Citation: LIU Tian-Xin, JIANG Lang, YANG Hong, CAO Ke-Qi, XU Ling, HUANG Yi, AN Rong, ZHANG Xiao-Hua, QING Xiang-Dong, ZHOU Xiao-Hong. A Novel Chemometrics Coupling Technique for Source Apportionment of 11 Kinds of Polycyclic Aromatic Hydrocarbons in Steel-industrial Soil[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(5): 791-800. doi: 10.19756/j.issn.0253-3820.201524 shu

A Novel Chemometrics Coupling Technique for Source Apportionment of 11 Kinds of Polycyclic Aromatic Hydrocarbons in Steel-industrial Soil

LIU Tian-Xin ¹ ,
JIANG Lang ¹ ,
YANG Hong ¹ ,
CAO Ke-Qi ² ,
XU Ling ¹ ,
HUANG Yi ¹ ,
AN Rong ¹ ,
ZHANG Xiao-Hua ³ ,
QING Xiang-Dong ^1,2,, ,
ZHOU Xiao-Hong ^1,,

1.
Hunan Provincial Key Laboratory of Dark Tea and Jin-hua, College of Materials and Chemical Engineering, Hunan City University, Yiyang 413000, China;
2.
School of Materials and Environmental Engineering, Hunan University of Humanities, Science and Technology, Loudi 417000, China;
3.
Henan Key Laboratory of Biomarker Based Rapid-detection Technology for Food Safety, Food and Pharmacy College, Xuchang University, Xuchang 461000, China

Corresponding author: QING Xiang-Dong, ZHOU Xiao-Hong,
Received Date: 30 August 2020
Revised Date: 10 January 2022

Fund Project: Supported by the National Natural Science Foundation of China (No.32172300), the Research Foundation of Education Bureau of Hunan Province, China (Nos.21B0720, 19C0345) and the Hunan Provincial Natural Science Foundation, China (No.2021JJ50151).

A novel chemometrics coupling technique was proposed for the source apportionment of 11 kinds of polycyclic aromatic hydrocarbons (PAHs) in six topsoils around the steel-industrial region and five nonindustrial topsoils. First, the second-order calibration method based on alternating trilinear decomposition was used to decompose the gas chromatography-mass spectrum-soil sample three-way data array, then component analysis and multiple diagnostic ratios were applied to the source apportionment of 11 kinds of PAHs in the steel-industrial topsoils according to the composition and content of PAHs. The research finding showed that the resolved chromatographic and mass spectral profiles of 11 kinds of PAHs were similar to their actual ones. The found PAHs were less than two kinds, and their total concentrations were less than 25.9 μg/kg in nonindustrial topsoil samples, but the found PAHs were in the range of seven kinds to eleven kinds and total PAHs' concentrations ranged from 249.1 to 2089.1 μg/kg in industrial topsoil samples, and the highest concentration of individual PAH in industrial topsoil samples was 600.4 μg/kg for acenaphthylene. The source of PAHs in these samples mainly came from high temperature combustion of industrial coal, and the combustion and leakage of oil product made a little contribution to the PAHs' pollution to the industrial topsoil. These results demonstrated that the developed method was a simple, fast, accurate and green analytical strategy for identification, quantification and source apportionment of PAHs in actual soil.
- Polycyclic aromatic hydrocarbon,
- Source apportionment,
- Soil,
- Alternating trilinear decomposition,
- Gas chromatography-mass spectrometry,
- Multiple diagnostic ratio
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