Citation: LIU Yu-Can, WANG Ying, ZHU Yu-Liang, JI Xian-Guo, LI Wei. Simultaneous Determination of Thirteen Kinds of Volatile Disinfection By-products in Water by Gas Chromatography-Tandem Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(1): 145-152. doi: 10.19756/j.issn.0253-3820.210411 shu

Simultaneous Determination of Thirteen Kinds of Volatile Disinfection By-products in Water by Gas Chromatography-Tandem Mass Spectrometry

LIU Yu-Can ^1,, ,
WANG Ying ¹ ,
ZHU Yu-Liang ¹ ,
JI Xian-Guo ¹ ,
LI Wei ²

1.
School of Civil Engineering, Yantai University, Yantai 264005, China;
2.
School of Environmental & Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China

Corresponding author: LIU Yu-Can, liuyucan@ytu.edu.cn
Received Date: 3 April 2021
Revised Date: 12 November 2021

Fund Project: Supported by the Natural Science Foundation of Shandong Province, China (Nos.ZR202103070178, ZR2017BEE016), the National Natural Science Foundation of China (No.51609207) and the Science Fund of Yantai University (No.TM17B19).

Thirteen kinds of volatile disinfection by-products (V-DBPs) in water were determined by gas chromatography-triple quadrupole mass spectrometer (GC-MS/MS). GC-MS/MS was used to identify the precursor ions and product ions of 13 kinds of V-DBPs, and the operating parameters of chromatography and mass spectrometry were optimized. The optimal operation parameters of four typical sample pretreatment methods (liquid-liquid extraction (LLE), static headspace (SH), purge and trap (P&T) and solid phase microextraction (SPME) were determined, and their accuracy and precision were compared and analyzed. The standard curves of 13 kinds of V-DBPs were established using the optimized pretreatment method and instrument parameter setting. The results showed that the precision of the method was in accordance with SPME>SH>P&T>LLE when the concentration of 13 kinds of V-DBPs ranged from 0.05 μg/L to 100 μg/L. The four pretreatment methods had good detection precision when 2.5 and 25 μg/L mixed standards of V-DBPs were added to surface water, groundwater and tap water, and the accuracy of the method was in accordance with LLE, P&T>SH>SPME. The detection method based on GC-MS/MS was superior to the existing detection methods, and could meet the needs of rapid and accurate determination of 13 kinds of V-DBPs in discharge water after disinfection.
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