一种化学计量学耦合新技术用于钢铁工业区土壤中11种多环芳烃的源解析

引用本文: 刘添鑫, 姜浪, 杨红, 曹科奇, 徐玲, 黄毅, 安蓉, 张晓华, 卿湘东, 周晓红. 一种化学计量学耦合新技术用于钢铁工业区土壤中11种多环芳烃的源解析[J]. 分析化学, 2022, 50(5): 791-800. doi: 10.19756/j.issn.0253-3820.201524 shu

Citation: LIU Tian-Xin, JIANG Lang, YANG Hong, CAO Ke-Qi, XU Ling, HUANG Yi, AN Rong, ZHANG Xiao-Hua, QING Xiang-Dong, ZHOU Xiao-Hong. A Novel Chemometrics Coupling Technique for Source Apportionment of 11 Kinds of Polycyclic Aromatic Hydrocarbons in Steel-industrial Soil[J]. Chinese Journal of Analytical Chemistry, 2022, 50(5): 791-800. doi: 10.19756/j.issn.0253-3820.201524 shu

一种化学计量学耦合新技术用于钢铁工业区土壤中11种多环芳烃的源解析

刘添鑫 ^1, ,
姜浪 ^1, ,
杨红 ^1, ,
曹科奇 ^2, ,
徐玲 ^1, ,
黄毅 ^1, ,
安蓉 ^1, ,
张晓华 ^3, ,
卿湘东 ^{1,2,
,} ,
周晓红 ^{1,
,}

1.
湖南城市学院材料与化学工程学院, 黑茶金花湖南省重点实验室, 益阳 413000;
2.
湖南人文科技学院材料与环境工程学院, 娄底 417000;
3.
许昌学院食品与药学院, 河南省食品安全生物标识快检技术重点实验室, 许昌 461000

通讯作者: 卿湘东,E-mail:xdqing123@hnu.edu.cn; 周晓红,E-mail:zhouxiaohong1201@163.com

基金项目:
国家自然科学基金项目（No.32172300）、湖南省教育厅科学研究基金项目（Nos.21B0720，19C0345）和湖南省自然科学基金项目（No.2021JJ50151）资助。

摘要: 建立了一种用于源解析钢铁工业区土壤中11种多环芳烃（PAHs）的化学计量学耦合新技术。首先采用基于交替三线性分解的二阶校正方法处理气相色谱-质谱-土壤样本三维数阵，然后耦合成分分析法和多特征比率法分析PAHs组成及含量，并进行污染源解析。研究结果表明，从实际土壤数据中获得的11种PAHs的色谱和质谱图与真实谱图基本吻合；在非工业区表层土壤（对照组）中最多检测出2种PAHs，PAHs总含量小于25.9 μg/kg，而在工业区表层土壤中检测出7~11种PAHs，PAHs总含量在249.1~2089.1 μg/kg之间，其中苊烯的浓度最高（600.4 μg/kg）；源解析结果说明，钢铁工业区表层土壤中PAHs主要来源于工业燃煤，而石油类燃烧和泄漏所产生的PAHs较少。本方法快速、准确、绿色、环保，为土壤中PAHs类有机污染物的防治提供了一种有潜力的分析方法。

关键词:

English

A Novel Chemometrics Coupling Technique for Source Apportionment of 11 Kinds of Polycyclic Aromatic Hydrocarbons in Steel-industrial Soil

1.
Hunan Provincial Key Laboratory of Dark Tea and Jin-hua, College of Materials and Chemical Engineering, Hunan City University, Yiyang 413000, China;
2.
School of Materials and Environmental Engineering, Hunan University of Humanities, Science and Technology, Loudi 417000, China;
3.
Henan Key Laboratory of Biomarker Based Rapid-detection Technology for Food Safety, Food and Pharmacy College, Xuchang University, Xuchang 461000, China

Corresponding author: QING Xiang-Dong, ; ZHOU Xiao-Hong,

Received Date: 30 August 2020
Revised Date: 10 January 2022
Fund Project:
Supported by the National Natural Science Foundation of China (No.32172300), the Research Foundation of Education Bureau of Hunan Province, China (Nos.21B0720, 19C0345) and the Hunan Provincial Natural Science Foundation, China (No.2021JJ50151).

Abstract: A novel chemometrics coupling technique was proposed for the source apportionment of 11 kinds of polycyclic aromatic hydrocarbons (PAHs) in six topsoils around the steel-industrial region and five nonindustrial topsoils. First, the second-order calibration method based on alternating trilinear decomposition was used to decompose the gas chromatography-mass spectrum-soil sample three-way data array, then component analysis and multiple diagnostic ratios were applied to the source apportionment of 11 kinds of PAHs in the steel-industrial topsoils according to the composition and content of PAHs. The research finding showed that the resolved chromatographic and mass spectral profiles of 11 kinds of PAHs were similar to their actual ones. The found PAHs were less than two kinds, and their total concentrations were less than 25.9 μg/kg in nonindustrial topsoil samples, but the found PAHs were in the range of seven kinds to eleven kinds and total PAHs' concentrations ranged from 249.1 to 2089.1 μg/kg in industrial topsoil samples, and the highest concentration of individual PAH in industrial topsoil samples was 600.4 μg/kg for acenaphthylene. The source of PAHs in these samples mainly came from high temperature combustion of industrial coal, and the combustion and leakage of oil product made a little contribution to the PAHs' pollution to the industrial topsoil. These results demonstrated that the developed method was a simple, fast, accurate and green analytical strategy for identification, quantification and source apportionment of PAHs in actual soil.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

一种化学计量学耦合新技术用于钢铁工业区土壤中11种多环芳烃的源解析

通讯作者: 卿湘东,E-mail:xdqing123@hnu.edu.cn; 周晓红,E-mail:zhouxiaohong1201@163.com

English

A Novel Chemometrics Coupling Technique for Source Apportionment of 11 Kinds of Polycyclic Aromatic Hydrocarbons in Steel-industrial Soil

Corresponding author: QING Xiang-Dong, ; ZHOU Xiao-Hong,

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

一种化学计量学耦合新技术用于钢铁工业区土壤中11种多环芳烃的源解析

通讯作者: 卿湘东,E-mail:xdqing123@hnu.edu.cn; 周晓红,E-mail:zhouxiaohong1201@163.com

English

A Novel Chemometrics Coupling Technique for Source Apportionment of 11 Kinds of Polycyclic Aromatic Hydrocarbons in Steel-industrial Soil

Corresponding author: QING Xiang-Dong, ; ZHOU Xiao-Hong,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

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