流体包裹体CO<sub>2</sub>碳同位素组成的在线连续流分析方法研究

引用本文: 金贵善, 刘汉彬, 张建锋, 韩娟, 邱林飞, 李军杰, 张佳, 石晓. 流体包裹体CO₂碳同位素组成的在线连续流分析方法研究[J]. 分析化学, 2021, 49(1): 137-143. doi: 10.19756/j.issn.0253-3820.201363 shu

Citation: JIN Gui-Shan, LIU Han-Bin, ZHANG Jian-Feng, HAN Juan, QIU Lin-Fei, LI Jun-Jie, ZHANG Jia, SHI Xiao. On-line Continuous Flow Analysis of Carbon Isotopic Composition of CO₂ in Fluid Inclusions[J]. Chinese Journal of Analytical Chemistry, 2021, 49(1): 137-143. doi: 10.19756/j.issn.0253-3820.201363 shu

流体包裹体CO₂碳同位素组成的在线连续流分析方法研究

核工业北京地质研究院, 北京 100029

通讯作者: 刘汉彬,E-mail:hanbinliu@sina.com

基金项目:
国家重点研发计划项目（No.2017YFC0602600）资助。

摘要: 在矿物包裹体中CO₂碳同位素组成的分析中，通常采用离线式机械破碎或者高温加热爆裂的方式将包裹体中的CO₂释放出来，纯化后，利用同位素比质谱仪双路测试其碳同位素组成。本研究设计了一种在线连续流爆裂提取装置，通过气体转换接口Conflo Ⅳ与稳定同位素质谱仪（IRMS）连接，采用高纯氦气作为载气，将石英单矿物的包裹体加热爆裂释放出来，并迅速带离高温区，减少同位素发生交换，液氮冷冻收集的气体加热释放后，经色谱柱分离，测试CO₂碳同位素组成，分析精度优于0.20‰（1 σ）。此外，将进样针连接于此系统，利用碳酸盐标准物质生成CO₂气体，收集并进行测试验证，结果表明，多标准建立碳同位素组成校正曲线的线性相关性（R²=1）较好。此系统可以快速、准确地在线分析矿物包裹体中CO₂碳同位素组成，实验过程全部在线完成，操作流程更加简化，实验效率大幅提高。

关键词:

English

On-line Continuous Flow Analysis of Carbon Isotopic Composition of CO₂ in Fluid Inclusions

Beijing Research Institute of Uranium Geology, Beijing 100029, China

Corresponding author: LIU Han-Bin, hanbinliu@sina.com

Received Date: 20 June 2020
Revised Date: 30 October 2020
Fund Project:
Supported by the National Key Research and Development Project of China (No. 2017YFC0602600).

Abstract: Generally, the off-line method is used to characterize the carbon isotopic composition of CO₂ enclosed in the mineral fluid inclusions. The enclosed CO₂ is first released by mechanical crushing or thermal decrepitation, and then is collected, purified and measured by isotope ratio mass spectrometer (IRMS). Here, an on-line continuous flow analytic system was developed by linking the thermal decrepitation device and IRMS with Conflo Ⅳ. The gas-liquid inclusions were heated and burst out and the released gas was quickly taken away from the high-temperature area by using high-purity He as carrier gas to reduce the isotope exchange. The gas of CO₂ was collected after cooling with liquid nitrogen and then separated by chromatographic column. The separated CO₂ was analyzed by IRMS with an analysis accuracy of 0.2‰ (1σ). By connecting the measurement needle to the system, it could be used to collect and test CO₂ produced by carbonate reference materials. The results showed that the linear correlation of the calibration curves established by several standards was significant, and the carbon isotopic composition of CO₂ within fluid inclusions could be accurately determined. By using this online method, the operation process was simplified, and the experimental efficiency was greatly improved.

