基于CdTe量子点-电纺纳米纤维组装体可视化、便携检测铜离子

引用本文: 李夏楚秦, 杨通, 王健, 黄承志. 基于CdTe量子点-电纺纳米纤维组装体可视化、便携检测铜离子[J]. 分析化学, 2021, 49(2): 207-215. doi: 10.19756/j.issn.0253-3820.201483 shu

Citation: LI Xia-Chu-Qin, YANG Tong, WANG Jian, HUANG Cheng-Zhi. CdTe Quantum Dots-Electrospun Nanofibers Assembly for Visual and Portable Detection of Cu²⁺[J]. Chinese Journal of Analytical Chemistry, 2021, 49(2): 207-215. doi: 10.19756/j.issn.0253-3820.201483 shu

基于CdTe量子点-电纺纳米纤维组装体可视化、便携检测铜离子

李夏楚秦 ^1, ,
杨通 ^2, ,
王健 ^{2,
,} ,
黄承志 ^{1,2,
,}

1.
西南大学化学化工学院, 发光分析与分子传感教育部重点实验室, 重庆 400715;
2.
西南大学药学院, 发光与实时分析系统重庆市重点实验室, 重庆 400715

通讯作者: 王健,E-mail:wj123456@swu.edu.cn; 黄承志,E-mail:chengzhi@swu.edu.cn

基金项目:
国家自然科学基金项目（No.21535006）资助。

摘要: 采用静电纺丝技术制备得到抗湿性能良好的电纺纳米纤维，进一步与CdTe量子点（CdTe QDs）静电结合得到组装体。扫描电镜、透射电镜和共聚焦荧光显微成像表征结果表明，在pH 7.2、静电组装时间90 min的条件下，CdTe QDs均匀地组装在电纺纳米纤维表面，在365 nm紫外灯照射下，CdTe QDs-电纺纳米纤维组装体呈现红色荧光，而Cu²⁺能显著地猝灭CdTe QDs-电纺纳米纤维组装体的荧光，其猝灭程度与Cu²⁺浓度在0.08~800 μmol/L范围内呈现良好的线性关系，检出限为11.1 nmol/L。本方法简单、便携、选择性好，并成功应用于环境水样中Cu²⁺的可视化及便携检测。

关键词:

English

CdTe Quantum Dots-Electrospun Nanofibers Assembly for Visual and Portable Detection of Cu²⁺

1.
Key Laboratory of Luminescence Analysis and Molecular Sensing, Ministry of Education, College of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China;
2.
Key Laboratory of Luminescent and Real-Time Analytical System, Chongqing Science and Technology Bureau, College of Pharmaceutical Sciences, Southwest University, Chongqing 400715, China

Corresponding author: WANG Jian, ; HUANG Cheng-Zhi,

Received Date: 11 August 2020
Revised Date: 26 October 2020
Fund Project:
Supported by the National Natural Science Foundation of China (No. 21535006).

Abstract: Electrospun nanofibers (NFs) with good moisture-resistance were prepared by electrospinning technology, and further assembled with CdTe quantum dots (CdTe QDs). The results of scanning electron microscopy, transmission electron microscopy and confocal fluorescence microscopy showed that the CdTe QDs with strong fluorescence were uniformly assembled on the electrospun NFs after the electrostatic adsorption for 90 min at pH 7.2. Under 365 nm excitation, the CdTe QDs-electrospun NFs assembly presented red fluorescence, which could be significantly quenched by copper ion (Cu²⁺), and the fluorescence quenching degree of CdTe QDs electrospun NFs assembly showed a good linear relationship with concentration of Cu²⁺ in the concentration range of 0.08-800 μmol/L, and the detection limit was 11.1 nmol/L (S/N=3). This method had advantages of simplicity and high selectivity, and was successfully applied to the visualization and portable detection of copper ions in environmental water samples.

Key words:

1. [1]
  HAN O, WESSLING-RESNICK M. Am. J. Physiol. Gastrointest. Liver Physiol., 2002, 282(3):G527-G533.
2. [2]
  CHEN L, TIAN X, YANG C, LI Y, ZHOU Z, WANG Y, XIANG F. Sens. Actuators B, 2017, 240:66-75.
3. [3]
  AYDŁN H, BULUT Y, YERLIKAYA Ç. J. Environ. Manage., 2008, 87(1):37-45.
4. [4]
  LILJA C, BETOVA I, BOJINOV M. Electrochim. Acta, 2016, 202:333-344.
5. [5]
  JI L, CHENG Q, WU K, YANG X. Sens. Actuators B, 2016, 231:12-17.
6. [6]
  AYALA-CABRERA J F, TRUJILLO-RODRÍGUEZ M J, PINO V, HERNÁNDEZ-TORRES Ó M, AFONSO A M, SIRIEIX-PLÉNET J. Int. J. Environ. Anal. Chem., 2015, 96(2):101-118.
7. [7]
  NAKATA K, HASHIMOTO B, UCHIHARA H, OKAMOTO Y, ISHIZAKA S, FUJIWARA T. Talanta, 2015, 138:279-284.
8. [8]
  ZORIY M V, BECKER J S. Rapid Commun. Mass Spectrom., 2009, 23(1):23-30.
9. [9]
  DU T, WANG J, ZHANG T, ZHANG L, YANG C, YUE T, SUN J, LI T, ZHOU M, WANG J. ACS Appl. Mater. Interfaces, 2020, 12(11):13189-13199.
10. [10]
  CUI Wen-Wen, XU Lin-Lin, SHI Yan-Yu, DONG Na, CHEN Ping. Chin. J. Anal. Chem., 2019, 47(12):1973-1980. 崔雯雯, 徐琳琳, 史艳宇, 董娜, 陈萍. 分析化学, 2019, 47(12):1973-1980.
11. [11]
  KHAN M M R, MITRA T, SAHOO D. RSC Adv., 2020, 10(16):9512-9524.
12. [12]
  YANG H, GAO P F, WU W B, YANG X X, ZENG Q L, LI C, HUANG C Z. Polym. Chem., 2014, 5(6):1965-1975.
13. [13]
  LIN M, ZOU H Y, YANG T, LIU Z X, LIU H, HUANG C Z. Nanoscale, 2016, 8(5):2999-3007.
14. [14]
  YANG T, LI C M, HE J H, CHEN B, LI Y F, HUANG C Z. Anal. Chem., 2018, 90(16):9966-9974.
15. [15]
  YANG T, HOU P, ZHENG L L, ZHAN L, GAO P F, LI Y F, HUANG C Z. Nanoscale, 2017, 9(43):17020-17028.
16. [16]
  WU S, DOU J, ZHANG J, ZHANG S. J. Mater. Chem., 2012, 22(29):14573-14578.
17. [17]
  YANG T, MA J, ZHEN S J, HUANG C Z. ACS Appl. Mater. Interfaces, 2016, 8(23):14802-14811.
18. [18]
  WU P, ZHAO T, WANG S, HOU X. Nanoscale, 2014, 6(1):43-64.
19. [19]
  LOU Y, ZHAO Y, CHEN J, ZHU J J. J. Mater. Chem. C, 2014, 2(4):595-613.
20. [20]
  WANG Y, ZHANG C, CHEN X, YANG B, YANG L, JIANG C, ZHANG Z. Nanoscale, 2016, 8(11):5977-5984.
21. [21]
  SENTHAMIZHAN A, CELEBIOGLU A, UYAR T. J. Mater. Chem. A, 2014, 2(32):12717-12723.
22. [22]
  ZHANG C L, LV K P, CONG H P, YU S H. Small, 2012, 8(5):647-653.
23. [23]
  GB 8978-1996, Integrated Wastewater Discharge Standard. National Standards of the People's Republic of China. 污水综合排放标准. 中华人民共和国国家标准. GB 8978-1996.
24. [24]
  HELAL A, NASIRUZZAMAN S M, ABDUL A M. J. Photochem. Photobiol. A, 2020, 389:112238.
25. [25]
  NGAMDEE K, CHAIENDOO K, SAIYASOMBAT C, BUSAYAPORN W, ITTISANRONNACHAI S, PROMARAK V, NGEONTAE W. Spectrochim. Acta, Part A, 2019, 211:313-321.
26. [26]
  WANG Y, HAO X, LIANG L, GAO L, REN X, WU Y, ZHAO H. RSC Adv., 2020, 10(10):6109-6113.
27. [27]
  ZHAO Xin-Yu, GENG Yu-Hao, TIAN Zhen-Hao, XU Jian-Hong. J. Chem. Ind. Eng. 2020, DOI:10.11949/0438-1157.20200324. 赵心语, 耿宇昊, 田震昊, 徐建鸿. 化工学报, 2020, DOI:10.11949/0438-1157.20200324.
28. [28]
  AN Chun, DU Pei-Yao, ZHANG Zhen, LU Xiao-Quan. Chin. J. Anal. Chem., 2020, 48(3):355-362. 安春, 杜佩瑶, 张振, 卢小泉. 分析化学, 2020, 48(3):355-362.
29. [29]
  YANG Qian-Hui, HAO Qing, LEI Jian-Ping, JU Huang-Xian. Chin. J. Anal. Chem., 2017, 45(12):1895-1902. 杨芊荟, 郝青, 雷建平, 鞠熀先. 分析化学, 2017, 45(12):1895-1902.
30. [30]
  ZOU C, FODA M F, TAN X, SHAO K, WU L, LU Z, BAHLOL H S, HAN H. Anal. Chem., 2016, 88(14):7395-7403.

扫一扫看文章

计量

PDF下载量: 5
文章访问数: 583
HTML全文浏览量: 68

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

基于CdTe量子点-电纺纳米纤维组装体可视化、便携检测铜离子

通讯作者: 王健,E-mail:wj123456@swu.edu.cn; 黄承志,E-mail:chengzhi@swu.edu.cn

English

CdTe Quantum Dots-Electrospun Nanofibers Assembly for Visual and Portable Detection of Cu²⁺

Corresponding author: WANG Jian, ; HUANG Cheng-Zhi,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

基于CdTe量子点-电纺纳米纤维组装体可视化、便携检测铜离子

通讯作者: 王健,E-mail:wj123456@swu.edu.cn; 黄承志,E-mail:chengzhi@swu.edu.cn

English

CdTe Quantum Dots-Electrospun Nanofibers Assembly for Visual and Portable Detection of Cu2+

Corresponding author: WANG Jian, ; HUANG Cheng-Zhi,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CdTe Quantum Dots-Electrospun Nanofibers Assembly for Visual and Portable Detection of Cu²⁺

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs