注射器内空气辅助萃取-小型便携式质谱法现场快速检测纺织品中的12种有害染料

华韵晨 倪章 郭项雨 陈萌 白桦 马潇潇 李晓旭 马强

引用本文: 华韵晨, 倪章, 郭项雨, 陈萌, 白桦, 马潇潇, 李晓旭, 马强. 注射器内空气辅助萃取-小型便携式质谱法现场快速检测纺织品中的12种有害染料[J]. 分析化学, 2022, 50(5): 757-763. doi: 10.19756/j.issn.0253-3820.210493 shu
Citation:  HUA Yun-Chen,  NI Zhang,  GUO Xiang-Yu,  CHEN Meng,  BAI Hua,  MA Xiao-Xiao,  LI Xiao-Xu,  MA Qiang. Rapid On-Site Analysis of 12 Kinds of Hazardous Colorants in Textiles Using In-Syringe Air-Assisted Extraction Coupled with a Miniature Mass Spectrometer[J]. Chinese Journal of Analytical Chemistry, 2022, 50(5): 757-763. doi: 10.19756/j.issn.0253-3820.210493 shu

注射器内空气辅助萃取-小型便携式质谱法现场快速检测纺织品中的12种有害染料

    通讯作者: 李晓旭,E-mail:xxli@suda.edu.cn; 马强,E-mail:maqiang@caiq.org.cn
  • 基金项目:

    国家自然科学基金项目(No.2194129)和国家市场监督管理总局科技计划项目(No.2019MK124)资助。

摘要: 采用注射器内空气辅助萃取技术,结合自主研发的小型化线形离子阱质谱仪,建立了纺织品中12种有害染料的现场快速检测方法。通过具有微小内径的金属中空针尖,可使空气以较高速率进入注射器内,扰动萃取溶剂形成湍流漩涡,从而高效萃取注射器内的纺织品样品。对注射器内空气辅助萃取的流体动力学进行模拟分析,并对萃取溶剂、萃取次数及喷雾电压等条件进行了优化。萃取完成后,萃取溶剂可在注射器针尖处形成电喷雾,采用小型便携式质谱仪进行检测。本方法对12种染料的检出限为0.15~2.50 mg/kg,定量限为0.40~6.00 mg/kg,回收率在80.1%~106.4%之间,相对标准偏差为7.5%~15.6%。本方法简便高效,可用于纺织品样品的现场快速检测。

English


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  • 收稿日期:  2021-05-10
  • 修回日期:  2022-02-21
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