Key words:

1. [1]
  ZHANG Zhou, ZHANG Hong-Fu. Earth Sci. Front., 2011, 18(3):268-283. 张舟, 张宏福. 地学前缘, 2011, 18(3):268-283.
2. [2]
  JAVOY M. Geophys. Res. Lett., 1997, 24(2):177-180.
3. [3]
  YAO Ying, SUN Qiang. Adv. Earth Sci., 2016, 31(10):1032-1040. 药瑛, 孙樯. 地球科学进展, 2016, 31(10):1032-1040.
4. [4]
  PLESSEN B, LUDERS V. Rapid Commun. Mass Spectrom., 2012, 26:1157-1161.
5. [5]
  WU R C, LIU J B, CALNER M, GONG F Y, LEHNERT O, LUAN X C, LI L X, ZHAN R B. J. Geol. Soc., 2020, 177(3):537-549.
6. [6]
  DES MARAIS D J. Rev. Mineral. Geochem., 2001, 43(1):555-578.
7. [7]
  GENNARO M E, GRASSA F, MARTELLI M, RENZULLI A, RIZZO A L. J. Volcanol. Geotherm. Res., 2017, 346:95-103.
8. [8]
  VERMA M P, GELDERN R, CARVALHO M C, GRASSA F, DELGADO-HUERTAS A, MONVOISIN G, CARRIZO D. Rapid Commun. Mass Spectrom., 2020, 34:e8685.
9. [9]
  BLANKS D E, HOLWELL D A, FIORENTINI M L, MORONI M, GIULIANI A, TASSARA S, FERRARI E. Nat. Commun., 2020, 11(1):4342.
10. [10]
  CASTILLO-OLIVER M, GIULIANI A, GRIFFIN W L, O'REILLY S Y, DRYSDALE R N, ABERSTEINER A, THOMASSOT E, LI X H. Contrib. Mineral. Petrol., 2020, 175(4):33.
11. [11]
  CHEN Yan-Jing, NI Pei, FAN Hong-Rui, Pirajno F, LAI Yong, SU Wen-Chao, ZHANG Hui. Acta Petrol. Sin., 2007, 23(9):2085-2108. 陈衍景, 倪培, 范洪瑞, Pirajno F, 赖勇, 苏文超, 张辉. 岩石学报, 2007, 23(9):2085-2108.
12. [12]
  MERNAGH T P, BASTRAKOV E N, ZAW K, WYGRALAK A S. Acta Petrol. Sin., 2007, 23(1):21-32.
13. [13]
  TAO R, HONG Z, ZHANG X C. Ore Geol. Rev., 2020, 118:103354.
14. [14]
  JIANG H, JIANG S Y, LI W Q, PENG N J, ZHAO K D. Ore Geol. Rev., 2019, 112:103007.
15. [15]
  KLEIN E L, FUZIKAWA K. Ore Geol. Rev., 2010, 37(1):31-40.
16. [16]
  LI Ji-Jun, CAO Xi-Cheng, WANG Wei-Ming, SHI Lei, LI Jing-Kun, HUO Qiu-Li. Oil Gas Geol., 2014, 35(1):124-130. 李吉君, 曹喜铖, 王伟明, 师磊, 李景坤, 霍秋立. 石油与天然气地质, 2014, 35(1):124-130.
17. [17]
  WANG Yong, HOU Zeng-Qian, MO Xuan-Xue, DONG Fang-Liu, BI Xian-Mei, ZENG Pu-Sheng. Miner. Depos., 2006, 25(1):60-70. 王勇, 侯增谦, 莫宣学, 董方浏, 毕先梅, 曾普胜. 矿床地质, 2006, 25(1):60-70.
18. [18]
  MUMM A S, OBERTHVR T, VETTER U, BLENKINSOP T G. Miner. Deposita, 1997, 32(2):107-118.
19. [19]
  HUANG Y H, TARANTOLA A, LU W J, CAUMON M C, WANG W J. Appl. Geochem., 2020, 115:104563.
20. [20]
  ZHANG Yue-Xia, HU Wen-Xuan, YAO Su-Ping, YU Hao, KANG Xun, WU Hai-Guang, HU Zhong-Ya. Geol. Bull. China, 2018, 37(10):1944-1955. 张月霞, 胡文瑄, 姚素平, 俞昊, 康逊, 吴海光, 胡忠亚. 地质通报, 2018, 37(10):1944-1955.
