bin. Controllable Preparation of Ag-Au Bimetallic Nanotubes for Non-invasive Detection of Glucose in Sweat[J]. Chinese Journal of Analytical Chemistry, 2021, 49(10): 1640-1648. doi: 10.19756/j.issn.0253-3820.210601 shu

银-金双金属纳米管的可控制备及其对汗液中葡萄糖的无创检测

    通讯作者: 常钢,E-mail:changgang@hubu.edu.cn; 何云斌,E-mail:ybhe@hubu.edu.cn
  • 基金项目:

    国家自然科学基金项目(Nos.51672074,11774082,11975093)、湖北省自然科学基金项目(No.2019CFA006)和武汉市应用基金前沿项目(No.201801041011287)资助。

摘要: 实时监测血糖水平对糖尿病患者的诊断和治疗具有重要意义,而传统的酶法微创测定存在稳定性低、体验感差等问题。本研究以银纳米线为模板,采用一步伽伐尼置换反应(Galvanic replacement reaction)制备高质量的银-金双金属纳米管(Ag-Au BMNTs),实现了对葡萄糖的无酶、无创测定。通过优化HAuCl4的含量,可调控Ag-Au BMNTs的形貌及组分。研究结果表明,Ag-Au BMNTs检测葡萄糖具有检测范围宽(1 μmol/L~3.79 mmol/L,3.79~13.79 mmol/L)、灵敏度高(154.09 μA/(mmol/L)、60.77 μA/(mmol/L)和检出限低(1 μmol/L)等特点。同时,此传感器表现出良好的抗干扰性能和稳定性,可用于人体汗液中葡萄糖含量的准确测定。基于Ag-Au BMNTs的电化学传感器在无酶、无创血糖检测中具有良好的潜在应用价值。

English


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  • 收稿日期:  2021-07-01
  • 修回日期:  2021-08-03
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