Citation: CHEN Yang, ZHAO Jie, ZHANG Jia-Hui, LI Jing, DU Pei-Yao, LU Xiao-Quan. Integration of Rhodamine B into Zirconium-based Metal-organic Framework for Selective Detection of Ferric Ion[J]. Chinese Journal of Analytical Chemistry, ;2021, 49(4): 642-651. doi: 10.19756/j.issn.0253-3820.201735 shu

Integration of Rhodamine B into Zirconium-based Metal-organic Framework for Selective Detection of Ferric Ion

CHEN Yang ¹ ,
ZHAO Jie ¹ ,
ZHANG Jia-Hui ¹ ,
LI Jing ¹ ,
DU Pei-Yao ^1,, ,
LU Xiao-Quan ^2,,

1.
Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China;
2.
Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, China

Corresponding author: DU Pei-Yao, LU Xiao-Quan,
Received Date: 7 December 2020
Revised Date: 20 January 2021

Fund Project: Supported by the National Natural Science Foundation of China (Nos.21575115, 22001193), the Program of Gansu Provincial Higher Education Research Project (No.2017-D-01) and the Special Fund Project for the Central Government to Guide Local Science and Technology Development (2020).

Rhodamine B (RhB) dyes usually have no selectivity in fluorescence detection of Fe³⁺, which limits their application in analytical detection. In this study, a composite material (RhB@PCN-777) with RhB encapsulated in a zirconium-based organic framework (PCN-777) channel was synthesized and applied to the specific detection of Fe³⁺ in water. Compared with free RhB, RhB@PCN-777 exhibited drastically improved fluorescence stability and high selectivity for the determination of Fe³⁺. RhB@PCN-777 composite featured a yellow emission at 586 nm when dispersed in aqueous solution, which could detect Fe³⁺ in water with high sensitivity and selectivity, with a detection limit as low as 0.16 μmol/L. Moreover, RhB@PCN-777 was successfully used to detect Fe³⁺ in real water samples with recoveries ranging from 94.2% to 103.9%, indicating that the fluorescent probe had high reliability in actual environmental aqueous samples.
- Fluorescence sensing,
- Metal-organic framework,
- Ferric ion,
- Rhodamine B,
- Selectivity
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