21. [21]
  ZHENG Shu-Hui, ZHENG Si-Cheng, MO Zhi-Chao.Stable Isotope Geochemical Analysis. Beijing, Peking University Press, 1986. 郑淑蕙, 郑斯成, 莫志超. 稳定同位素地球化学分析, 北京:北京大学出版社, 1986.
22. [22]
  DALLAI L, LUCCHINI R, SHARP Z D. Handbook of Stable Isotope Analytical Techniques, 2004:62-87.
23. [23]
  BUIKIN A I, KAMALEEVA A I, MIGDISOVA N A. Petrology, 2016, 24(3):303-313.
24. [24]
  MILLER M F, PILLINGER C T. Geochim. Cosmochim. Acta, 1997, 61(1):193-205.
25. [25]
  SANTOSH M, JACKSON D H, HARRIS N B W. J. Petrol., 1993, 34(2):233-258.
26. [26]
  LI Hong-Wei, FENG Lian-Jun, CHEN Jian. Chin. J. Anal. Chem., 2014, 42(1):127-130. 李洪伟, 冯连君, 陈健. 分析化学, 2014, 42(1):127-130.
27. [27]
  LI H W, FENG L J LI J T, CHEN J, LIU W. Anal. Methods, 2014, 6(13):4504-4506.
28. [28]
  ZHANG Han, WEI Lai, LIAO Xu, WANG Jia-Ni, SHI Qiu-Yue, ZHANG Xian. Chin. J. Anal. Chem., 2020,48(6):774-779. 张晗, 魏来, 廖旭, 王佳妮, 史秋月, 张娴. 分析化学, 2020, 48(6):774-779.
29. [29]
  YOKOKURA L, HAGIWARA Y, YAMAMOTO J. J. Raman Spectrosc., 2020, 51(6):997-1002.
30. [30]
  GONG S, SESTAK S, ARMAND S, VERGARA T. ASEG Extended Abstracts, 2018, 1:1-3.
31. [31]
  LÜDERS V, PLESSEN B, PRIMIO R D. Mar. Pet. Geol., 2012, 30(1):174-183.
32. [32]
  SOKERINA N V, ZYKIN N N, KUZNETSOV S K, ZHARKOV V A, ISAENKO S I, SHANINA S N. Geochem. Int., 2012, 51(1):76-82.
33. [33]
  KORNEXL B E, GEHRE M, HÖFLING R, WERNER R A. Rapid Commun. Mass Spectrom., 1999, 13(16):1685-1693.

扫一扫看文章

计量

PDF下载量: 0
文章访问数: 19
HTML全文浏览量: 0

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

流体包裹体CO₂碳同位素组成的在线连续流分析方法研究

通讯作者: 刘汉彬,E-mail:hanbinliu@sina.com

English

On-line Continuous Flow Analysis of Carbon Isotopic Composition of CO₂ in Fluid Inclusions

Corresponding author: LIU Han-Bin, hanbinliu@sina.com

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

流体包裹体CO2碳同位素组成的在线连续流分析方法研究

通讯作者: 刘汉彬,E-mail:hanbinliu@sina.com

English

On-line Continuous Flow Analysis of Carbon Isotopic Composition of CO2 in Fluid Inclusions

Corresponding author: LIU Han-Bin, hanbinliu@sina.com

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

流体包裹体CO₂碳同位素组成的在线连续流分析方法研究

On-line Continuous Flow Analysis of Carbon Isotopic Composition of CO₂ in Fluid Inclusions

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs